RITESH D. BHATT, JIGNESH P. PATEL, P. H. PARSANIA^*

Journal of Polymer Materials, Vol.38, No.1-2, pp. 71-87, 2021, DOI:10.32381/JPM.2021.38.1-2.7

Abstract Glass/Biofibers/Epoxy methacrylate of bisphenol-C (G/BF/EBCMAS) sandwich composites was prepared by compression molding. G/BF/EBCMAS showed good mechanical and good to excellent electrical properties and excellent chemical resistance. Studied properties are compared with EBCMAS and G/EBCMAS. In comparison with G/EBCMAS, G/BF/EBCMAS showed considerable decline of tensile strength (18-63.4%), flexural strength (18.8-38.7%), flexural modulus (12.8-50.7%), Izod impact strength (17.4-43.5%), Barcol hardness (2.1-16.7%) and dielectric strength (23.8-76.8%) except flexural strength of G/BM/EBCMAS. G/WC/EBCMAS (96.7%), G/B/EBCMAS (79.2%), G/GN/EBCMAS (83.3%) and G/RH/EBCMAS (97.9%) showed decline of volume resistivity, whereas other sandwich composites showed 1150-58233% improvement. The decrease in mechanical properties and dielectric strength of G/BF/EBCMAS sandwich… More >

JALPA V. CHOPDA, DHARMESH B. SANKHAVARA, JIGNESH P. PATEL, P. H. PARSANIA^*

Journal of Polymer Materials, Vol.38, No.1-2, pp. 35-48, 2021, DOI:10.32381/JPM.2021.38.1-2.4

Abstract Conventional curing study of epoxy resin of (2E, 6E)-bis (4-hydroxybenzylidene)-4-methyl cyclohexanone (EMBHBC) was conducted at 140 0 /150 0 C by using 4,4’-diaminodiphenylmethane (DDM),4,4’-diaminodiphenylsulphone (DDS),4-4’-diaminodiphenyl ether (DDE), p-phenylenediamine (PDA), 1,2,3,6-tetrahydrophthalic anhydride(THPA), maleic anhydride (MAH) and pyromellitic dianhydride (PMDA). The gel time for DDS, THPA and DDM hardeners are found considerably longer than those of DDE, PDA, MAH and PMDA systems indicated different reactivity towards curing of EMBHBC. Sol–gel analysis of cured resins was carried out in DMF at room temperature. Diamines cured samples showed 76.3-97.5% gel fractions, while anhydrides cured samples showed 84.6-99.6% gel fractions. DDM, PDA and THPA are… More >

DHARMESH B. SANKHAVARA, JALPA V. CHOPDA, JIGNESH P. PATEL, PARSOTAM H. PARSANIA^*

Journal of Polymer Materials, Vol.38, No.1-2, pp. 11-19, 2021, DOI:10.32381/JPM.2021.38.1-2.2

Abstract The curing of epoxy resin of (2E, 6E)-2,6-bis(4-hydroxy benzylidene) cyclohexanone (EBHBC) was carried out at four different heating rates in the nitrogen atmosphere by using 4,4’-diamino diphenylmethane (DDM), 4,4’-diamino diphenyl sulfone (DDS), and 1,2,3,6-tetrahydrophthalic anhydride (THPA) as hardeners. From DSC curves onset, peak exotherm and end set temperatures, as well as heat release, were derived. The energy of activation was derived following Kissinger and Ozawa methods. Observed trend in Ea is EBHBC-THPA > EBHBCDDS > EBHBC-DDM > EBHBC. Nature and chemical structure of the hardeners affected the curing of EBHBC. More >

RAJKUMAR SINGH RAWAT^1,2, MEENU TALWAR^1,*, RAJENDRA KUMAR DIWAN², AJAY KUMAR TYAGI¹

Journal of Polymer Materials, Vol.38, No.3-4, pp. 281-294, 2021, DOI:10.32381/JPM.2021.38.3-4.9

Abstract In the present paper,boron based diluent was synthesized and incorporated in to a Ultraviolet (UV) radiation curable epoxy coating composition comprising of phosphorus based initiator (Trimethylbenzoyl diphenyl phosphine oxide) for enhancing its flame retardant property. The boron based diluent was synthesized by thermal polymerization technique. The presence of boron and phosphorus on the coating surface was confirmed by Energy Dispersive X-Ray (EDX) and X-ray photoelectron spectroscopy (XPS) techniques and functionality was determination by Fourier Transform Infra-Red (FTIR) and proton/boron NMR spectroscopy technique. The flame retardency property of the coating composition was confirmed by determining limiting oxygen index,vertical burning test, rate… More >

GAURAV AGARWAL

Journal of Polymer Materials, Vol.39, No.3-4, pp. 255-267, 2022, DOI:10.32381/JPM.2022.39.3-4.6

