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  • Open Access

    ARTICLE

    Chitosan/PVA Films and Silver Nanoparticle Impregnated Nanofibrous Dressings for Evaluation of their Wound Healing Efficacy in Wistar Albino Rat Model

    SOBHA KOTA*, RATNAKUMARI ANANTHA, VAYUNANDANA RAO GOVADA, PRADEEP DUMPALA

    Journal of Polymer Materials, Vol.40, No.3-4, pp. 285-303, 2023, DOI:10.32381/JPM.2023.40.3-4.10

    Abstract The exoskeleton of marine shrimp contains a natural, biocompatible polymer chitin, which is dumped as a waste. The study proposes the sustainable single-pot-extraction of chitosan from the waste and its use in the fabrication of wound-dressings, and thus leverage its piezoelectric, antioxidant, hypoglycaemic and medicinal properties in wound-healing. The Fourier transform infrared spectrum revealed that marine chitosan contains functional groups with N-O, O-H, and CO stretching. Scanning electron micrographs demonstrated the spherical and mesoporous structures of the extracted chitosan. X-ray diffraction analysis showed a semi-crystalline phase of chitosan particles with a mean size of 28.9 nm. The film prepared with… More >

  • Open Access

    ARTICLE

    Effect of Sulfuric Acid on the Physiochemical Properties of Chitosan-PVA Blend for Direct Methanol Fuel Cell

    RABIRANJAN MURMUa,b, DEBASHIS ROYa, HAREKRUSHNA SUTARb, PRAGYAN SENAPATIc, SWETAK ABHISEK MOHAPATRAb

    Journal of Polymer Materials, Vol.39, No.1-2, pp. 89-109, 2022, DOI:10.32381/JPM.2022.39.1-2.6

    Abstract In this work, we have successfully cross-linked the different weight ratio of Chitosan-PVA blend with sulfuric acid. The effect of cross-linker on the properties of blends are studied by using different experimental technique. The cross-linked membrane provides higher ion exchange capacity due to the procurement of extra ionic hooping sites in the membrane. The compatibility of the blends are confirmed from the FTIR and DSC analysis. The crosslinking reaction fastening the phase transition behavior of the blends which reduces the glass transition temperature. The highly compatiblized cross-linked blend provides higher tensile strength and lower modulus at moderate temperature. The significant… More >

  • Open Access

    ARTICLE

    Exploration of Waterproofness of Concrete and Alkali-Aggregate Using Hydrophobic Impregnation and Coating

    Shun Kang1, Xun Yuan1, Changwu Liu1,*, Yulin Chen1, Xianliang Zhou1, Haikuan Wu2, Zhiguo Ma3

    Journal of Renewable Materials, Vol.10, No.12, pp. 3521-3538, 2022, DOI:10.32604/jrm.2022.021694

    Abstract Part of the tunnel spoil can not be used for concrete due to alkali-aggregate reaction (AAR). Water is an indispensable condition for AAR, so separating the alkali-aggregate from water is of great benefit to controlling the AAR. This paper investigates the modification of concrete and aggregate by hydrophobic impregnation and organic coating and then evaluates their waterproof and mechanical properties by dynamic contact angle (DCA), ultrasonic wave velocity, scanning electron microscope (SEM), nuclear magnetic resonance (NMR), and so on. For waterproofness, hydrophobic impregnation and organic coating can both improve the waterproofness of concrete and aggregate. The organic coating is suitable… More >

  • Open Access

    ARTICLE

    The Effect of Printing Parameters and Wood Surface Preparation on the Adhesion of Directly 3D-Printed PLA on Wood

    Daša Krapež Tomec, Angela Balzano, Jure Žigon, Milan Šernek, Mirko Kariž*

    Journal of Renewable Materials, Vol.10, No.7, pp. 1787-1796, 2022, DOI: 10.32604/jrm.2022.019760

    Abstract As additive manufacturing technologies advance, new opportunities are opening up for their application in the furniture industry. Wood remains one of the leading raw materials in the furniture industry; therefore, possible options for combining it with 3D printing have been researched. The bonding of 3D-printed polymer parts with wood or 3D printing with wood-plastic composites is already known, but in our research we attempted to directly 3D print polylactic acid (PLA) on wood surfaces. The effect of printing parameters, as well as the surface preparation of wood on the shear strength of the bond between wood and on-printed material was… More >

  • Open Access

    ARTICLE

    Green Synthesis of Silver Nanoparticles Using Plectranthus Amboinicus Leaf Extract for Preparation of CMC/PVA Nanocomposite Film

    Nguyen Thi Thanh Thuy1,*, Le Hoang Huy1, Truong Thuy Vy1, Nguyen Thi Thanh Tam2, Bien Thi Lan Thanh1, Nguyen Thi My Lan3

    Journal of Renewable Materials, Vol.9, No.8, pp. 1393-1411, 2021, DOI:10.32604/jrm.2021.015772

    Abstract In the present study, the biogenic silver nanoparticles have been synthesized using aqueous leaf extract of Plectranthus amboinicus (PA), which acted as both reducing and stabilizing agents. The PA synthesized silver nanoparticles were blended with carboxymethyl cellulose/polyvinyl alcohol (CMC/PVA) biocomposite. The prepared AgNPs as well as the biogenic AgNPs incorporated CMC/PVA films were investigated using UV-visible spectrophotometry, Fourier-transform infrared spectroscopy (FT-IR), dynamic light scattering (DLS), scanning electron microscope (SEM), and X–ray diffraction (XRD). The DLS results showed that biogenic AgNPs had the average particle size of 65.70 nm with polydispersity index of 0.44. The surface plasmon resonance of AgNPs, which… More > Graphic Abstract

