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  • Open Access

    ARTICLE

    Characteristic of Fresh and Harden Properties of Polyvinyl Alcohol Fibre Reinforced Alkali Activated Composite

    Yiguang Wang1,2, Zhe Zhang1, Xun Zhang1,*

    Journal of Renewable Materials, Vol.11, No.3, pp. 1321-1337, 2023, DOI:10.32604/jrm.2022.023266 - 31 October 2022

    Abstract Fibre can enhance the mechanical properties of cement-based composites, but fibre also degrades their workability. However, the quantitative effects of fiber content and length-diameter ratio on alkali-activated materials are still unclear. Various aspect ratio, volume fraction of polyvinyl alcohol fibre (PVAF), and various water-binder ratio were employed to prepare a total of 26 groups of fibre reinforced alkali-activated composite (FRAAC). The influence of PVAF fibre factor (product of fiber volume fraction and length-diameter ratio) on flowability, compactness, strength, and crack fractal dimension of FRAAC was researched. The influence of water-binder ratio on the plastic viscosity… More >

  • Open Access

    ARTICLE

    Study on Hydrogen Storage Properties, Anti-Oxide Ability and Rate Limiting Step of ZrCr-Based Alloy after Introducing Cobalt as Additive

    Dongfang Huang1,4, Peng Lv1,2,3,4,*, Changlin Zhong1,2, Xingsheng Zhou1,2, Zhichen Liu4

    Journal of Renewable Materials, Vol.11, No.3, pp. 1383-1400, 2023, DOI:10.32604/jrm.2022.023261 - 31 October 2022

    Abstract In this work, the microstructure, hydrogen storage properties, anti-oxide ability and rate limiting step of Zr(Cr1−xCox)2 (x = 0, 0.2, 0.4 and 0.6) alloys have been investigated. After studying the crystal structure, we found that all alloy samples could show C14-type phase but the alloy sample x = 0 could also show a small amount of Cr phase. Rietveld fitting showed that lattice parameter and unit cell volume of C14-type phase decreased with increasing x. After further research, it was clear that the first hydrogen absorption capacity decreased with increasing x. But introducing more Co content had a positive influence More >

  • Open Access

    ARTICLE

    Comparative Study on Properties of PBAT/PBSA Film Modified by a Multi-Functional Epoxide Chain Extender or Benzoyl Peroxide

    Yanfeng Zhu1, Huidong Shi1, Qing Ju1, Dong Zhao1, Yucai Shen1,2,*, Tingwei Wang1,2,*

    Journal of Renewable Materials, Vol.11, No.3, pp. 1303-1319, 2023, DOI:10.32604/jrm.2022.023129 - 31 October 2022

    Abstract Poly(butylene adipate-co-terephthalate) (PBAT) and poly(butylene succinate-co-adipate) (PBSA) blend films were prepared with different contents of a multifunctional epoxide chain extender Joncryl ADR-4468 (ADR) or benzoyl peroxide (BPO). The long-chain-branching (LCB) introduced by ADR and branched/crosslinked entanglement induced by BPO increased melt elasticity, viscosity and compatibility, as indicated by thermal properties, rheological and morphological analyses. It was found that the elongation at break and the tensile strength were significantly improved, due to the enhancement of compatibility and the interfacial adhesion by the incorporation of ADR or BPO. The best mechanical properties were obtained in PBAT/PBSA/ADR (60/40/0.3) (A4T6A0.3) More > Graphic Abstract

    Comparative Study on Properties of PBAT/PBSA Film Modified by a Multi-Functional Epoxide Chain Extender or Benzoyl Peroxide

  • Open Access

    ARTICLE

    Dynamic Behaviour of Pond Ash Mixed with Coir and Crumb Rubber

    Ashish Malik*, Sanjay Kumar Singh

    Journal of Renewable Materials, Vol.11, No.3, pp. 1271-1291, 2023, DOI:10.32604/jrm.2022.023084 - 31 October 2022

