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  • Open Access

    ARTICLE

    Effect of Sulfuric Acid on the Physiochemical Properties of Chitosan-PVA Blend for Direct Methanol Fuel Cell

    RABIRANJAN MURMUa,b, DEBASHIS ROYa, HAREKRUSHNA SUTARb, PRAGYAN SENAPATIc, SWETAK ABHISEK MOHAPATRAb

    Journal of Polymer Materials, Vol.39, No.1-2, pp. 89-109, 2022, DOI:10.32381/JPM.2022.39.1-2.6

    Abstract In this work, we have successfully cross-linked the different weight ratio of Chitosan-PVA blend with sulfuric acid. The effect of cross-linker on the properties of blends are studied by using different experimental technique. The cross-linked membrane provides higher ion exchange capacity due to the procurement of extra ionic hooping sites in the membrane. The compatibility of the blends are confirmed from the FTIR and DSC analysis. The crosslinking reaction fastening the phase transition behavior of the blends which reduces the glass transition temperature. The highly compatiblized cross-linked blend provides higher tensile strength and lower modulus at moderate temperature. The significant… More >

  • Open Access

    ARTICLE

    Fluoride Ion Adsorption Effect and Adsorption Mechanism of Self-Supported Adsorbent Materials Based on Desulfurization Gypsum-Aluminate Cement

    Xuefeng Song*, Minjuan Sun, Juan He, Lei Wang

    Journal of Renewable Materials, Vol.11, No.12, pp. 4079-4095, 2023, DOI:10.32604/jrm.2023.028885

    Abstract The adsorption method has the advantages of low cost, high efficiency, and environmental friendliness in treating fluorinated wastewater, and the adsorbent material is the key. This study combines the inherent anion-exchange adsorption properties of layered double hydroxides (LDHs). Self-supported porous adsorbent materials loaded with AFm and AFt were prepared from a composite cementitious system consisting of calcium aluminate cement (CAC) and flue gas desulfurization gypsum (FGDG) by chemical foaming technique. The mineral composition of the adsorbent material was characterized by X-ray diffraction (XRD) and Scanning electron microscopy (SEM). Through the static adsorption experiment, the adsorption effect of the mineral composition… More > Graphic Abstract

    Fluoride Ion Adsorption Effect and Adsorption Mechanism of Self-Supported Adsorbent Materials Based on Desulfurization Gypsum-Aluminate Cement

  • Open Access

    ARTICLE

    PROCESS INTEGRATION OF SULFURIC ACID PLANT BASED ON CONTACT PROCESS

    Misbahudin Alhanif, Gelbert Jethro Sanyoto, Widayat Widayat*

    Frontiers in Heat and Mass Transfer, Vol.15, pp. 1-6, 2020, DOI:10.5098/hmt.15.17

    Abstract Development of sulfuric acid production method has taken us to commercial use of contact process in most industries. However, most plants still utilize coolers and steam generators to divert the excess heat. This method of energy recovery is inefficient, thus, this study attempts to redesign commercial heat exchanger network for better efficiency and lower cost. Process integration using composite curve, cascade diagram, heat exchanger network alternatives, completed with improved plant flow diagram are successfully calculated and analyzed by HINT software. Total energy saving can reach up to 74.70% and this results in total cost saving up to $ 18,000/year. More >

  • Open Access

    ARTICLE

    Application of Submerged Ultrafiltration in Pretreatment of Flue Gas Desulfurization Wastewater

    Jiageng Zhang1, Zhengfeng Wang2, Jiguang Huang1, Chao Cheng1, Heng Zhang1, Dan Gao1,*

    Energy Engineering, Vol.119, No.6, pp. 2277-2296, 2022, DOI:10.32604/ee.2022.020795

    Abstract

    Nowadays, the zero liquid discharge of flue gas desulfurization (FGD) wastewater from coal-fired units has attracted the attention of all countries in the world. The pretreatment methods generally have the problems of high operation cost, small treatment capacity, and poor flexibility. However, the membrane method can avoid the above problems. In the current research, it has not been found that someone directly uses submerged ultrafiltration to pretreat FGD wastewater. Therefore, this paper innovatively proposed to directly use ceramic ultrafiltration membrane to treat FGD wastewater, which can ensure effluent quality and improve the flexibility of the pretreatment system. In this paper,… More >

  • Open Access

    ARTICLE

    Retrieval and Regional Distribution Analysis of Ammonia, Sulfur Dioxide and Nitrogen Dioxide in the Urban Environment Using Ultraviolet DOAS Algorithm

    Hao Chen1, Jie Xu1, Yibo Hu1, Fuzhou Niu1,*, Zhiyan Li2, Dan Wang2, Guizhong Fu1, Chuanxin Li3,*

    CMES-Computer Modeling in Engineering & Sciences, Vol.134, No.2, pp. 1251-1262, 2023, DOI:10.32604/cmes.2022.022279

    Abstract Aiming at the in situ and mobile observation of urban environmental air pollution, a portable instrument using ultraviolet spectrum retrieval algorithm was developed based on the basis of Differential Optical Absorption Spectroscopy (DOAS) and multiple-pass cell technique. Typical trace gas pollutants, NH3, SO2, and NO2, were explored using their optical spectral characteristics in deep ultraviolet wavelength range from 210 to 215 nm. The gas concentration was retrieved by Lambert-Beer's law and nonlinear least square method. With an optimized optical alignment, the detection limits of NH3, SO2, NO2 were estimated to be 2.2, 2.3, and 36.2 ppb, respectively. The system was… More >

