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  • Open Access

    ARTICLE

    Effects of PEG200 on the Properties and Performance of PVDF Membranes in the Separation of MethanolWater Mixtures by Pervaporation

    DIPESHKUMAR D. KACHHADIYA, Z.V.P. MURTHY*

    Journal of Polymer Materials, Vol.38, No.1-2, pp. 49-61, 2021, DOI:10.32381/JPM.2021.38.1-2.5

    Abstract The conventional process for methanol-water separation like distillation consumes about 60 % of total energy. As an alternative, researchers have developed a membrane-based separation process for alcohol-water mixtures separation. However, there is a big challenge for researches to separate alcohol-water aqueous mixtures using a polymeric membrane because of swelling. In the present work, the aim is to separate methanol from water by pervaporation using polymeric membranes made up of polyvinylidenefluroide (PVDF) and polyethylene glycol (PEG200) modified PVDF membranes. The membranes were characterized by thermogravimetry analysis (TGA), field emission scanning electron microscopy (FE-SEM), and Fourier-transform infrared spectroscopy (FTIR). A study on… More >

  • Open Access

    ARTICLE

    Growth of Non-enzymatic Cholesterol Biosensor using TiO2 Decorated Graphene Oxide with Bare GCE and PPy-GCE

    S. DEIVANAYAKI1,*, P. JAYAMURUGAN2, S. ASHOKAN3, V. GOPALA KRISHNAN4, B. YOGESWARI5

    Journal of Polymer Materials, Vol.38, No.3-4, pp. 295-307, 2021, DOI:10.32381/JPM.2021.38.3-4.10

    Abstract The cholesterol level determination is a significant clinical diagnostic solution for heart and, thrombosis problems. In this work, we examined a novel non-enzymatic cholesterol biosensor using cholesterol oxidase (ChOx) enzyme immobilized on TiO2 nanoparticles influenced by reduced graphene oxide (rGO) - polypyrrole (PPy) (rGO-TiO2 /PPy-GCE) nanocomposite was developed on a glassy carbon electrode (GCE) and the higher sensing response with lower detection limits were observed. The electrochemical properties of GCE modified PPy (PPy-GCE) were studied using CV (Cyclic Voltammetry) and DPV (Differential Pulse Voltammetry). The reported sensor exhibited piecewise linearity in the range of 0.1 µM to 1 µM and… More >

  • Open Access

    ARTICLE

    Development of Chitosan-based Films Containing Hypericum perforatum L. and Citrus limon L. as Potential Wound Dressing Materials

    DENIZ AKIN SAHBAZ1,*, BETUL TURP KAYA2

    Journal of Polymer Materials, Vol.38, No.3-4, pp. 247-256, 2021, DOI:10.32381/JPM.2021.38.3-4.6

    Abstract The objective of this study is to develop chitosan-based films containing Hypericum perforatum L. and/or Citrus limon L. oils and to investigate their suitability as novel wound dressing materials. The morphology of the chitosan-based films were observed by means of employing the scanning electron microscopy (SEM) and the chemical structure characterization was performed via Fourier Transform Infrared Spectroscopy (FTIR). Hypericum perforatum L. and/or Citrus limon L. were successfully incorporated to the chitosan films. Antibacterial, swelling, and mechanical properties of these films were investigated. The antibacterial property was enhanced by incorporating Hypericum perforatum L. and Citrus limon L. oils in the… More >

  • Open Access

    ARTICLE

    Investigation of Polypyrrole and Polypyrrolepolyethyleneimine as Adsorbents for Methyl Orange Dye Adsorption

    NORHABIBAH MOHAMAD1,*, NOORDINI M. SALLEH1,2, HABIBUN NABI MUHAMMAD EKRAMUL MAHMUD1

    Journal of Polymer Materials, Vol.40, No.3-4, pp. 165-189, 2023, DOI:10.32381/JPM.2023.40.3-4.4

    Abstract The present study has explored the adsorption properties of polypyrrole-based adsorbents (polypyrrole and polypyrrole-polyethyleneimine composite) as novel conducting polymers in adsorbing methyl orange (MO) (an anionic dye) effectively from aqueous solution. The adsorption characteristics of the prepared polymer-based adsorbents were characterized by BET, FTIR, FESEM, and XRD methods. The effectiveness of PPy-based adsorbents for MO dye adsorption was examined using the batch adsorption method. Different parameters were changed during the adsorption process, including contact time, solution pH, and adsorbent dosage. The highest BET surface area of the PPy-PEI composite was found to be 11.85 m2 /g, which is much greater… More >

  • Open Access

    ARTICLE

    Genome-Wide Exploration of the Grape GLR Gene Family and Differential Responses of VvGLR3.1 and VvGLR3.2 to Low Temperature and Salt Stress

    Honghui Sun1,2,#, Ruichao Liu1,2,#, Yueting Qi1, Hongsheng Gao1, Xueting Wang1, Ning Jiang1,2, Xiaotong Guo1,2, Hongxia Zhang1, Chunyan Yu1,2,*

    Phyton-International Journal of Experimental Botany, Vol.93, No.3, pp. 533-549, 2024, DOI:10.32604/phyton.2024.049417

    Abstract Grapes, one of the oldest tree species globally, are rich in vitamins. However, environmental conditions such as low temperature and soil salinization significantly affect grape yield and quality. The glutamate receptor (GLR) family, comprising highly conserved ligand-gated ion channels, regulates plant growth and development in response to stress. In this study, 11 members of the VvGLR gene family in grapes were identified using whole-genome sequence analysis. Bioinformatic methods were employed to analyze the basic physical and chemical properties, phylogenetic trees, conserved domains, motifs, expression patterns, and evolutionary relationships. Phylogenetic and collinear analyses revealed that the VvGLRs were divided into three… More >

