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  • Open Access

    ARTICLE

    Profiles of the Headspace Volatile Organic and Essential Oil Compounds from the Tunisian Cardaria draba (L.) Desv. and Its Leaf and Stem Epidermal Micromorphology

    Wissal Saadellaoui1, Samiha Kahlaoui1, Kheiria Hcini1, Abir Haddada1, Noomene Sleimi2,*, Roberta Ascrizzi3, Guido Flamini3, Fethia Harzallah-Skhiri4, Sondes Stambouli-Essassi1

    Phyton-International Journal of Experimental Botany, Vol.93, No.4, pp. 725-744, 2024, DOI:10.32604/phyton.2024.048110

    Abstract In this work, we investigated aroma volatiles emanated by dry roots, stems, leaves, flowers, and fruits of Cardaria draba (L.) Desv. growing wild in Tunisia and its aerial part essential oils (EOs) composition. A total of 37 volatile organic compounds (96.7%–98.9%) were identified; 4 esters, 4 alcohols, 7 hydrocarbons, 12 aldehydes, 5 ketones, 1 lactone, 1 organosulfur compound, 2 organonitrogen compounds, and 1 acid. The hydrocarbons form the main group, representing 49.5%–84.6% of the total detected volatiles. The main constituent was 2,2,4,6,6-pentamethylheptane (44.5%–76.2%) reaching the highest relative percentages. Forty-two compounds were determined in the two fractions of EOs, representing 98.8%… More >

  • Open Access

    ARTICLE

    Functionalized 2-(hydroxyethyl) methacrylate (HEMA)- co-acrylamide (AAm) hydrogels: Kinetic and Isotherm Modelling Analysis on the Removal of Cu(II) Ions

    AYÇA BAL ÖZTÜRK1,2,*, ZEHRA ÖZBAŞ3, BENGİ ÖZKAHRAMAN4, SERKAN EMİK5

    Journal of Polymer Materials, Vol.36, No.2, pp. 161-173, 2019, DOI:10.32381/JPM.2019.36.02.5

    Abstract A functionalized hydrogel composed of 2-(hydroxyethyl) methacrylate (HEMA) and acrylamide (AAm) was synthesized by amination and saponification reactions, respectively, and its functionality was examined for the elimination of copper(II) ions. The maximum adsorption capacity for copper(II) ions was 0.617 mmol g-1 before saponification, whereas it was 1.2225 mmol g-1 after saponification. The adsorption data was analyzed with pseudo-first-order (r2 =0.8867), intra-particle diffusion (r2 =0.9453), Elovich (r2=0.9489) and pseudo-secondorder(r2 =0.9999) kinetic models. Based on the adsorption equilibrium experimental data Freundlich(r2 =0.9964), Langmuir(r2=0.998) and Dubinin–Radushkevich (D-R) (r2 =0.9960) adsorption isotherms provided good fits for all of experimental results. Finally, the datas of… More >

  • Open Access

    ARTICLE

    Development of Functional Adsorbent from Natural Biosorbent “Chitosan” by Radiation Induced Grafting of MAETC for the Removal of Arsenic (V)

    VIJAYASRI. K1, ALKA TIWARI1,*, C.V. CHAUDHARI2

    Journal of Polymer Materials, Vol.36, No.1, pp. 53-73, 2019, DOI:10.32381/JPM.2019.36.01.5

    Abstract High energy gamma radiation has been used to graft [2-(methacryloyloxyethyl) trimethylammonium chloride (MAETC) onto chitosan by radiation grafting method. Grafting yield was found to increase with the increase in radiation dose and monomer concentration. Fourier Transform Infrared Spectroscopy (FTIR) was used to characterize the grafted polymer and their morphological structure was analyzed by Scanning Electron Microscope (SEM). As(V) ions uptake capacity of the adsorbent was evaluated in different pH, contact time, temperature, adsorbent dose, and different arsenate ion concentration. The adsorption data was fitted well in the Langmuir model and various static parameters were calculated. It is stated that this… More >

  • Open Access

    ARTICLE

    Investigation of Polypyrrole and Polypyrrolepolyethyleneimine as Adsorbents for Methyl Orange Dye Adsorption

    NORHABIBAH MOHAMAD1,*, NOORDINI M. SALLEH1,2, HABIBUN NABI MUHAMMAD EKRAMUL MAHMUD1

    Journal of Polymer Materials, Vol.40, No.3-4, pp. 165-189, 2023, DOI:10.32381/JPM.2023.40.3-4.4

    Abstract The present study has explored the adsorption properties of polypyrrole-based adsorbents (polypyrrole and polypyrrole-polyethyleneimine composite) as novel conducting polymers in adsorbing methyl orange (MO) (an anionic dye) effectively from aqueous solution. The adsorption characteristics of the prepared polymer-based adsorbents were characterized by BET, FTIR, FESEM, and XRD methods. The effectiveness of PPy-based adsorbents for MO dye adsorption was examined using the batch adsorption method. Different parameters were changed during the adsorption process, including contact time, solution pH, and adsorbent dosage. The highest BET surface area of the PPy-PEI composite was found to be 11.85 m2 /g, which is much greater… More >

  • Open Access

    REVIEW

    Types and Sources of Microplastics; The Ubiquitous Environment Contaminant: A Review

    ARCHNA RANI

    Journal of Polymer Materials, Vol.39, No.1-2, pp. 17-35, 2022, DOI:10.32381/JPM.2022.39.1-2.2