  • Open Access

    ARTICLE

    Research on the Performance of Titanium Gypsum Concrete Based on Calcium-Silicon-Sulfur Ratio

    Lixia Guo1,2,3, Weikai Wang1, Ling Zhong1,2,3,*, Yuhang Guo1

    Journal of Renewable Materials, Vol.11, No.1, pp. 423-434, 2023, DOI:10.32604/jrm.2022.022942

    Abstract Based on the high sulfur content in titanium gypsum, the concept of the calcium-silicon-sulfur (Ca/Si/S) ratio was proposed. The Ca/Si/S ratio of concrete was adjusted by changing the titanium gypsum, fly ash, and cement content. The effects of different Ca/Si/S ratios on the mechanical properties, hydration products, and concrete microstructure were investigated by nuclear magnetic resonance, uniaxial compression, and scanning electron microscopy. The result shows: (1) The compressive strength of concrete mixed with titanium gypsum increases first and then decreases with the Ca/Si/S ratio decrease. When the Ca/Si/S ratio is 1:0.85:0.10, the strength reaches the peak and is lower than… More > Graphic Abstract

    Research on the Performance of Titanium Gypsum Concrete Based on Calcium-Silicon-Sulfur Ratio

  • Open Access

    ARTICLE

    Transcriptome Analysis of Soybean in Response to Different Sulfur Concentrations

    Xiyue Wang1, Xiaomei Li2, Zihao Wu1, Shoukun Dong1,*

    Phyton-International Journal of Experimental Botany, Vol.91, No.6, pp. 1165-1182, 2022, DOI:10.32604/phyton.2022.019130

    Abstract Sulfur is an indispensable nutrient for plant growth and development, and is important in the synthesis of sulfur-containing amino acids. Although several studies on the effects of some macronutrients, including nitrogen and phosphorus, have been conducted on the performance of several crops at the genomic level, studies on the effect of sulfur on crop performance are limited. Therefore, this study aimed to examine the effect of different sulfur concentration on the transcriptome of soybean. Additionally, soybean yield parameters were also examined. Two soybean varieties, DND252 and HN84, were exposed to low and high concentrations of sulfur, and differentially expressed genes… More >

  • Open Access

    ARTICLE

    Synthesis of Hierarchical TS-1 and Its Recycling Catalytic Property for Oxidative Desulfurization

    Jinglong Huai1, Xiaoxue Liu2,*, Yinhai Zhang1, Yang Yang1, Yan Gou1, Li Qin1, Jinling Shan1, Yancheng Zheng1, Hao Li1,*

    Journal of Renewable Materials, Vol.10, No.6, pp. 1711-1726, 2022, DOI:10.32604/jrm.2022.018474

    Abstract Because of its unique pore structure, good hydrothermal stability and high specific surface area, hierarchical TS-1 zeolite (HTS-1) has become an important catalyst for the deep oxidative desulfurization of fuel oils. In this work, HTS-1 has been successfully synthesized by a hydrothermal crystallization method using the C-SiO2 composite as both silicon source and mesoporous template, tetrapropylammonium hydroxide as microporous template, and tetrabutylorthotitanate as titanium source. The C-SiO2 composite is obtained by mild carbonization of the SiO2/T-40 (Tween 40) xerogel, which is prepared by the two step sol-gel method. The reaction conditions for the oxidative desulfurization (ODS) of dibenzothiophene (DBT) and… More > Graphic Abstract

    Synthesis of Hierarchical TS-1 and Its Recycling Catalytic Property for Oxidative Desulfurization

  • Open Access

    ARTICLE

    Field Studies on the Removal Characteristics of Particulate Matter and SOx in Ultra-Low Emission Coal-Fired Power Plant

    Xu Zhao, Houzhang Tan, Fuxin Yang*, Shuanghui Deng

    Energy Engineering, Vol.119, No.1, pp. 49-62, 2022, DOI:10.32604/EE.2022.015622

    Abstract In order to reduce the environmental smog caused by coal combustion, air pollution control devices have been widely used in coal-fired power plants, especially of wet flue gas desulfurization (WFGD) and wet electrostatic precipitator (WESP). In this work, particulate matter with aerodynamic diameter less than 10 μm (PM10) and sulfur oxides (SOx) have been studied in a coal-fired power plant. The plant is equipped with selective catalytic reduction, electrostatic precipitator, WFGD, WESP. The results show that the PM10 removal efficiencies in WFGD and WESP are 54.34% and 50.39%, respectively, and the overall removal efficiency is 77.35%. WFGD and WESP have… More >

  • Open Access

    ARTICLE

    Development of Steel Slag-Based Solidification/Stabilization Materials for High Moisture Content Soil

    Yu Jia1, Sudong Hua1,*, Liying Qian2, Xiaojian Ren2, Jie Zuo3, Yanfang Zhang3

    Journal of Renewable Materials, Vol.10, No.3, pp. 735-749, 2022, DOI:10.32604/jrm.2022.016819

    Abstract To solve the problems of high moisture content, high viscosity, and poor engineering mechanical properties of soil, this paper using with steel slag (SS) and desulfurization ash (DS) as initial raw materials, realizing the cooperative treatment of solid waste and solidification of silt soil. The synergistic utilization of SS and DS can reduce the production cost of curing agent and promote its own consumption. According to blended cement of various SS contents and inspected compressive strength performances, the most suitable raw materials ratio was selected. The best formula for this curing agent is cement:steel slag = 3:7 with 5% DS, and its… More >

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