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  • Open Access

    ARTICLE

    Recycling of Mud Derived from Backwash Wastewater Coagulation as Magnetic Sodalite Sphere for Zn2+Adsorption

    Suiyi Zhu1, Manhong Ji1, Hongbin Yu1,*, Zhan Qu1, Jiakuan Yang2, Mingxin Huo1, Yi Wang1

    Journal of Renewable Materials, Vol.9, No.9, pp. 1599-1607, 2021, DOI:10.32604/jrm.2021.015189 - 23 April 2021

    Abstract

    Herein, we reported a method to prepare magnetic sodalite sphere by using the mud from backwash wastewater after polyaluminum chloride (PAC) coagulation. The results showed that approximately 100% of Fe in the wastewater was precipitated as flocculent iron mud (FM) by adding PAC. FM was converted to spherical magnetic sodalite (FMP) with a diameter of 3 μm via a facile alkali hydrothermal method without adding Al/Si resources or reductant. The product FMP had the saturated magnetization of 10.9 emu g−1 and high Zn2+ adsorption capacity of 50.6 mg g−1. Without coagulation with PAC, the removal rate of

    More > Graphic Abstract

    Recycling of Mud Derived from Backwash Wastewater Coagulation as Magnetic Sodalite Sphere for Zn<sup>2+</sup>Adsorption

  • Open Access

    ARTICLE

    Preparation and Properties of Polyacrylamide/Sodium Alginate Hydrogel and the Effect of Fe3+ Adsorption on Its Mechanical Performance

    Zheng Cao1,2,3,4,*, Yang Zhang2, Keming Luo2, Yinqiu Wu2, Hongxin Gao2, Junfeng Cheng2,*, Chunlin Liu2,3, Guoliang Tao2, Qingbao Guan1, Lei Zhang5

    Journal of Renewable Materials, Vol.9, No.8, pp. 1447-1462, 2021, DOI:10.32604/jrm.2021.015593 - 08 April 2021

    Abstract

    The preparation and application of functional hydrogels based on natural polysaccharides have always been a hot research topic. In this study, using acrylamide (AM) monomer, N, N'-methylene bisacrylamide (MBA) as cross-linking agent, potassium persulfate (K2S2O8) as initiator, in the presence of natural polysaccharide sodium alginate (SA), the PAM/SA hydrogel was prepared by free radical polymerization. Fourier transform infrared spectroscopy (FT-IR), swelling performance tests, scanning electron microscope (SEM), thermogravimetric analysis (TGA), UV-visible spectrophotometer, mechanical property measurements were carried out to analyze the composition, morphology, and performance of the hydrogels. The swelling behavior, dye adsorption performance, and the

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  • Open Access

    ARTICLE

    Facile Preparation of a Porous Biochar Derived from Waste Crab Shell with High Removal Performance for Diesel

    Xiao Han1, Zhaodi Wu1, Yi Yang1, Jian Guo1, Yaning Wang2, Lu Cai3, Wendong Song4, Lili Ji2,*

    Journal of Renewable Materials, Vol.9, No.8, pp. 1377-1391, 2021, DOI:10.32604/jrm.2021.015076 - 08 April 2021

    Abstract In this study, a porous biochar material derived from waste crab shell was prepared by one-step hydrothermal carbonization and acetic acid activation method at 180°C, which was characterized by SEM, BET, XRD and FTIR. The results show that the as-prepared crab shell biochar (CSB) exhibits a fluffy irregular layered structure with abundant pores and oxygen-containing functional groups, which can facilitate the adsorption of diesel using CSB. In addition, batch adsorption experiments had been performed, effects of initial diesel concentration, adsorption time, adsorbent dosage and pH on the diesel adsorption using CSB were analyzed, which could… More >

  • Open Access

    ARTICLE

    Novel Magnetically Interconnected Micro/Macroporous Structure of Monolithic Porous Carbon Adsorbent Derived from Sodium Alginate and Wasted Black Liquor and Its Adsorption Performance**

    Parichart Onsri1, Decha Dechtrirat2,3,4, Patcharakamon Nooeaid5, Apiluck Eiad-ua6, Pongsaton Amornpitoksuk1,7, Supanna Techasakul4, Ahmad Taufiq8, Laemthong Chuenchom1,7,*

    Journal of Renewable Materials, Vol.9, No.6, pp. 1059-1074, 2021, DOI:10.32604/jrm.2021.013362 - 11 March 2021

    Abstract The novel and facile preparation of magnetically interconnected micro/ macroporous structure of monolithic porous carbon adsorbent (MPCA) were designed and presented herein. The synthesis was achieved via conventional freeze-drying and pyrolysis processes. In this study, sodium alginate and wasted black liquor were employed as starting precursors. Sodium alginate acts as a template of materials, whereas black liquor, the wasted product from the paper industry with plentiful of lignin content and alkaline solution, played an essential role in the reinforcement and activation of porosity for the resulting materials. Moreover, both the precursors were well dissolved in Fe3+More >

  • Open Access

    ARTICLE

    Removal of Cu(II), Pb(II), Mg(II), and Fe(II) by Adsorption onto Alginate/Nanocellulose Beads as Bio-Sorbent

    Ragab E. Abou-Zeid1, Korany A. Ali2, Ramadan M. A. Gawad2, Kholod H. Kamal3, Samir Kamel1, Ramzi Khiari4,5,6,*

    Journal of Renewable Materials, Vol.9, No.4, pp. 601-613, 2021, DOI:10.32604/jrm.2021.014005 - 01 February 2021

