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  • Open Access

    ARTICLE

    The importance of CdS and ZnO-NPs in study anti-microbial activity prepared by laser ablation and simple chemical method

    H. A. Ahmed, M. Y. Ali, S. S. Hamood, A. N. Abd*

    Chalcogenide Letters, Vol.22, No.1, pp. 11-22, 2025, DOI:10.15251/CL.2025.221.11

    Abstract As a potential substitute for antibiotics, cadmium sulfide and zinc oxide nano-particles (CdS and ZnO NPs) were created using laser ablation and a straightforward chemical process, respectively. Target of cadmium sulfide, deionized water, zinc nitrate, and sodium hydroxide were used as precursors. Different characterization techniques were used to characterize the CdS and ZnO NPs. X-ray diffraction was used to confirm that the CdS and ZnO had polycrystalline structures with average crystalline sizes of 54.16 nm and 29.23 nm, respectively. The ZnO particles were densely packed 2D curved nanopetals with a diameter of 51.65 nm, whereas… More >

  • Open Access

    ARTICLE

    ZnO/ZnS sensor with broadband visible response for flexible polyethylene terephthalate substrates combined with artificial intelligence analysis

    X. Y. Chena,b, Y. H. Caia, Y. S. Chenc, S. J. Huangb, M. H. Lid, Y. H. Lie, C. H. Linc, H. Chena,*

    Chalcogenide Letters, Vol.22, No.9, pp. 777-785, 2025, DOI:10.15251/CL.2025.229.777

    Abstract This study focuses on the development of zinc oxide (ZnO)/zinc sulfide (ZnS) core-shell structures on flexible polyethylene terephthalate (PET) substrates for enhanced light sensing. PET offers high elasticity, optical transparency, and chemical resistance, making it ideal for wearable optoelectronics. By optimizing the vulcanization process, a uniform ZnS shell is formed on the exposed regions of ZnO nanorods (NRs), significantly enhancing ZnO-based sensor’s sensitivity to visible light, especially red light (peak wavelength at 630 nm). Structural and spectral analyses confirm the successful formation of the ZnO/ZnS heterostructure, improved charge separation, and broadened light response. To improve More >

  • Open Access

    ARTICLE

    Thin-Film Solar Cell Based on Sb2(Sx,Se1−x)3 Solid Solution Films

    T. M. Razykov1, K. M. Kuchkarov1, R. T. Yuldoshov1, M. P. Pirimmatov1, R. R. Khurramov1, D. Z. Isakov1, M. A. Makhmudov1, A. Matmuratov1, J. G. Bekmirzoyev1, A. N. Olimov2

    Chalcogenide Letters, Vol.22, No.11, pp. 959-964, 2025, DOI:10.15251/CL.2025.2211.959

    Abstract This work presents the results of investigating the photovoltaic characteristics of Sb2(SxSe1−x)3 thin film solar cells manufactured on glass substrates with molybdenum coating using the chemical molecular beam deposition method. Illuminated IV and spectral response measurements on Sb2(SxSe1−x)3 alloy films show that the device with S/(S + Se) = 0.6 delivers the best performance, reaching 6.47% power-conversion efficiency with VOC = 523 mV, JSC = 27.2 mA cm−2 , and a fill factor of 46.71%. More >

  • Open Access

    ARTICLE

    Thermal Performance Analysis of Shell and Tube Heat Exchanger Using Hybrid Nanofluids Based on Al2O3, TiO2, and ZnO Nanoparticles

    Ans Ahmed Memon1, Laveet Kumar1,2,*, Abdul Ghafoor Memon1, Khanji Harijan1, Ahmad K. Sleiti2

    Frontiers in Heat and Mass Transfer, Vol.23, No.3, pp. 833-856, 2025, DOI:10.32604/fhmt.2025.064805 - 30 June 2025

    Abstract Climate change, rising fuel prices, and fuel security are some challenges that have emerged and have grown worldwide. Therefore, to overcome these obstacles, highly efficient thermodynamic devices and heat recovery systems must be introduced. According to reports, much industrial waste heat is lost as flue gas from boilers, heating plants, etc. The primary objective of this study is to investigate and compare unary (Al2O3) thermodynamically, binary with three different combinations of nanoparticles namely (Al2O3 + TiO2, TiO2 + ZnO, Al2O3 + ZnO) and ternary (Al2O3 + TiO2 + ZnO) as a heat transfer fluid. Initially, three different types of… More > Graphic Abstract

    Thermal Performance Analysis of Shell and Tube Heat Exchanger Using Hybrid Nanofluids Based on Al<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub>, and ZnO Nanoparticles

  • Open Access

    ARTICLE

    Synergistic Effect of Piperazine Pyrophosphate (PAPP)/Melamine Polyphosphate (MPP)/ZnO Halogen-Free Flame Retardant System in PPC-P/PBAT Blends

    Yuxin Zheng, Ke Xu, Baicheng Zhang, Shengxin Guan, Lin Xia, Zhaoge Huang*

    Journal of Polymer Materials, Vol.42, No.1, pp. 237-253, 2025, DOI:10.32604/jpm.2025.059622 - 27 March 2025

    Abstract In this manuscript, we conveniently prepared a series of polyester-polycarbonate copolymer (PPC-P)/polybutylene adipate terephthalate (PBAT) blends that exhibit both flame-retardant properties and toughness. Piperazine pyrophosphate (PAPP), melamine phosphate (MPP) and ZnO were used as synergistic flame retardants for PPC-P/PBAT blends. The effects of synergistic flame retardants on thermal stability, combustion behavior and flame retardancy of PPC-P/PBAT blends were investigated. The results showed that when the ratio of PAPP/MPP/ZnO was 18.4:9.2:2.4, the LOI of PPC-P/PBAT composite was 42.8%, and UL-94 reached V-0 level. The results of cone calorimetry showed that the mass loss rate (MLR), the… More >