  • Open Access

    ARTICLE

    Effects of Flowering Mode and Pollinator Sharing on Reproductive Success in Natural Hybrid of Two Epimedium (Berberidaceae) Species

    Lanying Chen1,2, Qiumei Quan3,*, Yunxiang Li3

    Phyton-International Journal of Experimental Botany, Vol.93, No.3, pp. 551-566, 2024, DOI:10.32604/phyton.2024.048103

    Abstract Mediated by pollen flow, natural hybridization is deemed a crucial factor that propels speciation in floral plants. Despite the fact that the diversity of Epimedium species is concentrated mainly in Southwestern China, the potential impact of interspecific pollination on natural hybridization has yet to be empirically scrutinized. To explore this, we studied the flowering period and the visitors of flowers in three frequently overlapping Epimedium species at Jinchengshan National Forest Park, located in Nanchong, Sichuan Province. Additionally, we performed a series of pollination experiments to examine breeding systems and hybrid compatibility. Morphologically, Epimedium pubescens and Epimedium wushanense are clearly distinct… More >

  • Open Access

    ARTICLE

    Effect of Sulfuric Acid on the Physiochemical Properties of Chitosan-PVA Blend for Direct Methanol Fuel Cell

    RABIRANJAN MURMUa,b, DEBASHIS ROYa, HAREKRUSHNA SUTARb, PRAGYAN SENAPATIc, SWETAK ABHISEK MOHAPATRAb

    Journal of Polymer Materials, Vol.39, No.1-2, pp. 89-109, 2022, DOI:10.32381/JPM.2022.39.1-2.6

    Abstract In this work, we have successfully cross-linked the different weight ratio of Chitosan-PVA blend with sulfuric acid. The effect of cross-linker on the properties of blends are studied by using different experimental technique. The cross-linked membrane provides higher ion exchange capacity due to the procurement of extra ionic hooping sites in the membrane. The compatibility of the blends are confirmed from the FTIR and DSC analysis. The crosslinking reaction fastening the phase transition behavior of the blends which reduces the glass transition temperature. The highly compatiblized cross-linked blend provides higher tensile strength and lower modulus at moderate temperature. The significant… More >

  • Open Access

    ARTICLE

    Study of Galvanic Charging-Discharging Properties of Graphene Nanoplatelets Incorporated Epoxy-Carbon Fabric Composites

    HADIMANI SHIVAKUMAR1, GURUMURTHY G. D.1, BOMMEGOWDA K. B.2, S. PARAMESHWARA3

    Journal of Polymer Materials, Vol.40, No.1-2, pp. 93-103, 2023, DOI:10.32381/JPM.2023.40.1-2.8

    Abstract Polymer composites are increasing in demand in energy storage applications including in the electronic as well as electrical industries due to the ease of processing of these materials with associated advantages like light weight, corrosion resistance, and high mechanical strength. In this investigation, efforts are made to enhance the charging and discharging properties of epoxy/carbon fabric composite by the addition of graphene nanoplatelets (GNPs) into the epoxy/ carbon matrix. The performance of the composites with graphene platelets of 0.5 to 5 wt. % in epoxy were characterized and 1wt.% percolation threshold was observed poor performance in gravimetric charge and discharge… More >

  • Open Access

    ARTICLE

    Bioactivity of Nanohybrid: Comprising of Metallosalen Incorporated into Lacunary Polyoxometalate and Encapsulated with Chitosan Biopolymer

    SHIVA ARUNa, VINAY KUMAR SINGHa,#, PRABHA BHARTIYAb, PRADIP KUMAR DUTTAc,*

    Journal of Polymer Materials, Vol.40, No.1-2, pp. 19-31, 2023, DOI:10.32381/JPM.2023.40.1-2.2

    Abstract Biocompatible polymer chitosan has note-worthy applications in biomedical science. Nanohybrids synthesized by using chitosan as an encapsulating unit for polyoxometalates (POMs) and study of its biomedical applications is a fast-emerging field. In this research work, a lacunary polyoxometalate (α-K8SiW11O39) has been synthesized and then alkylsilane has been inserted into its lacunary position. It has been then reacted with 2-hydroxy-1-naphtaldehyde followed by copper metalation and finally encapsulated into chitosan by using the ionotropic gelation technique, in which the chitosan and the POM served as cation and anion, respectively. The bands in UV-Vis spectra at characteristic wavelength indicate that the organosilane is… More >

  • Open Access

    REVIEW

    Mini Review on PEDOT:PSS as a Conducting Material in Energy Harvesting and Storage Devices Applications

    HYUNGSUB YOONa,*, HEEBO HAa, CHUNGHYEON CHOIa, TAE GWANG YUNb, BYUNGIL HWANGa

    Journal of Polymer Materials, Vol.40, No.1-2, pp. 1-17, 2023, DOI:10.32381/JPM.2023.40.1-2.1

    Abstract Poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS), one of the conducting polymers, is widely used as a conducting material in various applications. PEDOT:PSS possesses high electrical conductivity, optical transparency in visible light range, good chemical and physical stability in ambient state, etc. Furthermore, PEDOT:PSS offers the advantages of flexibility and possibility of solution-based process, which makes it suitable for use in flexible electronic devices. In this mini review, the applications of PEDOT:PSS as a conductive parts in energy harvesting and storage technologies are discussed and summarized. More >

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