Abstract Studies were conducted to observe the effect of fracture toughness and damping response on fabric reinforced epoxy polymer composites. The samples of glass fabric, kevlar fabric and carbon fabric having 15wt%, 25wt%, 35wt%, 45wt% and 55wt % fabric content were prepared and tested following ASTM standards. Fracture toughness, peak load and increase in energy absorption are determined for the fabric-epoxy composites. Effect of temperature on storage modulus, loss modulus and tan delta values for various percentages of fabric epoxy composites are noticed and corresponding damping response behaviour is determined. The results revealed that reduction in strength at higher percentage of… More >

RITESH D. BHATT, JIGNESH P. PATEL, PARSOTAM H. PARSANIA^*

Journal of Polymer Materials, Vol.39, No.3-4, pp. 223-239, 2022, DOI:10.32381/JPM.2022.39.3-4.4

Abstract Compression-molded epoxy methacrylate of bisphenol-C-jute/treated jute-banana/groundnut/ cane sugar/pineapple leaf/rice husk/wheat husk sandwich composites were fabricated under 5 MPa pressure at room temperature for 3 h. Alkali treated jute-natural fiber sandwich composites displayed considerably improved mechanical properties over untreated jute-natural fiber sandwich composites due to surface modification of the jute fibers. Both types of sandwich composites showed high water uptake tendency, excellent hydrolytic stability against acids, alkali, and salt solutions, and also a longer equilibrium time at 30o C. Alkali treated sandwich composites revealed a considerably lower water uptake tendency than untreated sandwich composites. Observed water uptake trend is H₂ SO₄… More >

RITESH D. BHATT, JIGNESH P. PATEL, PARSOTAM H. PARSANIA^*

Journal of Polymer Materials, Vol.39, No.3-4, pp. 205-221, 2022, DOI:10.32381/JPM.2022.39.3-4.3

Abstract Epoxy methacrylate of bisphenol-C-jute/treated jute and their sandwich composites of white coir, brown coir, wild almond, bamboo, betel nut, and palmyra were prepared by a compression molding technique under 5MPa pressure and at room temperature for three h. The neat sample showed almost double tensile strength than its jute composite, while it is comparable for treated jute. The composites revealed substantially improved flexural strength compared to neat. The neat, jute/treated jute and their sandwich composites indicated good impact strength, pretty good Barcol hardness, and fairly good electric strength. The neat sample showed excellent volume resistivity, while jute/treated jute and their… More >

PARSOTAM H. PARSANIA^1,*, JIGNESH V. PATEL², JIGNESH P. PATEL³

Journal of Polymer Materials, Vol.40, No.3-4, pp. 271-284, 2023, DOI:10.32381/JPM.2023.40.3-4.9

Abstract Bisphenol-C epoxy crotonate resin was synthesized by reacting 8.09g epoxy resin of bisphenolC, and 2.15g crotonic acid using 25 mL 1,4-dioxane as a solvent, and 1 mL triethylamine as a catalyst at reflux temperature for 1-6 h. Solid epoxy crotonate (ECCR) is highly soluble in common organic solvents. ECCR was characterized by its acid (24.5-1.5 mg KOH/g) and hydroxyl (504.5-678.4 mg KOH/g) values. The structure of ECCR is supported by FTIR and 1 HNMR spectroscopic methods. A DSC endothermic transition at 229o C indicated melting followed by thermal polymerization of ECCR. ECCR is thermally stable up to 320o C and… More >

K. KRISHNAMOORTHY^a,*, N. PRABHU^b

Journal of Polymer Materials, Vol.40, No.3-4, pp. 215-226, 2023, DOI:10.32381/JPM.2023.40.3-4.7

Abstract The acoustic emission monitoring with artificial neural networks predicts the ultimate strength of glass/epoxy composite laminates using Acoustic Emission Data. The ultimate loads of all the specimens were used to characterise the emission of hits during failure modes. The six layered glass fiber laminates were prepared (in woven mat form) with epoxy as the binding medium by hand lay-up technique. At room temperature, with a pressure of 30 kg/cm², the laminates were cured. The laminates of standard dimensions as per ASTM D3039 for the tensile test were cut from the lamina. The Acoustic Emission (AE) test was conducted on these… More >

RITESH D. BHATT, JIGNESH P. PATEL, PARSOTAM H. PARSANIA^*

Journal of Polymer Materials, Vol.39, No.1-2, pp. 37-53, 2022, DOI:10.32381/JPM.2022.39.1-2.3

Abstract Compression-molded epoxy methacrylate of bisphenol-C-jute/treated jute-banana/groundnut/ cane sugar/pineapple leaf/rice husk/wheat husk sandwich composites were fabricated under 5 MPa pressure at room temperature for 3 h. Alkali treated jute-natural fiber sandwich composites displayed considerably improved mechanical properties over untreated jute-natural fiber sandwich composites due to surface modification of the jute fibers. Both types of sandwich composites showed high water uptake tendency, excellent hydrolytic stability against acids, alkali, and salt solutions, and also a longer equilibrium time at 30o C. Alkali treated sandwich composites revealed a considerably lower water uptake tendency than untreated sandwich composites. Observed water uptake trend is H₂ SO₄… More >