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  • Open Access

    ARTICLE

    Synthesis and Characterization of Phenyl Camellia oleifera Seed Oil Ester Plasticizing PVC

    Wenqing Xiao1,#, Yuhang Liu2,#, Yuxin He1, Qiaoguang Li1,*, Yongquan Li3,*

    Journal of Renewable Materials, Vol.12, No.3, pp. 615-628, 2024, DOI:10.32604/jrm.2023.046780

    Abstract Plasticizers are essential additives in the processing of polyvinyl chloride (PVC), with phthalate plasticizers being widely used. However, these conventional plasticizers have been shown to be harmful to human health and environmentally unfriendly, necessitating the exploration of eco-friendly bio-based alternatives. In this study, Camellia oleifera seed oil, a specialty resource in China, was utilized as a raw material and reacted with 4,4′-Methylenebis(N,N-diglycidylaniline) (AG-80) to synthesize Phenyl Camellia seed Oil Ester (PCSOE). PCSOE was employed as a plasticizer to prepare modified PVC films with varying concentrations, with the conventional plasticizer dioctyl phthalate (DOP) serving as a control. Experimental results demonstrate that… More >

  • Open Access

    ARTICLE

    An Experimental Study and Analysis of Different Dielectrics in Electrical Discharge Machining of Al 6063 Alloy

    B. MOULIPRASANTHA, P. HARIHARANB

    Journal of Polymer Materials, Vol.36, No.4, pp. 351-369, 2019, DOI:10.32381/JPM.2019.36.04.5

    Abstract Electrical discharge machining is a non-traditional machining processes in which it is based upon thermal and electrical energy source as an interval energy pulse discharge in-between the work piece and tool electrode so as to remove the material. A systematical investigation of melting and vaporising of aluminium to find the output responses such as Material removal rate (MRR), Electrode wear rate (Ra), and Surface finish (EWR) in EDM using two different dielectrics was conducted as experimental work. The working fluids are Polyethylene glycol (PEG 600) and kerosene. It is the hour of need to get the maximum MRR and surface… More >

  • Open Access

    ARTICLE

    CuBr2/Me6 TREN Mediated ARGET ATRP of Methyl acrylate in Polyethylene Glycol

    XIANRONG SHEN1,*, DENGZHOU XIA1, YIXIN XIANG1, JIANGANG GAO1

    Journal of Polymer Materials, Vol.36, No.3, pp. 229-241, 2019, DOI:10.32381/JPM.2019.36.03.3

    Abstract ARGET ATRP of methyl acrylate (MA) with low concentration of air stable-CuBr2 catalyst was successfully carried out in green solvent polyethylene glycol (PEG) without any external reducing agent.The polymerizations of MA proceeded in a well-controlled manner as evidenced by kinetic studies, chain extension results, a linear increase of the molecular weights with the increasing of monomer conversion. and narrow molecular weight distribution (Mw/Mn =1.1). Interestingly, we found that the PEG has the reduction ability to CuBr2 and could play as supplement reducing agent cooperation with Me6 TREN to mediate ARGET ATRP. Reduction of Cu(II)Br2 to Cu(I)Br by different molecular weight… More >

  • Open Access

    ARTICLE

    Plasticized Polyethylene/Chitosan Blend Films and Study of the Effect of Plasticizers on their various Properties and Biodegradabilty

    HULYA SEMA KOKER1, HÜLYA YAVUZ ERSAN1, AYSE AYTAC2,3,*

    Journal of Polymer Materials, Vol.37, No.3-4, pp. 165-177, 2020, DOI:10.32381/JPM.2020.37.3-4.4

    Abstract Chitosan (CH) and low-density polyethylene (PE) blend films were produced by a twin-screw extruder and heat press with different plasticizers glycerol (GLY), sorbitol (SOR) and polyethylene glycol (PEG). The tensile strength decreased and elongation at break increased with the incorporation of plasticizer for blends with 10 wt% of CH. The thermal stability of the films was slightly higher for films containing GLY and PEG as compared to SOR. Contact angles reduced from CH-PE film to the films containing PEG, SOR and GLY in decreasing order, respectively. Fourier transform infrared spectroscopy revealed no interactions between CH and PE in CH-PE film… More >

  • Open Access

    ARTICLE

    Preparation of Oil Shale Ash Filled High Density Polyethylene Composite Materials and their Characterization

    RAID BANAT1,*, MANAL AL-RAWASHDEH1, HEBA ALKHLAIFAT1

    Journal of Polymer Materials, Vol.38, No.1-2, pp. 137-151, 2021, DOI:10.32381/JPM.2021.38.1-2.11

    Abstract Composite of oil Shale ash (OSA) filler and high density polyethylene (HDPE) matrix was formulated and studied. OSA mainly composed of Ca, Si, and Fe most of which in oxide forms. OSA-HDPE composite with 0, 5, 10, 15, 20, and 25 wt. % OSA were produced using extrusion and hot press. Mechanical, morphological, and water uptake properties of the composite are discussed herein. While the tensile stress at yield, 47 MPa, restored its value close to the neat HDPE, an increase in the mean values of the tensile stress at rapture from 19 to 33 MPa, the tensile modulus from… More >

  • Open Access

    ARTICLE

    Investigation of Polypyrrole and Polypyrrolepolyethyleneimine as Adsorbents for Methyl Orange Dye Adsorption

