Maryam Mirzaie^a,† , Ali Reza Talebizadeh^a , Hassan Hashemipour^a,b

Frontiers in Heat and Mass Transfer, Vol.14, pp. 1-7, 2020, DOI:10.5098/hmt.14.19

Abstract In this work, a combination of computational fluid dynamics (CFD) and porous media model was applied to simulate the benzene adsorption on activated carbon and the flow fields in a porous media. The three dimensional unsteady state the gas flow was modeled by using the laminar one phase flow equations in conjunction with the mass transfer equation. The adsorption rate on solid phase was implemented to the model by a user defined source. The model was validated by comparing the simulated breakthrough curves by experimental data. After the validation of the model, the effects of More >

Yun Wang¹, Zhen Wang², Lei Zhang^1,*, Minxu Lu¹

Journal of Renewable Materials, Vol.8, No.7, pp. 819-932, 2020, DOI:10.32604/jrm.2020.09395 - 01 June 2020

Abstract The adsorption process of new nicotinic derivatives on Fe (110) surface and diffusion of corrosive particles in inhibition film were studied by quantum chemistry and molecular dynamics simulation, and inhibition mechanism of inhibitor was discussed. The results indicated that the main active sites of three inhibitors are located in N atoms on the five membered ring. The inhibitor YM-1 has the strongest activity of electrophilic reaction, and the adsorption process of inhibitor molecules is polycentric chemisorption. The adsorption energy for inhibitors followed the order of YM-1 > YM-2 > YM-3. The adsorption film YM-1 more More >

Li Fu^1,2, Xianying Xu^1,2,*, Guiquan Fu², Renduo Zhang³, Hujun Liu²

Journal of Renewable Materials, Vol.8, No.7, pp. 801-818, 2020, DOI:10.32604/jrm.2020.09369 - 01 June 2020

Abstract The aim of this study was to investigate adsorption and desorption characteristics of cadmium ion (Cd(II)) by ash-free biochars and the adsorption mechanism. Biochars were prepared using peanut shell, bamboo, and Sophora japonica Linn. Ash-free biochars were obtained by treating the biochars with acid elution. Adsorption and desorption data from batch experiments were analyzed using the Langmuir and Freundlich models and three adsorption kinetics models (i.e., the Pseudo second-order, Elovich model, and the Intraparticle diffusion models). Results showed that the acid elution improved the pore structure of biochars, increased C content and aromatic functional group… More >

Jonathan Lacuesta^1,*, Iris Beatriz Vega Erramuspe², Liji Sobhana², Dennis Kronlund³, Jouko Peltonen³, Soledad Gutiérrez¹, Pedro Fardim^2,4

Journal of Renewable Materials, Vol.8, No.3, pp. 275-287, 2020, DOI:10.32604/jrm.2020.08861 - 01 March 2020

Abstract Biobased adsorbents are eco-friendly materials used for water and wastewater treatment and air cleaning. This research work explores the potential use of rice husk chars as a low-cost adsorbent for pollutants from water, such as methylene blue and ethinylestradiol. Rice husk chars are prepared by combustion of rice husks (RH-Char) or pre-treated rice husks (PT-Char). A third char (M-Char) supplied by a local company which uses rice husks as combustion material is also studied. The chars are characterized by field emission scanning electron microscopy (FE-SEM) in conjunction with energy dispersive X-ray spectroscopy (EDX), X-ray powder… More >

Maud Chemin, Céline Moreau, Bernard Cathala, Ana Villares^*

Journal of Renewable Materials, Vol.8, No.1, pp. 29-43, 2020, DOI:10.32604/jrm.2020.07850 - 01 January 2020

Abstract In this work, we studied the adsorption of modified cellulose nanocrystals onto solid surfaces by quartz crystal microbalance with dissipation monitoring (QCM-D). Cellulose nanocrystals obtained from tunicate (CNC) were modified at reducing end by amidation reactions. Two different functionalities were investigated: a polyamine dendrimer (CNC-NH₂), which interacts with gold surface by the amine groups; and a biotin moiety (CNC-Biot), which has a strong affinity for the protein streptavidin (SAV). QCM-D results revealed different adsorption behaviors between modified and unmodified CNCs. Hence, unmodified CNCs covered almost all the surface forming a rigid and flat layer whereas reducing More >

