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  • Open Access

    ARTICLE

    Development and Characterization of Graphite Fluoride Dry Lubrication System by using Gamma Radiation

    SACHIN SINGHa, MUKTI TYAGIa,*, AJAY KUMAR TYAGIa, PRAVEEN KUMAR KAICKERa, LALIT VARSHNEYb

    Journal of Polymer Materials, Vol.36, No.4, pp. 305-321, 2019, DOI:10.32381/JPM.2019.36.04.2

    Abstract Graphite is the most suitable material as dry lubricant. However, its application as a lubricant is limited with necessity of moisture vapors. Alternatively, polytetrafluoroethylene (PTFE) has an excellent lubrication property but does not have mechanical characteristics. The effect of gamma radiation doses on the lubrication behavior of graphite –PTFE (Inoflon A-408) system has been studied using (TR-TW-30L) tribotester with thrust washer attachment. Different compositions of graphite and PTFE were prepared and irradiated by gamma rays. Improved tribological properties of graphite –PTFE system showed by decrease in coefficient of friction and wear. SEM-EDX, XRD and contact angle analysis confirm fluorination of… More >

  • Open Access

    ARTICLE

    Fabrication of Microspherical Catalyst with Hierarchical Porous Structure from Functional Monomers via Low-Temperature Phase-Separation Photopolymerization

    KEMIN WANG, LIFEI HE

    Journal of Polymer Materials, Vol.36, No.3, pp. 253-260, 2019, DOI:10.32381/JPM.2019.36.03.5

    Abstract This study proposes a simple approach for the fabrication of microspherical catalysts with a hierarchical porous structure. The cross-linked porous microspheres with catalytic ability were prepared directly from small-molecular monomers via low-temperature phase-separation photopolymerization of water/oil suspension. The morphology, pore size, chemical structure, and thermal stability of the obtained porous microspheres were characterized by SEM, Mercury Intrusion Porosimetry, FTIR, and TGA. The porous microspheres directly served as an acid catalyst for the condensation reaction of benzaldehyde and ethylene glycol, which exhibited superior catalytic activity and recyclability. The results indicated that such porous microspheres have great potential in the application of… More >

  • Open Access

    ARTICLE

    Anionic Polymerization of ε-Caprolactone Using Potassium tert-Butoxide/18-Crown-6 Initiating System

    YAN WANGA, LI-FANG ZHANGA,B,C,*, XIAO-QI WANGB

    Journal of Polymer Materials, Vol.37, No.1-2, pp. 77-89, 2020, DOI:10.32381/JPM.2020.37.1-2.6

    Abstract The effect of 18-crown-6 ether (18C6) on the anionic polymerization of ε-caprolactone (ε -CL) using potassium tert-butoxide (t-BuOK) as the initiator was studied. The experimental results showed that 18C6 in combination with t-BuOK exhibited high selectivity for ring opening relative to trans-esterification and improved control toward the ROP of ε-CL, producing poly(ε- caprolactone) (PCL) with much higher molecular weight and relatively narrow distribution compared to those using t-BuOK alone as the initiator.The influences of reaction conditions, such as monomer concentration, monomer/initiator molar ratio, and [18C6]/[t-BuOK] molar ratio, as well as reaction temperature and time on the polymerization have been examined… More >

  • Open Access

    ARTICLE

    Synthesis and Characterization of Pyridine-containing Epoxy: H-bonds Distribution and Thermomechanical Performances

    ZHAO JUNa, LIU AIQINa, ZHOU HONGa, LUO JUNb,*, AND LIU YUANb,*

    Journal of Polymer Materials, Vol.37, No.1-2, pp. 29-42, 2020, DOI:10.32381/JPM.2020.37.1-2.3

    Abstract Heteroatoms (N, O, and F) and hydrogen groups are important elements for forming the H-bonds. It is well known that a large number of hydrogen groups are formed after curing reaction of epoxy. However, literatures about epoxy resins containing heteroaromatic ring and the H-bonds after cure reaction of the epoxy resins are seldom published. To bridge the gap, a kind of new epoxy monomer containing pyridine ring (EMP) has been synthesized in this work, andit is further cured by 4,4-diaminodiphenyl methane (DDM). The properties of cured EMP/ DDM are evaluated by DSC, DMA, and static contact angle measurement. Moreover, the… More >

  • Open Access

    ARTICLE

    Preparation of Corn Cellulose Films with Controllable Mechanical Property by Using Switchable CO2 /DBU/ DMSO System

    BAOHAI PAN1,2, JUNCHENG HUANG1, LAI CHEN2, FEI LIU1,*, CHEN JING, HAINING NA1,*, JIN ZHU1

    Journal of Polymer Materials, Vol.37, No.1-2, pp. 17-27, 2020, DOI:10.32381/JPM.2020.37.1-2.2

    Abstract A switchable CO2 /1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)/dimethyl sulfoxide (DMSO) solvent system is applied to prepare corn cellulose film with controllable mechanical property. By use of the switchable CO2 /DBU/DMSO system, a rather simple process concerning reacted dissolution and heated precipitation controlled by addition and releasing of CO2 respectively, to prepare corn cellulose film, is formed. Results exhibit the degree of dissolution of corn cellulose is easily controlled just by adjusting the feeding amount of DBU in the switchable solvent system. Accordingly, some undissolved part of corn cellulose with relative high crystallinity can be appropriately retained to contribute to the improvement of mechanical… More >