    Abstract Accumulation of Microplastics (MPs) in diverse ecosystems is a growing global problem of our time. These are entering into the environment directly (micro-sized plastics manufactured purposefully) and by degradation of plastic products. Due to a diverse range of polymers and additives used to manufacture plastic products, the MPs of different chemical compositions are abundant in the environment. A detailed literature survey revealed that MPs -environment interaction is largely governed by these chemicals and other intrinsic properties of MPs viz. shape, size, density, surface charge, etc. The current investigation primarily aims to review different chemical and physical factors of MPs that… More >

  • Open Access

    ARTICLE

    Activated Carbon from Nipa Palm Fronds (Nypa fruticans) with H3PO4 and KOH Activators as Fe Adsorbers

    Ninis Hadi Haryanti1,*, Eka Suarso1, Tetti N. Manik1, Suryajaya1, Nurlita Sari1, Darminto2

    Journal of Renewable Materials, Vol.12, No.2, pp. 203-214, 2024, DOI:10.32604/jrm.2023.043549

    Abstract Nipa palm is one of the non-wood plants rich in lignocellulosic content. In this study, palm fronds were converted into activated carbon, and their physical, chemical, and morphological properties were characterized. The resulting activated carbon was then applied as an adsorbent of Fe metal in peat water. The carbonization process was carried out for 60 min, followed by sintering at 400°C for 5 h with a particle size of 200 mesh. KOH and H3PO4 were used in the chemical activation process for 24 h. KOH-activated carbon contained 6.13% of moisture, 4.55% of ash, 17.02% of volatile matter, and 78.84% of… More > Graphic Abstract

    Activated Carbon from Nipa Palm Fronds (<i>Nypa fruticans</i>) with H<sub>3</sub>PO<sub>4</sub> and KOH Activators as Fe Adsorbers

  • Open Access

    REVIEW

    Crossroads: Pathogenic role and therapeutic targets of neutrophil extracellular traps in rheumatoid arthritis

    YANG LI1,2, JIAN LIU1,3,*, YUEDI HU1,2, CHENGZHI CONG1,2, YIMING CHEN1,2, QIAO ZHOU1,2

    BIOCELL, Vol.48, No.1, pp. 9-19, 2024, DOI:10.32604/biocell.2023.045862

    Abstract Rheumatoid arthritis (RA) is a prevalent autoimmune disease whose main features include chronic synovial inflammation, bone destruction, and joint degeneration. Neutrophils are often considered to be the first responders to inflammation and are a key presence in the inflammatory milieu of RA. Neutrophil extracellular traps (NETs), a meshwork of DNA-histone complexes and proteins released by activated neutrophils, are widely involved in the pathophysiology of autoimmune diseases, especially RA, in addition to playing a key role in the neutrophil innate immune response. NETs have been found to be an important source of citrullinated autoantigen antibodies and inflammatory factor release, which can… More > Graphic Abstract

    Crossroads: Pathogenic role and therapeutic targets of neutrophil extracellular traps in rheumatoid arthritis

  • Open Access

    ARTICLE

    SDH-FCOS: An Efficient Neural Network for Defect Detection in Urban Underground Pipelines

    Bin Zhou, Bo Li*, Wenfei Lan, Congwen Tian, Wei Yao

    CMC-Computers, Materials & Continua, Vol.78, No.1, pp. 633-652, 2024, DOI:10.32604/cmc.2023.046667

    Abstract Urban underground pipelines are an important infrastructure in cities, and timely investigation of problems in underground pipelines can help ensure the normal operation of cities. Owing to the growing demand for defect detection in urban underground pipelines, this study developed an improved defect detection method for urban underground pipelines based on fully convolutional one-stage object detector (FCOS), called spatial pyramid pooling-fast (SPPF) feature fusion and dual detection heads based on FCOS (SDH-FCOS) model. This study improved the feature fusion component of the model network based on FCOS, introduced an SPPF network structure behind the last output feature layer of the… More >

  • Open Access

    ARTICLE

    Two-Stage Optimal Scheduling of Community Integrated Energy System

    Ming Li1,*, Rifucairen Fu1, Tuerhong Yaxiaer1, Yunping Zheng1, Abiao Huang2, Ronghui Liu2, Shunfu Lin2

    Energy Engineering, Vol.121, No.2, pp. 405-424, 2024, DOI:10.32604/ee.2023.044509

    Abstract From the perspective of a community energy operator, a two-stage optimal scheduling model of a community integrated energy system is proposed by integrating information on controllable loads. The day-ahead scheduling analyzes whether various controllable loads participate in the optimization and investigates the impact of their responses on the operating economy of the community integrated energy system (IES) before and after; the intra-day scheduling proposes a two-stage rolling optimization model based on the day-ahead scheduling scheme, taking into account the fluctuation of wind turbine output and load within a short period of time and according to the different response rates of… More >

  • Open Access

    ARTICLE

    An Analysis of the Dynamic Behavior of Damaged Reinforced Concrete Bridges under Moving Vehicle Loads by Using the Moving Mesh Technique

    Fabrizio Greco*, Paolo Lonetti, Arturo Pascuzzo, Giulia Sansone

    Structural Durability & Health Monitoring, Vol.17, No.6, pp. 457-483, 2023, DOI:10.32604/sdhm.2023.030075

    Abstract This work proposes a numerical investigation on the effects of damage on the structural response of Reinforced Concrete (RC) bridge structures commonly adopted in highway and railway networks. An effective three-dimensional FE-based numerical model is developed to analyze the bridge’s structural response under several damage scenarios, including the effects of moving vehicle loads. In particular, the longitudinal and transversal beams are modeled through solid finite elements, while horizontal slabs are made of shell elements. Damage phenomena are also incorporated in the numerical model according to a smeared approach consistent with Continuum Damage Mechanics (CDM). In such a context, the proposed… More >

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