KEMIN WANG, LIFEI HE

Journal of Polymer Materials, Vol.36, No.3, pp. 253-260, 2019, DOI:10.32381/JPM.2019.36.03.5

Abstract This study proposes a simple approach for the fabrication of microspherical catalysts with a hierarchical porous structure. The cross-linked porous microspheres with catalytic ability were prepared directly from small-molecular monomers via low-temperature phase-separation photopolymerization of water/oil suspension. The morphology, pore size, chemical structure, and thermal stability of the obtained porous microspheres were characterized by SEM, Mercury Intrusion Porosimetry, FTIR, and TGA. The porous microspheres directly served as an acid catalyst for the condensation reaction of benzaldehyde and ethylene glycol, which exhibited superior catalytic activity and recyclability. The results indicated that such porous microspheres have great potential in the application of… More >

RUBY AHMED¹, MOHAMMAD OMAISH ANSARI², FARMAN ALI¹, SHAHID PERVEZ ANSARI^1,*

Journal of Polymer Materials, Vol.36, No.3, pp. 243-251, 2019, DOI:10.32381/JPM.2019.36.03.4

Abstract Polyaniline (PANI) and molybdenum disulphide (MoS₂ ) were used to prepare nanocomposites by in-situ oxidative polymerization of acidified aniline in presence of dispersed MoS₂ in the reaction mixture. Electron Microscopy (SEM & TEM), Fourier Transform Infrared (FTIR) spectroscopy, Ultraviolet-Visible (UV-Vis) spectroscopy, and X-ray diffraction (XRD) were used to characterize these nanocomposites. SEM micrographs showed that PANI is present on the layers of MoS₂ which were exfoliated during the preparation and the presence of MoS₂ is also confirmed by XRD peaks. The nanocomposites were studied for their electrical conductivity and stability of electrical conductivity in terms of d.c. electrical conductivity retention.… More >

XIANRONG SHEN^1,*, DENGZHOU XIA¹, YIXIN XIANG¹, JIANGANG GAO¹

Journal of Polymer Materials, Vol.36, No.3, pp. 229-241, 2019, DOI:10.32381/JPM.2019.36.03.3

Abstract ARGET ATRP of methyl acrylate (MA) with low concentration of air stable-CuBr₂ catalyst was successfully carried out in green solvent polyethylene glycol (PEG) without any external reducing agent.The polymerizations of MA proceeded in a well-controlled manner as evidenced by kinetic studies, chain extension results, a linear increase of the molecular weights with the increasing of monomer conversion. and narrow molecular weight distribution (M_w/M_n =1.1). Interestingly, we found that the PEG has the reduction ability to CuBr₂ and could play as supplement reducing agent cooperation with Me₆ TREN to mediate ARGET ATRP. Reduction of Cu(II)Br₂ to Cu(I)Br by different molecular weight… More >

KAZIM SHAMIM RIZVI, P. K. DUTTA

Journal of Polymer Materials, Vol.36, No.3, pp. 217-228, 2019, DOI:10.32381/JPM.2019.36.03.2

Abstract In this investigation we have shown the preparation of carboxylic acid containing new chromophore : 4-(3-(4-nitrophenyl) thioureido) benzoic acid and its use.The chemical modification of chitosan, e.g., chitosan- acid salt complexes is done under mild conditions. The synthesis of chromophore was carried out by conventional methods and the novel polymer complex was soluble in most of the organic solvents. The modified chitosan was analyzed by various techniques like optical properties by UV and SHG spectroscopy which showed red shift. The antibacterial activity showed obvious effect against food pathogenic bacteria. More >

MERYEM KORUYUCU^a, FEHMi SALTAN^a,b, GÖKHAN KÖK^a, HAKAN AKAT^a, YEŞIM SALMAN^a,*

Journal of Polymer Materials, Vol.36, No.3, pp. 207-216, 2019, DOI:10.32381/JPM.2019.36.03.1

Abstract The present study has demonstrated that novel acrylic glycopolymers are successfully prepared by using monosaccharides containing an acrylate group (9-12). For this purpose, sugar based acrylate monomers were synthesized via ring opening method (Method B) and homopolymerization of this sugar oxypropylacrylates was performed using free radical polymerization. The characterization of all the monomers and polymers were verified by ¹HNMR, ¹³CNMR, FTIR and GPC techniques. The Glass transition temperatures and thermal characteristics of the polymers were also analyzed by using DSC and TG techniques. The thermal stability of prepared polymers have changed with the stereochemistry of the carbohydrate moiety. Also, the… More >