  • Open Access

    ARTICLE

    Study of the Effect of UV-exposure on HDPE/Carbon Black Composite Floating Structure

    ALOK K. SAHUa, RAJSHREE VIJAYVARGIYAa, R. M. SARVIYAb

    Journal of Polymer Materials, Vol.39, No.3-4, pp. 183-193, 2022, DOI:10.32381/JPM.2022.39.3-4.1

    Abstract HDPE material is found to be best suited material for the manufacturing of floating bed structure for the solar photovoltaic (PV) system due to its light weight and excellent mechanical & chemical resistant properties. However, the major restriction in this regard is the limited engineering design and also the effect of UV radiations present in the natural environment that leads to the degradation of the plastic materials. Hence, in order to improve its UV stability carbon black is incorporated into it as UV resistant additive and hollow cubical floats of such HDPE/carbon black composite material has been manufactured by rotational… More >

  • Open Access

    ARTICLE

    Genome-Wide Exploration of the Grape GLR Gene Family and Differential Responses of VvGLR3.1 and VvGLR3.2 to Low Temperature and Salt Stress

    Honghui Sun1,2,#, Ruichao Liu1,2,#, Yueting Qi1, Hongsheng Gao1, Xueting Wang1, Ning Jiang1,2, Xiaotong Guo1,2, Hongxia Zhang1, Chunyan Yu1,2,*

    Phyton-International Journal of Experimental Botany, Vol.93, No.3, pp. 533-549, 2024, DOI:10.32604/phyton.2024.049417

    Abstract Grapes, one of the oldest tree species globally, are rich in vitamins. However, environmental conditions such as low temperature and soil salinization significantly affect grape yield and quality. The glutamate receptor (GLR) family, comprising highly conserved ligand-gated ion channels, regulates plant growth and development in response to stress. In this study, 11 members of the VvGLR gene family in grapes were identified using whole-genome sequence analysis. Bioinformatic methods were employed to analyze the basic physical and chemical properties, phylogenetic trees, conserved domains, motifs, expression patterns, and evolutionary relationships. Phylogenetic and collinear analyses revealed that the VvGLRs were divided into three… More >

  • Open Access

    ARTICLE

    Correlation and Pathway Analysis of the Carbon, Nitrogen, and Phosphorus in Soil-Microorganism-Plant with Main Quality Components of Tea (Camellia sinensis)

    Chun Mao1, Ji He1,*, Xuefeng Wen1, Yangzhou Xiang2, Jihong Feng1, Yingge Shu1

    Phyton-International Journal of Experimental Botany, Vol.93, No.3, pp. 487-502, 2024, DOI:10.32604/phyton.2024.048246

    Abstract The contents of carbon (C), nitrogen (N), and phosphorus (P) in soil-microorganisms-plant significantly affect tea quality by altering the main quality components of tea, such as tea polyphenols, amino acids, and caffeine. However, few studies have quantified the effects of these factors on the main quality components of tea. The study aimed to explore the interactions of C, N, and P in soil-microorganisms-plants and the effects of these factors on the main quality components of tea by using the path analysis method. The results indicated that (1) The contents of C, N, and P in soil, microorganisms, and tea plants… More >

  • Open Access

    ARTICLE

    Effects of Flowering Mode and Pollinator Sharing on Reproductive Success in Natural Hybrid of Two Epimedium (Berberidaceae) Species

    Lanying Chen1,2, Qiumei Quan3,*, Yunxiang Li3

    Phyton-International Journal of Experimental Botany, Vol.93, No.3, pp. 551-566, 2024, DOI:10.32604/phyton.2024.048103

    Abstract Mediated by pollen flow, natural hybridization is deemed a crucial factor that propels speciation in floral plants. Despite the fact that the diversity of Epimedium species is concentrated mainly in Southwestern China, the potential impact of interspecific pollination on natural hybridization has yet to be empirically scrutinized. To explore this, we studied the flowering period and the visitors of flowers in three frequently overlapping Epimedium species at Jinchengshan National Forest Park, located in Nanchong, Sichuan Province. Additionally, we performed a series of pollination experiments to examine breeding systems and hybrid compatibility. Morphologically, Epimedium pubescens and Epimedium wushanense are clearly distinct… More >

  • Open Access

    ARTICLE

    Chiral Copolymers of (R)-N-(1-Phenyl-Ethyl) Methacrylamide (R-NPEMAM) and 2-Hydroxy Ethyl Methacrylate (HEMA): Investigation of PhysicoChemical Behavior, Thermal Properties and Degradation Kinetics

    DIBYENDU S. BAG*, SHILPI TIWARI, AKANSHA DIXIT, KM. MEENU

    Journal of Polymer Materials, Vol.40, No.1-2, pp. 105-123, 2023, DOI:10.32381/JPM.2023.40.1-2.9

    Abstract In this paper, we report the microstructural investigation and influence of H-bonding on the thermal behavior e.g., glass transition (Tg ) and thermal degradation of chiral copolymers of (R)- N-(1-phenyl-ethyl) methacrylamide (R-NPEMAM) and 2-hydroxy ethyl methacrylate (HEMA). The Tg increases with the increase of chiral unit content in the copolymers and then attains optimum at around 25 mole % of chiral content. Thereafter it decreases with the increase of chiral content. The effect of copolymer composition and secondary interaction associated with the Hbonding on the thermal properties of these copolymers was also studied. Secondary interaction, specifically H-bonding has been interpreted… More >

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