    Green Synthesis of Silver Nanoparticles Using <i>Plectranthus Amboinicus</i> Leaf Extract for Preparation of CMC/PVA Nanocomposite Film

  • Open Access

    ARTICLE

    Influence of the Molecular Weight on PVA/GO Composite Membranes for Fuel Cell Applications

    C. González-Guisasola1, O. Gil-Castell1,2, R. Teruel-Juanes1, A. Ribes-Greus1,*

    Journal of Renewable Materials, Vol.8, No.9, pp. 1171-1180, 2020, DOI:10.32604/jrm.2020.04399

    Abstract Composite polymer electrolyte membranes were prepared with poly (vinyl alcohol) (PVA). Two different molecular weight (Mw), 67·103 and 130·103 g·mol−1 were selected, cross-linked with sulfosuccinic acid (SSA) and doped graphene oxide (GO). The effects on the membranes obtained from these polymers were characterized in order to evaluate the fuel cell performance. Electron microscopy showed a proper nanoparticle distribution in the polymer matrix. The chemical structure was evaluated by Fourier transform infrared spectroscopy. The absence of a crystalline structure and the enhancement on the thermal stability with the addition of 1% of GO was demonstrated by thermal characterization. Total transference number… More >

  • Open Access

    ARTICLE

    Effect of Y-Methacryloxypropyltrimethoxysilane (MPS) and Tetraethoxysilane (TEOS) Towards Preparation of Oil Absorbent Foams from Polyvinyl Alcohol (PVA) Reinforced with Microfibrillated Cellulose (MFC)

    Dzun Noraini Jimat*, Sharifah Shahira Syed Putra, Parveen Jamal, Wan Mohd Fazli Wan Nawawi, Mohammed Saedi Jami

    Journal of Renewable Materials, Vol.8, No.7, pp. 739-757, 2020, DOI:10.32604/jrm.2020.010357

    Abstract Increasing usage of foams in various industry sectors had causing serious disposal problems once it reaches the end of its life-cycle. Herein, PVA-MFC foam was prepared by freeze-drying using polyvinyl alcohol (PVA) and microfibrillated cellulose (MFC) as a reinforced material from sugarcane bagasse (SCB). In this study, the PVA-MFC foam was chemically silylated with Y-methacryloxypropyltrimethoxysilane (MPS) and tetraethoxysilane (TEOS). The wetting ability and mechanical strength of the silylated 2,20PVA-MFC foam was greatly enhanced compared with unmodified 2,20PVA-MFC foam. The silane chemicals (MPS and TEOS) had been confirmed grafted on 2,20PVA-MFC foam due to the presence of Si-C and Si-O-C stretching… More >

  • Open Access

    ARTICLE

    Feasible design for electricity generation from Chlorella vulgaris using convenient photosynthetic conditions

    Mahmoud MOUSTAFA1,2*, Tarek TAHA3, Mohamed ELNOUBY4, M.A. ABU-SAIED5, Ali SHATI1, Mohamed AL-KAHTANI1, Sulaiman ALRUMMAN1

    BIOCELL, Vol.42, No.1, pp. 7-12, 2018, DOI:10.32604/biocell.2018.07002

    Abstract Many recent studies are concerned with low cost, easy to handle and alternative renewable energy as a feasible solution for the upcoming crisis of energy shortage. Microalgae are unicellular entities the can only depend on CO2, water and solar power to cover their nutritional needs. The current study is concerned with using algal cells in a polymeric hydrogel, as a cheap source of energy for electricity generation. Chlorella vulgaris has been proved to be a promising algal species for electricity generation, as compared with Micractinium reisseri. PVA hydrogel has been used for the immobilization of both algal species in order… More >

  • Open Access

    ABSTRACT

    Evaluation of fiber dispersion of PVA-ECC

    Y. Y. Kim1, B. Y. Lee2, J. K. Kim2

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.7, No.4, pp. 167-172, 2008, DOI:10.3970/icces.2008.007.167

    Abstract The fiber dispersion performance in fiber-reinforced cementitious composites is a crucial factor with respect to achieving desired mechanical performance. However, evaluation of the fiber dispersion performance in the composite PVA-ECC (Polyvinyl alcohol-Engineered Cementitious Composite) is extremely challenging because of the low contrast of PVA fibers with the cement-based matrix. In the present work, an enhanced image processing technique including more detailed classification of types of fibers and adaptation of a morphological reconstruction, the fiber detection performance is enhanced. Test results using artificial and real fiber images showed that a distribution coefficient αf, referred to as the fiber dispersion coefficient was… More >

  • Open Access

    ARTICLE

    Biocompatible Blends Based on Poly (Vinyl Alcohol) and Solid Organic Waste

    Antonio Greco*, Francesca Ferrari, Raffaella Striani, Carola Esposito Corcione

    Journal of Renewable Materials, Vol.7, No.10, pp. 1023-1035, 2019, DOI:10.32604/jrm.2019.07778

    Abstract This work is aimed at the development of new green composite materials through the incorporation of the solid organic waste (SOW) in a thermoplastic matrix. After being ground, the organic waste was exposed to a sterilization process, though an autoclave cycle, in order to obtain a complete removal of the bacterial activity. The SOW was found to have a high amount of water, about 65-70%, which made uneconomical its further treatment to reduce the water amount. Therefore, a water soluble polymer, poly (vinyl alcohol) (PVA) was chosen in order to produce SOW based blends. However, in order to reduce the… More >

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