    Abstract

    Alginate blended with cellulose nanocrystals (CNC), cellulose nanofibers (CNF), and tri-carboxylate cellulose nanofibers (TPC-CNF) prepared and encapsulated in the form of microcapsules (bio-polymeric beads). The cellulosic nanomaterials that used in this study were investigated as nanomaterials for wastewater treatment applications. Batch experiments were performed to study the removal of copper, lead, magnesium, and iron from aqueous solutions by the prepared beads. The effects of the sorbent dosage and the modified polymers on the removing efficiency of the metal cations were examined. Atomic absorption was used to measure the metal ions concentrations. The modified bio-polymeric beads

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  • Open Access

    ARTICLE

    CFD SIMULATION OF BENZENE ADSORPTION ON PISTACHIO ACTIVATED CARBON POROUS MEDIA

    Maryam Mirzaiea,† , Ali Reza Talebizadeha , Hassan Hashemipoura,b

    Frontiers in Heat and Mass Transfer, Vol.14, pp. 1-7, 2020, DOI:10.5098/hmt.14.19

    Abstract In this work, a combination of computational fluid dynamics (CFD) and porous media model was applied to simulate the benzene adsorption on activated carbon and the flow fields in a porous media. The three dimensional unsteady state the gas flow was modeled by using the laminar one phase flow equations in conjunction with the mass transfer equation. The adsorption rate on solid phase was implemented to the model by a user defined source. The model was validated by comparing the simulated breakthrough curves by experimental data. After the validation of the model, the effects of More >

  • Open Access

    ARTICLE

    Theoretical Insights into the Inhibition Performance of Three Neonicotine Derivatives as Novel Type of Inhibitors on Carbon Steel

    Yun Wang1, Zhen Wang2, Lei Zhang1,*, Minxu Lu1

    Journal of Renewable Materials, Vol.8, No.7, pp. 819-932, 2020, DOI:10.32604/jrm.2020.09395 - 01 June 2020

    Abstract The adsorption process of new nicotinic derivatives on Fe (110) surface and diffusion of corrosive particles in inhibition film were studied by quantum chemistry and molecular dynamics simulation, and inhibition mechanism of inhibitor was discussed. The results indicated that the main active sites of three inhibitors are located in N atoms on the five membered ring. The inhibitor YM-1 has the strongest activity of electrophilic reaction, and the adsorption process of inhibitor molecules is polycentric chemisorption. The adsorption energy for inhibitors followed the order of YM-1 > YM-2 > YM-3. The adsorption film YM-1 more More >

  • Open Access

    ARTICLE

    Adsorption and Desorption Characteristics of Cadmium Ion by Ash-Free Biochars

    Li Fu1,2, Xianying Xu1,2,*, Guiquan Fu2, Renduo Zhang3, Hujun Liu2

    Journal of Renewable Materials, Vol.8, No.7, pp. 801-818, 2020, DOI:10.32604/jrm.2020.09369 - 01 June 2020

    Abstract The aim of this study was to investigate adsorption and desorption characteristics of cadmium ion (Cd(II)) by ash-free biochars and the adsorption mechanism. Biochars were prepared using peanut shell, bamboo, and Sophora japonica Linn. Ash-free biochars were obtained by treating the biochars with acid elution. Adsorption and desorption data from batch experiments were analyzed using the Langmuir and Freundlich models and three adsorption kinetics models (i.e., the Pseudo second-order, Elovich model, and the Intraparticle diffusion models). Results showed that the acid elution improved the pore structure of biochars, increased C content and aromatic functional group… More >

  • Open Access

    ARTICLE

    Rice Husk Bio-Chars as Adsorbent for Methylene Blue and Ethinylestradiol from Water

    Jonathan Lacuesta1,*, Iris Beatriz Vega Erramuspe2, Liji Sobhana2, Dennis Kronlund3, Jouko Peltonen3, Soledad Gutiérrez1, Pedro Fardim2,4

    Journal of Renewable Materials, Vol.8, No.3, pp. 275-287, 2020, DOI:10.32604/jrm.2020.08861 - 01 March 2020

    Abstract Biobased adsorbents are eco-friendly materials used for water and wastewater treatment and air cleaning. This research work explores the potential use of rice husk chars as a low-cost adsorbent for pollutants from water, such as methylene blue and ethinylestradiol. Rice husk chars are prepared by combustion of rice husks (RH-Char) or pre-treated rice husks (PT-Char). A third char (M-Char) supplied by a local company which uses rice husks as combustion material is also studied. The chars are characterized by field emission scanning electron microscopy (FE-SEM) in conjunction with energy dispersive X-ray spectroscopy (EDX), X-ray powder… More >

  • Open Access

    ARTICLE

    Adsorption Behavior of Reducing End-Modified Cellulose Nanocrystals: A Kinetic Study Using Quartz Crystal Microbalance

    Maud Chemin, Céline Moreau, Bernard Cathala, Ana Villares*

    Journal of Renewable Materials, Vol.8, No.1, pp. 29-43, 2020, DOI:10.32604/jrm.2020.07850 - 01 January 2020

    Abstract In this work, we studied the adsorption of modified cellulose nanocrystals onto solid surfaces by quartz crystal microbalance with dissipation monitoring (QCM-D). Cellulose nanocrystals obtained from tunicate (CNC) were modified at reducing end by amidation reactions. Two different functionalities were investigated: a polyamine dendrimer (CNC-NH2), which interacts with gold surface by the amine groups; and a biotin moiety (CNC-Biot), which has a strong affinity for the protein streptavidin (SAV). QCM-D results revealed different adsorption behaviors between modified and unmodified CNCs. Hence, unmodified CNCs covered almost all the surface forming a rigid and flat layer whereas reducing More >

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