Henghui Deng^1,2, Jingyi Lu^1,2, Dunsheng Liang^1,2, Xiaomin Wang^1,2, Tongyao Wang^1,2, Weihao Zhang^1,2, Jing Wang^3,*, Chaoqun Zhang^1,2,*

Journal of Renewable Materials, Vol.11, No.3, pp. 1209-1222, 2023, DOI:10.32604/jrm.2022.023371

Abstract In this study, acrylic acid was used as a neutralizer to prepare bio-based WPU with an interpenetrating polymer network structure by thermally induced free radical emulsion polymerization. The effects of the content of acrylic acid on the properties of the resulting waterborne polyurethane-poly (acrylic acid) (WPU-PAA) dispersion and the films were systematically investigated. The results showed that the cross-linking density of the interpenetrating network polymers was increased and the interlocking structure of the soft and hard phase dislocations in the molecular segments of the double networks was tailored with increasing the content of acrylic acid, leading to enhancement of the… More > Graphic Abstract

Sai Gong^1,2,#, Shanglin Xiang^1,#, Tingwei Wang^1,*, Dongyu Cai^2,*

Journal of Renewable Materials, Vol.11, No.3, pp. 1063-1076, 2023, DOI:10.32604/jrm.2022.023011

Abstract Waterborne polymers are vital for coating industry to reduce carbon emissions. However, formation of robust and self-healable films at ambient temperature remains a challenge owing to high energy cost of film formation process. This work reports a solar-driven film formation of waterborne polyurethanes (WPUs) containing disulfide bonds via in-situ incorporation of 2D titanium carbide (MXene) with ability to convert light to heat. Instead of directly mixed with WPUs, MXene is added to join the reaction with isocyanate-terminated pre-polymer before emulsification process. This approach not only prevents aggregation of MXene in water but stabilizes MXene against thermal degradation which is the… More > Graphic Abstract

Xuechuan Wang^1,2, Wenying Zhao^1,2, Xugang Dang^1,2,*, Yiqing Wang^1,2, Huijie Zhang^1,2,*

Journal of Renewable Materials, Vol.10, No.11, pp. 2747-2763, 2022, DOI:10.32604/jrm.2022.021555

Abstract As a non-toxic, highly reactive biomass material, gelatin is wildly used as the component of biomass-based adhesive. However, like most aqueous adhesives, gelatin-based adhesives suffer from long solidifying time or high solidifying temperature due to the low volatility of water, which highly limits the application potential of gelatinbased adhesives. Inspired by the fast adhesion of marine organisms through the formation of chemical crosslinks, herein, a kind of low temperature curable eco-friendly gelatin-based adhesive with good adhesive properties and fast curing at low temperature is developed by introducing clicking chemical Diels-Alder (DA) reaction between blocked waterborne polyurethane (MWPU) and gelatin. The… More > Graphic Abstract

Xing Zhou^*

Journal of Renewable Materials, Vol.10, No.6, pp. 1623-1639, 2022, DOI:10.32604/jrm.2022.018935

Abstract A facile method, focusing on emulsification, chain extension and dispersion process in preparing waterborne polyurethane, was developed to prepare emulsion with rod-like nanoparticles. The facile method involves a water addition procedure by in situ generated water to react with polyurethane prepolymer instead of the external water addition process. As a comparison, waterborne polyurethane was synthesized through the external water addition process. According to the characterization methods including FTIR, ¹H-NMR, TEM and water swelling experiments, it is suggested there are two kinds of hydrogen bonds interactions in hard/soft domain of the novel polyurethane, and the phase separation of hard/soft domains increases… More > Graphic Abstract

Zhipeng He^1,2, Junqi Xue^1,2, Yanzi Ke^1,2, Ying Luo^1,2,*, Qiming Lu^1,2, Yuehua Xu^1,2, Chaoqun Zhang^1,2,*

Journal of Renewable Materials, Vol.10, No.3, pp. 591-604, 2022, DOI:10.32604/jrm.2022.017790

Abstract Nowadays, waterborne polyurethanes (WPUs) prepared from renewable resources has attracted more and more attention. However, due to its structure, the prepared films easily swells in water and greatly affects the application range of WPUs. Therefore, solving the problem of water resistance is a way to improve the application range of WPUs. In this study, a series of WPU dispersions were prepared using castor oil as the bio-based polyol. Besides, the thiol-ene photo click reaction was carried out on the WPU films for silane modification. The effect of the silane modification on the chemical structures of the WPU dispersions and the… More > Graphic Abstract

Xing Zhou^1,*, Xin Zhang¹, Dong Wang¹, Changqing Fang^1,*, Wanqing Lei¹, Zhigang Huang², Yonghua Song¹, Xinyu He¹, Yingwei Huang¹

Journal of Renewable Materials, Vol.8, No.6, pp. 631-645, 2020, DOI:10.32604/jrm.2020.010176

Abstract Cellulose plays a key role in abundant organic natural materials meeting the increasing demand for green and biocompatible products. The highly crystalline nanoscale component of cellulose nanocrystals has recently attracted great attention due to the versatile performance as filler or matrix in producing functional materials. In this work, we prepared the waterborne polyurethane via a prepolymer process, and obtained cellulose and cellulose nanocrystals from waste paper via a facile acid hydrolysis process. After that, the cellulose nanocrystals were assembled into film and mixed with polyurethane to prepare flexible polyurethane/cellulose nanocrystals composite membrane with different soaking time. The correlation between the… More >

Verónica L. Mucci¹, M. E. Victoria Hormaiztegui², Mirta I. Aranguren^1,*

Journal of Renewable Materials, Vol.8, No.6, pp. 579-601, 2020, DOI:10.32604/jrm.2020.09455

Abstract The increasing pressure from consumers and policy makers to reduce the use of synthetic polymers, whose production contributes to the depletion of non-renewable resources and are usually non- biodegradable, has prompted the efforts to find suitable bio-based sources for the production of polymers. Vegetable oils have been a frequently spotted in this search because they are versatile, highly available and a low cost liquid biosource, which can be used in the synthesis of a wide plethora of different polymers and reactive monomers. Following the same idea of reducing the environmental stress, the traditional polyurethanes that are soluble in organic solvents… More >