    Abstract An experimental program was conducted to determine the dynamic properties of pond ash (PA) and pond ash mixed with admixtures like crumb rubber (CR) and coir fiber (CF) which are wastes of different industries. Additives CR and CF were mixed separately with pond ash in a percentage ranging from 0%–20% at an interval of 5% and 0%–2% at an interval of 0.5% by weight of pond ash, respectively. Dynamic properties (Shear modulus, Number of cycles to initiate liquefaction, Degradation index and Damping ratio) for pond ash mixes were determined using strain-controlled cyclic tri-axial apparatus. The… More >

  • Open Access

    ARTICLE

    Towards Solar-Driven Formation of Robust and Self-Healable Waterborne Polyurethane Containing Disulfide Bonds via in-situ Incorporation of 2D Titanium Carbide MXene

    Sai Gong1,2,#, Shanglin Xiang1,#, Tingwei Wang1,*, Dongyu Cai2,*

    Journal of Renewable Materials, Vol.11, No.3, pp. 1063-1076, 2023, DOI:10.32604/jrm.2022.023011 - 31 October 2022

    Abstract Waterborne polymers are vital for coating industry to reduce carbon emissions. However, formation of robust and self-healable films at ambient temperature remains a challenge owing to high energy cost of film formation process. This work reports a solar-driven film formation of waterborne polyurethanes (WPUs) containing disulfide bonds via in-situ incorporation of 2D titanium carbide (MXene) with ability to convert light to heat. Instead of directly mixed with WPUs, MXene is added to join the reaction with isocyanate-terminated pre-polymer before emulsification process. This approach not only prevents aggregation of MXene in water but stabilizes MXene against thermal More > Graphic Abstract

    Towards Solar-Driven Formation of Robust and Self-Healable Waterborne Polyurethane Containing Disulfide Bonds via <i>in-situ</i> Incorporation of 2D Titanium Carbide MXene

  • Open Access

    ARTICLE

    Seaweed Fiber Fabricated with Agar Alkali-Free Extracted from Gracilaria lemaneiformis

    Yuzhi Wu1, Cunzhen Geng1,*, Chaochao Cui2, Zhefeng Xin2, Yanzhi Xia1, Zhixin Xue1,*

    Journal of Renewable Materials, Vol.11, No.3, pp. 1199-1208, 2023, DOI:10.32604/jrm.2022.022976 - 31 October 2022

    Abstract The sulfate groups in agar structure played a good role in the formation of fiber. However, commercially available agar is usually extracted from red algae by alkali treatment to decrease the content of sulfate group for the purpose of high gel strength. In this paper, an alkali-free method of agar extraction from Gracilaria lemaneiformis was proposed for the wet-spinning purpose. This method is environmentally friendly, reduces the extraction steps, saves energy, and reduces the production cost of agar fiber. The improved agar preparation process not only has higher agar yield, but also has higher molecular weight More > Graphic Abstract

    Seaweed Fiber Fabricated with Agar Alkali-Free Extracted from <i>Gracilaria lemaneiformis</i>

  • Open Access

    ARTICLE

    Nano-CaO2 Promotes the Release of Carbon Sources from Municipal Sludge and the Preparation of Double-Network Hydrogels with High Swelling Ratios

    Yalin Li1,2,*, Yu Huang2, Lei Liu1, Haozhao Liu1, Haiyang He1, Dongxue Lu1, Tingting Dong1

    Journal of Renewable Materials, Vol.11, No.3, pp. 1237-1253, 2023, DOI:10.32604/jrm.2022.022972 - 31 October 2022