  • Open Access

    ARTICLE

    Preparation and characterization of ZnO@MoS2 nanocomposites: investigating photoelectrical, electrocatalytic, and electrochemical behaviors

    J. M. Shi*, H. F. Zhang, H. C. Wang

    Chalcogenide Letters, Vol.21, No.3, pp. 263-274, 2024, DOI:10.15251/CL.2024.213.263

    Abstract This study presents the synthesis and characterization of 3D ZnO@MoS2 nanocomposites, demonstrating their superior performance in photoelectrochemical applications. Employing a combination of hydrothermal and solvothermal methods, the research focuses on creating heterostructures with optimized interfacial characteristics. The ZnO@MoS2 composites show a substantial increase in photocurrent density (1.02 mA/cm²), compared to ZnO nanorods (0.32 mA/cm²), underlining enhanced charge separation efficiency. In electrocatalytic hydrogen evolution, the heterostructures exhibit a lower onset potential (-175 mV vs RHE) and reduced Tafel slope (51 mV/dec), indicating improved catalytic activity over MoS2 nanosheets. Additionally, the composites demonstrate a significant increase in electrochemical capacitance (398 More >

  • Open Access

    ARTICLE

    Er3+-doped SiO2-TeO2-ZnO-Na2O thin film fabricated by ultrafast laser plasma doping under different ambient atmospheres

    S. A. Kamila,b,*, G. Josec

    Chalcogenide Letters, Vol.21, No.1, pp. 11-20, 2024, DOI:10.15251/CL.2024.211.11

    Abstract Er3+-ions doped SiO2-ZnO-Na2O thin films were fabricated using ultrafast laser plasma doping (ULPD) techniques under different ambient atmospheres; vacuum, nitrogen, oxygen and argon gas. The thickness of the layer produced depends on the ambient atmosphere during fabrication. The layer fabricated under a vacuum is the thinnest among all of the samples. In addition, the surface layer for the sample fabricated under a vacuum environment seems to be relatively smoother compared with those of the others. XRD patterns show that all samples are in a mixed amorphous-crystalline phase. All the Raman spectra exhibited a similar pattern, except More >

  • Open Access

    ARTICLE

    Influence of copper on zinc oxide films and solar cell performance

    B. K. H. Al-Maiyaly, S. M. Ali, B. H. Hussein, H. K. Hassun*

    Chalcogenide Letters, Vol.21, No.8, pp. 605-613, 2024, DOI:10.15251/CL.2024.218.605

    Abstract Copper doped Zinc oxide and (n-ZnO / p-Si and n-ZnO: Cu / p-Si) thin films thru thickness (400±20) nm were deposited by thermal evaporation technique onto two substrates. The influence of different Cu percentages (1%,3% and 5%) on ZnO thin film besides hetero junction (ZnO / Si) characteristics were investigated, with X-ray diffractions examination supports ZnO films were poly crystal then hexagonal structural per crystallite size increase from (22.34 to 28.09) nm with increasing Cu ratio. The optical properties display exceptional optically absorptive for 5% Cu dopant with reduced for optically gaps since 3.1 toward More >

  • Open Access

    ARTICLE

    High optimization of crystallization experimental conditions of ZnO nano thin films prepared by spray pyrolysis technique for optoelectronic applications

    L. Bourasa, A. Beggasa,*, D. Sahnouneb, M. Ghougalia, R. Ferhata

    Chalcogenide Letters, Vol.21, No.11, pp. 917-926, 2024, DOI:10.15251/CL.2024.2111.917

    Abstract The present study intends to provide the impact of nitric acid on the structural and optical characteristics of thin films of ZnO. The latter was grown on substrates of glass via spray pyrolysis with 400°C, using Zinc acetate aqueous solution acidified by different amounts of nitric acid to obtain a pH ranging from 6.8 to 2.9. The film properties were analyzed as a function of pH. In the light of the XRD analysis, all the films have a preferential direction along the (002) plane. Depending on pH conditions, the crystal size increased from 32.38 to More >

  • Open Access

    ARTICLE

    Synthesis and Characterization of CMC-Wrapped ZnONPs at Different Calcination Temperatures for Photocatalytic Degradation of Methylene Blue Dye under Sunlight

    Abhishek Kumar Patel, Ashlesha P. Kawale, Neeru Sharma, Nishant Shekhar, Subhash Banerjee*, Arti Srivastava*

    Journal of Polymer Materials, Vol.41, No.2, pp. 69-86, 2024, DOI:10.32604/jpm.2024.052695 - 09 August 2024

    Abstract This study aims to synthesize, characterize, and evaluate the photocatalytic efficiency of carboxymethyl cellulose (CMC) wrapped ZnONPs for the degradation of methylene blue (MB) dye under sunlight and also focuses on the effect of varying calcination temperatures on crystallite size of the synthesized ZnONPs@CMC. It focuses on developing biopolymer (CMC) wrapped ZnO nanoparticles (ZnONPs@CMC) at different calcination temperatures. ZnONPs@CMC are synthesized using zinc acetate dihydrate as a precursor under alkaline conditions, followed by adding capping agent CMC at various calcination temperatures ranging from 250°C to 650°C. The nanomaterials are characterized by UV-Vis, FTIR, and powder… More >

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