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  • Open Access

    ARTICLE

    The Application of Cellulose Nanocrystals Modified with Succinic Anhydride under the Microwave Irradiation for Preparation of Polylactic Acid Nanocomposites

    Ewa Szefer*, Agnieszka Leszczyńska, Edyta Hebda, Krzysztof Pielichowski

    Journal of Renewable Materials, Vol.9, No.6, pp. 1127-1142, 2021, DOI:10.32604/jrm.2021.014584 - 11 March 2021

    Abstract The aim of this work was to use cellulose nanocrystals that were obtained by hydrolysis in phosphoric acid solution and further modified with succinic anhydride in the microwave field for PLA reinforcement. A series of all-bionanocomposites containing unmodified and surface modified cellulose nanocrystals with CNC content in the range of 1–3 %w.t. were obtained by melt blending and tested by XRD, SEM, DSC and DMA to investigate the effect of surface esterification of CNCs on the structure, morphology, dynamic mechanical properties of bionanocomposites, as well as phase transitions of PLA in the presence of cellulosic nanofiller. More > Graphic Abstract

    The Application of Cellulose Nanocrystals Modified with Succinic Anhydride under the Microwave Irradiation for Preparation of Polylactic Acid Nanocomposites

  • Open Access

    ARTICLE

    Dissolution and Degradation of Spent Radioactive Cation Exchange Resin by Fenton Oxidation Combining Microwave

    Jiangbo Li1,2, Lielin Wang1,2,*, Hua Xie1,2, Xiaoyu Li1,2, Zhiqiang Feng1,2, Wenxiu Zhang1,2

    Energy Engineering, Vol.117, No.3, pp. 129-142, 2020, DOI:10.32604/EE.2020.010336 - 10 July 2020

    Abstract This study introduced a significantly effective approach called the microwave-enhanced Fenton method to degrade spent radioactive cation exchange resin. Compared with the Fenton (99% after 180 min) and photo-Fenton (90% after 198 min) reactions, this unique microwave-enhanced Fenton reaction has the highest degradation rate for spent radioactive cation exchange resin degradation (98.55% after 60 min). Carbon dioxide, sulfate and small molecular compounds were produced in the degradation of cation exchange resin, as determined by XRD and FT-IR. A model for the microwave-enhanced Fenton degradation mechanism of cation exchange resin was constructed. Microwaves were implemented to More >

  • Open Access

    ARTICLE

    Physicochemical Characterization and Antimicrobial Properties of Inulin Acetate Obtained by Microwave-Assisted Synthesis

    Nadezhda Petkova1,*, Radka Arabadzhieva1, Dragomir Vassilev2, Gergana Gencheva1, Yulian Tumbarski3, Tsveteslava Ignatova-Ivanova4, Sevginar Ibryamova4, Mina Todorova1, Milena Koleva2, Panteley Denev1

    Journal of Renewable Materials, Vol.8, No.4, pp. 365-381, 2020, DOI:10.32604/jrm.2020.09292 - 24 April 2020

    Abstract Microwave-assisted irradiation was performed for esterification of chicory inulin with high degree of polymerization with acetic anhydride without a solvent only with a catalyst. The resulting esters were characterized by melting point, hydrophilic-lipophilic balance, thin-layer chromatography, ultraviolet spectroscopy, Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR) spectroscopy. Inulin acetate demonstrated a high degree of acetylation (2.5–3.0) and presented a white, water-insoluble substance with bitter taste. The FTIR and NMR spectra confirmed esterification and demonstrated the incorporation of hydrophobic residue to the water soluble inulin backbone. Swelling capacity, water holding, oil-holding capacities, the foamability,… More >

  • Open Access

    ARTICLE

    Development of Functional Adsorbent from Natural Biosorbent “Chitosan” by Radiation Induced Grafting of MAETC for the Removal of Arsenic (V)

    VIJAYASRI. K1, ALKA TIWARI1,*, C.V. CHAUDHARI2

    Journal of Polymer Materials, Vol.36, No.1, pp. 53-73, 2019, DOI:10.32381/JPM.2019.36.01.5

    Abstract High energy gamma radiation has been used to graft [2-(methacryloyloxyethyl) trimethylammonium chloride (MAETC) onto chitosan by radiation grafting method. Grafting yield was found to increase with the increase in radiation dose and monomer concentration. Fourier Transform Infrared Spectroscopy (FTIR) was used to characterize the grafted polymer and their morphological structure was analyzed by Scanning Electron Microscope (SEM). As(V) ions uptake capacity of the adsorbent was evaluated in different pH, contact time, temperature, adsorbent dose, and different arsenate ion concentration. The adsorption data was fitted well in the Langmuir model and various static parameters were calculated. More >

  • Open Access

    ARTICLE

    SURROGATE-BASED OPTIMIZATION OF THERMAL DAMAGE TO LIVING BIOLOGICAL TISSUES BY LASER IRRADIATION

    Nazia Afrina , Yuwen Zhangb,*

    Frontiers in Heat and Mass Transfer, Vol.12, pp. 1-6, 2019, DOI:10.5098/hmt.12.27

    Abstract The surrogate-based analysis and optimization of thermal damage in living biological tissue by laser irradiation are discussed in this paper. Latin Hypercube Sampling (LHS) and Response Surface Model (RSM) are applied to study the surrogate-based optimization of thermal damage in tissue using a generalized dual-phase lag model. Response value of high temperature as a function of input variables and the relationship of maximum temperature and thermal damage as a function of input variables are investigated. Comparisons of SBO model and simulation results for different sample sizes are examined. The results show that every input variable More >