AYÇA BAL ÖZTÜRK^1,2,*, ZEHRA ÖZBA޳, BENGİ ÖZKAHRAMAN⁴, SERKAN EMİK⁵

Journal of Polymer Materials, Vol.36, No.2, pp. 161-173, 2019, DOI:10.32381/JPM.2019.36.02.5

Abstract A functionalized hydrogel composed of 2-(hydroxyethyl) methacrylate (HEMA) and acrylamide (AAm) was synthesized by amination and saponification reactions, respectively, and its functionality was examined for the elimination of copper(II) ions. The maximum adsorption capacity for copper(II) ions was 0.617 mmol g^-1 before saponification, whereas it was 1.2225 mmol g^-1 after saponification. The adsorption data was analyzed with pseudo-first-order (r² =0.8867), intra-particle diffusion (r² =0.9453), Elovich (r²=0.9489) and pseudo-secondorder(r² =0.9999) kinetic models. Based on the adsorption equilibrium experimental data Freundlich(r² =0.9964), Langmuir(r²=0.998) and Dubinin–Radushkevich (D-R) (r² =0.9960) adsorption isotherms provided good fits for all of experimental results. Finally, the datas of More >

VIJAYASRI. K¹, ALKA TIWARI^1,*, C.V. CHAUDHARI²

Journal of Polymer Materials, Vol.36, No.1, pp. 53-73, 2019, DOI:10.32381/JPM.2019.36.01.5

Abstract High energy gamma radiation has been used to graft [2-(methacryloyloxyethyl) trimethylammonium chloride (MAETC) onto chitosan by radiation grafting method. Grafting yield was found to increase with the increase in radiation dose and monomer concentration. Fourier Transform Infrared Spectroscopy (FTIR) was used to characterize the grafted polymer and their morphological structure was analyzed by Scanning Electron Microscope (SEM). As(V) ions uptake capacity of the adsorbent was evaluated in different pH, contact time, temperature, adsorbent dose, and different arsenate ion concentration. The adsorption data was fitted well in the Langmuir model and various static parameters were calculated. More >

Yongbin Zhang^*

Frontiers in Heat and Mass Transfer, Vol.13, pp. 1-4, 2019, DOI:10.5098/hmt.13.22

Abstract The power loss is calculated by a multiscale approach in the pressure driven mass transfer in a micro slit pore where there are the physical adsorbed layers respectively on the coupled walls and intermediate between them is a continuum fluid flow. The flow factor approach model for nanoscale flow is taken to simulate the flow of the adsorbed layer, and conventional hydrodynamic flow theory models the continuum fluid flow. The calculation shows that the adsorbed layer on the wall surface can have a very significant effect on the power loss in this multiscale mass transfer, More >

Ying Lin¹, Yihua Cao¹, Qingping Song¹, Jiangang Gao¹, Puyou Jia^2，*, Hamed Alsulami³, Marwan Amin Kutbi³

Journal of Renewable Materials, Vol.7, No.12, pp. 1403-1414, 2019, DOI:10.32604/jrm.2019.08380

Abstract Biocompatible and high content grafted carboxymethyl cellulose-gpoly(acrylic acid) powder was successfully synthesized in an aqueous system, and used as adsorbents for the removal of Cu(II) in aqueous solution. The copolymer was characterized by FT-IR and SEM techniques. Graft copolymerization introduced a large number of carboxyl groups in the polymer and caused the micro-surface of the material to be porous. The fundamental adsorption behaviors of the material were studied. The adsorption kinetics was well fitted with pseudo-second order equation, while the adsorption isotherm preferred to be described the Langmuir equation. The maximum adsorption capacity obtained from More >

Yan Wu^1,*, Xinyu Wu¹, Feng Yang^2,*, Li Xu¹, Meng Sun¹

Journal of Renewable Materials, Vol.7, No.11, pp. 1181-1195, 2019, DOI:10.32604/jrm.2019.07493

Abstract The cellulose nanocrystals/graphene composite aerogel (CGA) and polyvinyl alcohol/cellulose nanocrystals/graphene composite aerogel (PCGA) were prepared by suspension titration, tert-butanol solution replacement and freeze-drying successively. The removal rates of methyl blue (MB) from water by CGA and PCGA were evaluated and the effects of additions, adsorption time, reaction temperature and pH value of CGA and PCGA on MB removal rate were discussed. It was found that the optimal concentrations of both CGA and PCGA were 2 g∙L-1 in the adsorption reaction process and the adsorption equilibrium was reached within 120 min. The higher the initial pH More >