    Abstract

    In this study, hydrogels were prepared from municipal sludge to recycle and realize the value-added utilization of the carbon components in this abundant waste material. The carbon sources were extracted from the municipal sludge using synthesised nano CaO2 as an oxidant, and the carbon sources were graft copolymerised with acrylic acid monomer using N, N′-methylenebisacrylamide as a crosslinking agent and ammonium persulfate as an initiator. The factors influencing the hydrogel preparation were investigated by single-factor experiments. Based on the results of the single-factor experiments, a hydrogel with a swelling ratio of up to 19768.4% at 12

    More > Graphic Abstract

    Nano-CaO<sub>2</sub> Promotes the Release of Carbon Sources from Municipal Sludge and the Preparation of Double-Network Hydrogels with High Swelling Ratios

  • Open Access

    ARTICLE

    Properties and Hydration Mechanism of Cementitious Materials Prepared from Calcined Coal Gangue

    Zhaopeng Wang, Shaowu Jiu, Hui Li*, Kaifeng Zhang, Simeng Cheng

    Journal of Renewable Materials, Vol.11, No.3, pp. 1223-1236, 2023, DOI:10.32604/jrm.2022.022893 - 31 October 2022

    Abstract The preparation of cementitious materials by replacing part of the cement with activated coal gangue is of great significance to the cement industry in terms of carbon reduction and coal-based solid waste utilization. For this paper, cementitious material was prepared by firing activated coal gangue under suspension conditions and batching it with limestone powder using Inner Mongolia coal gangue as raw material. The optimal ratio was determined by testing the strength changes of the cementitious material at 3, 7, and 28 days of hydration, and the hydration process and mechanism were explored by combining the… More >

  • Open Access

    ARTICLE

    Life Cycle Assessment Introduced by Using Nanorefrigerant of Organic Rankine Cycle System for Waste Heat Recovery

    Yuchen Yang1,2, Lin Ma1,2,*, Jie Yu1,2, Zewen Zhao1,2, Pengfei You1,2

    Journal of Renewable Materials, Vol.11, No.3, pp. 1153-1179, 2023, DOI:10.32604/jrm.2022.022719 - 31 October 2022

    Abstract The use of nanorefrigerants in Organic Rankine Cycle (ORC) units is believed to affect the cycle environment performance, but backed with very few relevant studies. For this purpose, a life cycle assessment (LCA) has been performed for the ORC system using nanorefrigerant, the material and energy input, characteristic indicators and comprehensive index of environmental impact, total energy consumption and energy payback time (BPBT) of the whole life cycle of ORC system using Al2O3/R141b nanorefrigerant were calculated. Total environmental comprehensive indexes reveal that ECER-135 index decrease by 1.5% after adding 0.2% Al2O3 nanoparticles to R141b. Based on… More >

  • Open Access

    ARTICLE

    Fully Bio-Based Composites of Poly (Lactic Acid) Reinforced with Cellulose-Graft-Poly-(ε-Caprolactone) Copolymers

    Chengtao Gao1,2, Yang Wu3, Haibo Xie1,*

    Journal of Renewable Materials, Vol.11, No.3, pp. 1137-1152, 2023, DOI:10.32604/jrm.2022.021473 - 31 October 2022

    Abstract

    Due to the increasing demand for modified polylactide (PLA) meeting “double green” criteria, the research on sustainable plasticizers for PLA has attracted broad attentions. This study reported an open-ring polymerization method to fabricate cellulose (MCC)-g-PCL (poly (ε-caprolactone)) copolymers with a fully sustainable and biodegradable component. MCC-g-PCL copolymers were synthesized, characterized, and used as green plasticizers for the PLA toughening. The results indicated that the MCC-g-PCL derivatives play an important role in the compatibility, crystallization, and toughening of the PLA/MCC-g-PCL composites. The mechanical properties of the fully bio-based PLA/MCC-g-PCL composites were optimized by adding 15 wt% MCC-g-PCL,

    More > Graphic Abstract

    Fully Bio-Based Composites of Poly (Lactic Acid) Reinforced with Cellulose-Graft-Poly-(ε-Caprolactone) Copolymers

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