  • Open Access

    ARTICLE

    The Effects of Gamma Irradiation on Molecular Weight, Morphology and Physical Properties of PHBV/Cloisite 30B Bionanocomposites

    Kahina Iggui1,2,*, Mustapha Kaci1, Mohamed Mahlous3, Nicolas Le Moigne4, Anne Bergeret4

    Journal of Renewable Materials, Vol.7, No.9, pp. 807-820, 2019, DOI:10.32604/jrm.2019.06778

    Abstract In this paper, the effects of gamma irradiation on Cast poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) and PHBV/Cloisite 30B (C30B) (3 wt%) bionanocomposite prepared by melt compounding, were evaluated at various doses, i.e., 5, 15, 20, 50 and 100 kGy at room temperature in air. Changes in molecular weight, morphology and physical properties were investigated. The study showed that the main degradation mechanism occurring in gamma irradiation in both Cast PHBV and C-PHBV/3C30B bionanocomposite is chain scission, responsible for the decrease of molecular weight. Differential scanning calorimetry (DSC) data indicated a regular decrease in crystallization temperature, melting temperature and… More >

  • Open Access

    ARTICLE

    Modeling and Analysis of Global and Diffuse Solar Irradiation Components Using the Satellite Estimation Method of HELIOSAT

    Selmin Ener Rusen1

    CMES-Computer Modeling in Engineering & Sciences, Vol.115, No.3, pp. 327-343, 2018, DOI:10.3970/cmes.2018.00159

    Abstract It is very important to determine the daily horizontal global, diffuse and beam irradiations correctly in planning energy systems, in cost analysis, in the atmosphere, and in the productivity evaluations. Besides, the knowledge of accurate solar irradiation is the most important component of the essential climate variables according to the Global Climate Observing System (GCOS) in August 2010. It is known that the changes of these irradiation parameters directly affect our atmosphere and cloud formation processes. Turkey is one of the countries, which has high solar energy potential by reason of its climatic and regional… More >

  • Open Access

    ARTICLE

    Microwave-Assisted Isolation and Acetylation of Inulin from Helianthus Tuberosus L Tubers

    Nadezhda Petkova1,*, Gergana Gencheva1, Dragomir Vassilev2, Milena Koleva2, Albert Krastanov3, Panteley Denev1

    Journal of Renewable Materials, Vol.6, No.7, pp. 671-679, 2018, DOI:10.32604/JRM.2018.00001

    Abstract Jerusalem artichoke (Helianthus tuberosus L.) tubers are industrial crop considered as a promising source for inulin production. “Green” method was performed for accelerated inulin extraction from Helianthus tuberosus L. tubers by the application of microwave irradiation. Further pretreatment of the water extract with acetone and ethanol yielded inulin (20%) with purity 89% and degree of polymerization 18. Jerusalem artichoke inulin was characterized by FTIR and NMR spectroscopy. For the first time eco-friendly synthesis of acetylated Jerusalem artichoke inulin was performed by the reaction with acetic anhydride, without toxic solvent, but only with sodium acetate as More >

  • Open Access

    ARTICLE

    Gamma Irradiation Upregulates B-cell Translocation Gene 2 to Attenuate Cell Proliferation of Lung Cancer Cells Through the JNK and NF-κB Pathways

    Peihe Wang*, Yuanyuan Cai*, Dongju Lin, Yingxiao Jiang*

    Oncology Research, Vol.25, No.7, pp. 1199-1205, 2017, DOI:10.3727/096504017X14873444858101

    Abstract Gamma ray can promote cancer cell apoptosis and cell cycle arrest. It is often used in the clinical treatment of tumors, including lung cancer. In this study, we aimed to explore the role of gamma ray treatment and its correlation with BTG2 in cell proliferation, apoptosis, and cell cycle arrest regulation in a lung cancer cell line. A549 cell viability, apoptosis rate, and cell cycle were investigated after gamma ray treatment. We then used siRNA for BTG2 to detect the effect of BTG2 knockdown on the progress of gamma ray-treated lung cancer cells. Finally, we… More >

  • Open Access

    ARTICLE

    Conductive Polymer Composites Synthesized from Diacetylene-Functionalized Linseed Oil and MWCNT: Gamma Irradiation and Organic Vapor Sensing

    A. Ramírez-Jiménez1*, S. Hernández López1, E. Bucio2, E. Vigueras Santiago1

    Journal of Renewable Materials, Vol.5, No.2, pp. 132-144, 2017, DOI:10.7569/JRM.2016.634138

    Abstract Epoxidized linseed oil (ELO) was synthesized and functionalized with propargylamine (PA) or 3-ethynylaniline (EA) and the products were crosslinked to obtain the diacetylene-functionalized epoxidized linseed oil polymers which were used as matrices in the preparation of the composites with multiwalled carbon nanotubes (MWCNTs). Electrical resistance at percentages between 4 and 20 wt/wt% of filler was measured and the percolation threshold was calculated, obtaining 1.2 and 1.7% for the composites with EA and PA respectively. Low critical concentration evidenced a good dispersion of the MWCNTs without necessity of any modification. The final products were used in More >

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