    NORHABIBAH MOHAMAD1,*, NOORDINI M. SALLEH1,2, HABIBUN NABI MUHAMMAD EKRAMUL MAHMUD1

    Journal of Polymer Materials, Vol.40, No.3-4, pp. 165-189, 2023, DOI:10.32381/JPM.2023.40.3-4.4

    Abstract The present study has explored the adsorption properties of polypyrrole-based adsorbents (polypyrrole and polypyrrole-polyethyleneimine composite) as novel conducting polymers in adsorbing methyl orange (MO) (an anionic dye) effectively from aqueous solution. The adsorption characteristics of the prepared polymer-based adsorbents were characterized by BET, FTIR, FESEM, and XRD methods. The effectiveness of PPy-based adsorbents for MO dye adsorption was examined using the batch adsorption method. Different parameters were changed during the adsorption process, including contact time, solution pH, and adsorbent dosage. The highest BET surface area of the PPy-PEI composite was found to be 11.85 m2 /g, which is much greater… More >

  • Open Access

    ARTICLE

    SiRAP2-12, a Positive Regulatory Factor, Effectively Improves the Waterlogging Tolerance of Foxtail Millet (Setaria italica)

    Xueyan Xia1,#, Xiaohong Fu2,#, Yu Zhao1, Jihan Cui1, Nuoya Xiao1, Jingxin Wang1, Yiwei Lu1, Meihong Huang1, Cheng Chu1, Jia Zhang2, Mengxin Yang2, Shunguo Li1,*, Jianfeng Liu2,*

    Phyton-International Journal of Experimental Botany, Vol.93, No.3, pp. 445-465, 2024, DOI:10.32604/phyton.2024.048273

    Abstract Foxtail millet (Setaria italica) growth was inhibited because of waterlogging stress, which has caused yield reduction. ERF family plays an important role to plant adversity tolerance. In our study, we obtained 19,819 differential expressed genes (DEGs) between the two treatments based on the RNA-seq sequencing of foxtail millet of waterlogging stress. Furthermore, a total of 28 ERF family members were obtained, which have a complete open reading frame. We studied the evolution and function of SiERF family and how they affected the waterlogging tolerance. It was found that SiERF1A/B/C (GenBank ID: OR775217, OR775219, OR775218) and SiRAP2-12 (GenBank ID: OR775216) have… More >

  • Open Access

    ARTICLE

    Study of the Neutron Radiation Effect on Bi-oriented Polyethylene Naphthalate Structure

    A. BELOUADAH1, S. BERDOUS1,3, D. BERDOUS2, M. IZERROUKEN4, N. SAIDI-AMROUN1

    Journal of Polymer Materials, Vol.39, No.1-2, pp. 1-15, 2022, DOI:10.32381/JPM.2022.39.1-2.1

    Abstract In this work, neutron induced structural modifications, on the biaxially-oriented polyethylene naphthalate (BOPEN) film, were studied by X-ray diffraction technique (XRD), Fourier transform infrared spectroscopy (FTIR/ATR), scanning electron microscopy (SEM) and polarized light optical microscopy (PLOM). The irradiation with neutron was carried out, under air, at room temperature. The changes of the structure, in volume and in surface were evaluated under the impact of neutron’s flux composed by thermally neutrons and fast neutrons. The X-ray technique showed the effect of the neutron flux’s fluence on the crystallinity of the BOPEN, which was also determined through the FTIR/ATR spectroscopy, traduced by… More >

  • Open Access

    ARTICLE

    Interface and Friction Properties of Copper-embedded Polyethylene Terephthalate Filament

    FOUED KHOFFI1,*, OMAR HARZALLAH2, JEAN YVES DREAN2

    Journal of Polymer Materials, Vol.40, No.1-2, pp. 59-69, 2023, DOI:10.32381/JPM.2023.40.1-2.5

    Abstract The aim of this study is to analyze the interfacial and the frictional properties of copper (Cu) reinforced polyethylene terephthalate (PET) filament. This Cu-Embedded PET filament will be used as an information transmitter. This filament was prepared by a co-extrusion process. Mechanical properties of these filaments have been quantified by tensile and pull-out analyses. It is shown that the mechanical properties of composite filament were improved by adding the copper filament (from 0.82 to 1.2 GPa). The results of the pull-out test revealed some adhesion between the copper and the PET despite the existence of a slippage of the copper… More >

  • Open Access

    ARTICLE

    Preparation of Environmentally Friendly Urea-Hexanediamine-Glyoxal (HUG) Resin Wood Adhesive

    Qianyu Zhang1,2,#, Shi Chen1,2,#, Long Cao1,2, Hong Lei3, Antonio Pizzi4, Xuedong Xi1,2,*, Guanben Du1,2

    Journal of Renewable Materials, Vol.12, No.2, pp. 235-244, 2024, DOI:10.32604/jrm.2023.029537

    Abstract Using non-toxic, low-volatile glyoxal to completely replace formaldehyde for preparing urea-glyoxal (UG) resin adhesive is a hot research topic that could be of great interest for the wood industry. However, urea-glyoxal (UG) resins prepared by just using glyoxal instead of formaldehyde usually yields a lower degree of polymerization. This results in a poorer bonding performance and water resistance of UG resins. A good solution is to pre-react urea to preform polyurea molecules presenting already a certain degree of polymerization, and then to condense these with glyoxal to obtain a novel UG resin. Therefore, in this present work, the urea was… More > Graphic Abstract

    Preparation of Environmentally Friendly Urea-Hexanediamine-Glyoxal (HUG) Resin Wood Adhesive

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