AYÇA BAL ÖZTÜRK^1,2,*, ZEHRA ÖZBA޳, BENGİ ÖZKAHRAMAN⁴, SERKAN EMİK⁵

Journal of Polymer Materials, Vol.36, No.2, pp. 161-173, 2019, DOI:10.32381/JPM.2019.36.02.5

Abstract A functionalized hydrogel composed of 2-(hydroxyethyl) methacrylate (HEMA) and acrylamide (AAm) was synthesized by amination and saponification reactions, respectively, and its functionality was examined for the elimination of copper(II) ions. The maximum adsorption capacity for copper(II) ions was 0.617 mmol g^-1 before saponification, whereas it was 1.2225 mmol g^-1 after saponification. The adsorption data was analyzed with pseudo-first-order (r² =0.8867), intra-particle diffusion (r² =0.9453), Elovich (r²=0.9489) and pseudo-secondorder(r² =0.9999) kinetic models. Based on the adsorption equilibrium experimental data Freundlich(r² =0.9964), Langmuir(r²=0.998) and Dubinin–Radushkevich (D-R) (r² =0.9960) adsorption isotherms provided good fits for all of experimental results. Finally, the datas of More >

VIJAYASRI. K¹, ALKA TIWARI^1,*, C.V. CHAUDHARI²

Journal of Polymer Materials, Vol.36, No.1, pp. 53-73, 2019, DOI:10.32381/JPM.2019.36.01.5

Abstract High energy gamma radiation has been used to graft [2-(methacryloyloxyethyl) trimethylammonium chloride (MAETC) onto chitosan by radiation grafting method. Grafting yield was found to increase with the increase in radiation dose and monomer concentration. Fourier Transform Infrared Spectroscopy (FTIR) was used to characterize the grafted polymer and their morphological structure was analyzed by Scanning Electron Microscope (SEM). As(V) ions uptake capacity of the adsorbent was evaluated in different pH, contact time, temperature, adsorbent dose, and different arsenate ion concentration. The adsorption data was fitted well in the Langmuir model and various static parameters were calculated. More >

Yongbin Zhang^*

Frontiers in Heat and Mass Transfer, Vol.13, pp. 1-4, 2019, DOI:10.5098/hmt.13.22

Abstract The power loss is calculated by a multiscale approach in the pressure driven mass transfer in a micro slit pore where there are the physical adsorbed layers respectively on the coupled walls and intermediate between them is a continuum fluid flow. The flow factor approach model for nanoscale flow is taken to simulate the flow of the adsorbed layer, and conventional hydrodynamic flow theory models the continuum fluid flow. The calculation shows that the adsorbed layer on the wall surface can have a very significant effect on the power loss in this multiscale mass transfer, More >

Ying Lin¹, Yihua Cao¹, Qingping Song¹, Jiangang Gao¹, Puyou Jia^2，*, Hamed Alsulami³, Marwan Amin Kutbi³

Journal of Renewable Materials, Vol.7, No.12, pp. 1403-1414, 2019, DOI:10.32604/jrm.2019.08380

Abstract Biocompatible and high content grafted carboxymethyl cellulose-gpoly(acrylic acid) powder was successfully synthesized in an aqueous system, and used as adsorbents for the removal of Cu(II) in aqueous solution. The copolymer was characterized by FT-IR and SEM techniques. Graft copolymerization introduced a large number of carboxyl groups in the polymer and caused the micro-surface of the material to be porous. The fundamental adsorption behaviors of the material were studied. The adsorption kinetics was well fitted with pseudo-second order equation, while the adsorption isotherm preferred to be described the Langmuir equation. The maximum adsorption capacity obtained from More >

Yan Wu^1,*, Xinyu Wu¹, Feng Yang^2,*, Li Xu¹, Meng Sun¹

Journal of Renewable Materials, Vol.7, No.11, pp. 1181-1195, 2019, DOI:10.32604/jrm.2019.07493

Abstract The cellulose nanocrystals/graphene composite aerogel (CGA) and polyvinyl alcohol/cellulose nanocrystals/graphene composite aerogel (PCGA) were prepared by suspension titration, tert-butanol solution replacement and freeze-drying successively. The removal rates of methyl blue (MB) from water by CGA and PCGA were evaluated and the effects of additions, adsorption time, reaction temperature and pH value of CGA and PCGA on MB removal rate were discussed. It was found that the optimal concentrations of both CGA and PCGA were 2 g∙L-1 in the adsorption reaction process and the adsorption equilibrium was reached within 120 min. The higher the initial pH More >