KAVITA^*, R.K. TIWARI

Journal of Polymer Materials, Vol.36, No.2, pp. 195-205, 2019, DOI:10.32381/JPM.2019.36.02.7

Abstract The effect of poly (vinyl butyral) and acid functionalized multiwalled carbon nanotubes (f-MWCNT) on the thermal and mechanical performance of Kevlar fiber reinforced novolac epoxy nanocomposites was investigated and presented in this paper. Nanocomposite containing 1.5 wt. % poly (vinyl butyral) and 0.5 wt. % f-MWCNT exhibited best thermal and mechanical properties (except flexural strength) among all the nanocomposites reported here. It showed ~5%, 27% and 126 % improvement in tensile strength, young’s modulus and impact strength respectively as compared to the neat novolac epoxy Kevlar composite.Nanocomposite containing 0.5 wt. % f- MWCNT and 2 wt. % poly (vinyl butyral)… More >

AMRITA SHARMA, P. P. PANDE

Journal of Polymer Materials, Vol.36, No.2, pp. 175-194, 2019, DOI:10.32381/JPM.2019.36.02.6

Abstract ‘Comb-like polymers’ are a special class of polymers. These are consisting of two types of chains, first one is the backbone chain and second is long side chains. The structure of such a polymer is very similar to hair comb. Usually, every monomer unit in the backbone has a long n-alkyl side chain. Comb like polymers have an intrinsic ability towards forming ordered structure. Now-a-days, these polymers find wide range of applications because of their excellent physicochemical properties. Some applications are in preparation of polysoaps (polymeric disinfectants), as dispersing agent for ink and paints, textile industry, in surface modification of… More >

AYÇA BAL ÖZTÜRK^1,2,*, ZEHRA ÖZBA޳, BENGİ ÖZKAHRAMAN⁴, SERKAN EMİK⁵

Journal of Polymer Materials, Vol.36, No.2, pp. 161-173, 2019, DOI:10.32381/JPM.2019.36.02.5

Abstract A functionalized hydrogel composed of 2-(hydroxyethyl) methacrylate (HEMA) and acrylamide (AAm) was synthesized by amination and saponification reactions, respectively, and its functionality was examined for the elimination of copper(II) ions. The maximum adsorption capacity for copper(II) ions was 0.617 mmol g^-1 before saponification, whereas it was 1.2225 mmol g^-1 after saponification. The adsorption data was analyzed with pseudo-first-order (r² =0.8867), intra-particle diffusion (r² =0.9453), Elovich (r²=0.9489) and pseudo-secondorder(r² =0.9999) kinetic models. Based on the adsorption equilibrium experimental data Freundlich(r² =0.9964), Langmuir(r²=0.998) and Dubinin–Radushkevich (D-R) (r² =0.9960) adsorption isotherms provided good fits for all of experimental results. Finally, the datas of… More >

ZONGQIAN WANG, HAIWEI YANG, JIAN XING, ZHI LIU^*

Journal of Polymer Materials, Vol.36, No.2, pp. 149-159, 2019, DOI:10.32381/JPM.2019.36.02.4

Abstract Colored silk fibroin (SF) film can change the proportion of transmitted light composition and therefore shows potential application in optoelectronics area. However, few methods are reported for the preparation of colored SF film with good color fastness. Herein, colored SF film was prepared by coupling modification dyeing (CM-dyeing) of SF tyrosine residues in solution. SF film shows excellent color fastness due to the formation of the azo covalent bond formed by electrophilic substitution reaction between SF tyrosine residues and aniline diazonium salt. Furthermore, compared with the undyed film, the dyed SF film is effectively preserved its mechanical property by the… More >

FEHMI SALTAN^1,2, AYLIN PALAMUTLU², HAKAN AKAT^2,*

Journal of Polymer Materials, Vol.36, No.2, pp. 133-147, 2019, DOI:10.32381/JPM.2019.36.02.3

Abstract In this work, tetraphenylporphyrin (TPP) compound was first synthesized by the condensation reaction of pyrrole and benzaldehyde using Adler method. Then, the synthesized tetraphenylporphyrin was nitrated with sodium nitrite. Nitro-functionalized porphyrin (TPP-NO₂ ) compound was reduced to amine-functional using ammonia and this amine- functionalized porphyrin was reacted with methacryloyl chloride to obtain porphyrin-derived radical monomer (TPP-MAO). Copolymer was synthesized with obtained porphyrin functional monomer and styrene by free radical polymerization method. Structural characterization and spectroscopic studies of the synthesized compounds were carried out by FTIR, H¹ -NMR, UV spectroscopy. The molecular weight and thermal properties of the copolymer were determined… More >