Xiaoyu Chen*, Jie Zhu

Journal of Renewable Materials, Vol.7, No.10, pp. 983-996, 2019, DOI:10.32604/jrm.2019.07325

Abstract With the rapid development of textile industry, a large amount of dye-contaminated effluents was produced and caused serious environmental problem. To remove the dye from effluents, adsorption materials have been applied because of their relatively cheap, high efficiency, and easy handling. In this study, a novel composite hydrogel bead with unique multilayer flake structure was fabricated by alginate, acrylamide and attapulgite for dye adsorption. Acrylamide was grafted polymerization onto alginate to obtain alginate-g-poly(acrylamide). Then alginate-g-poly(acrylamide) was cross-linked by Ca²⁺ ions in present of attapulgite to form composite hydrogel bead. Scanning electron microscopy (SEM) results show that… More >

Abdelkrim Trabelsi^1,*, Zakaria Slimani¹, Akli Younsi², Joseph Virgone¹, Rafik Belarbi²

Journal of Renewable Materials, Vol.7, No.6, pp. 547-556, 2019, DOI:10.32604/jrm.2019.04426

Abstract Water adsorption and capillarity are key phenomena involved during heat and moisture transfer in porous building materials. They account for interaction between solid matrix, liquid water and moist air. They are considered through Water Vapor Adsorption Isotherm (WVAI) and Retention Curve (RC) functions which are constitutive laws characterizing water activity within a porous medium. The objective of this paper is to present a water vapor adsorption and retention models built from multimodal Pore Size Distribution Function (PSDF) and to see how its parameters modify moisture storage for hygroscopic and near saturation ranges. The microstructure of… More >

Lídia K. Lazzari^*, Vitória B. Zampieri, Ademir J. Zattera, Camila Baldasso

Journal of Renewable Materials, Vol.7, No.3, pp. 227-234, 2019, DOI:10.32604/jrm.2019.00024

Abstract This work aimed at analyzing the petroleum adsorption capacity and the compressive strength of cellulose cryogels produced with the addition of 4 and 8% (w/w) sodium hydroxide (NaOH). Cryogels were produced from a 1.5% (m/m) suspension of cellulose microfibers, which originated from Pinus elliotti, in distilled water. The addition of NaOH increased the compression strength of cryogel by 30% when compared to cryogel without the reagent. Due to the 50% decrease in volume, the cryogel FLNB-8h (8% NaOH) has its petroleum adsorption capacity decreased in average by 58%, whereas the FLNB-4 (4% NaOH) cryogel had More >

Yi Xue^1,2,*, Faning Dang², Rongjian Li², Fei Liu³

CMES-Computer Modeling in Engineering & Sciences, Vol.115, No.3, pp. 345-358, 2018, DOI:10.3970/cmes.2018.08052

Abstract Adsorption deformation significantly affects the seepage characteristics of coal. However, effect of sorption time on coal permeability and gas pressure has not been investigated systematically. In this study, the sorption experiment of coal samples is conducted to elaborate the importance of sorption equilibration time. Then a coupled coal deformation and gas flow model is established considering the sorption characteristic and permeability evolution. This coupled model is implemented through finite element method to analyze the effect of sorption time on coal permeability and gas pressure. The simulation results reveal that the gas pressure of the coal More >

Yasemin Kaptan, M.Sc.^1,*, Yüksel Avcıbaşı-Güvenilir¹

Journal of Renewable Materials, Vol.6, No.6, pp. 619-629, 2018, DOI:10.32604/JRM.2018.00142

Abstract Surface-modified rice husk ash was used as an inorganic support material for immobilization of Candida antarctica lipase B. (3-aminopropyl) trimethoxysilane was used for surface modification. Immobilization of CALB was performed via both physical adsorption and cross-linking. PCL synthesis was carried out by using these immobilized enzymes, free enzyme and Novozyme 435®. Molecular weight distribution of polymer samples was obtained by gel permeation chromatography (GPC) and chain structures of the polymer samples were observed by hydrogen nuclear magnetic resonance (1H-NMR). The highest monomer conversion is generally obtained by using cross-linked enzyme, around 90%. PDI values for More >