Bo Chen¹, Bo Liu^2,*, Yong Chao³, Chao Zhong¹

Journal of Renewable Materials, Vol.10, No.12, pp. 3491-3504, 2022, DOI:10.32604/jrm.2022.021302

Abstract The formation process of aromatic hydrocarbon tar during the pyrolysis process of biomass components of cellulose and lignin was carried out by quantum chemical calculation based on density functional theory method B3LYP/6-31G++(d, p). 5-Hydroxymethylfurfural was chosen as the model compound of cellulose and hemicellulose, and syringaldehyde was chosen as the model compound of lignin. The calculation results show that the formation process of cellulose monocyclic aromatic hydrocarbon tar is the conversion process of benzene ring from furan ring, and the highest reaction energy barrier appears in the process of decarbonylation, which is 370.8 kJ/mol. The formation of lignin monocyclic aromatic… More >

Shuangyan Zhang^*, Shun Yang, Chuangui Wang, Weiyi Su, Huangfei Lv, Yuanyuan Li

Journal of Renewable Materials, Vol.10, No.12, pp. 3229-3241, 2022, DOI:10.32604/jrm.2022.020489

Abstract Bamboo harvesting residues are wastes by-products of bamboo industries that contain holocellulose for about 63.14% to 70.71%, which often be discarded, incinerated or buried. In this study, carboxymethyl cellulose was prepared from bamboo harvesting residues (bamboo-branch and bamboo-tip) as raw materials. The chemical composition of bamboo harvesting residues, the viscosity and degree of substitution of carboxymethyl cellulose were determined. Carboxymethyl cellulose obtained was further characterized and compared by means of FTIR, SEM, XRD and TG. Results showed that under the optimized identical conditions, the viscosity and degree of substitution of carboxymethyl cellulose from bamboo-branch and bamboo-tip were 6.0 and 78.9… More > Graphic Abstract

Chaodong Liu, Yutong Yang, Boyu Cui, Weihong Wang^*

Journal of Renewable Materials, Vol.10, No.11, pp. 2961-2972, 2022, DOI:10.32604/jrm.2022.019761

Abstract Microfibrillated cellulose (MFC) is often added to polylactic acid (PLA) matrixes as a reinforcing filler to obtain fully-biodegradable composites with improved mechanical properties. However, the incompatibility between MFC and the PLA matrix limits the mechanical performance of MFC-reinforced PLA composites. In this paper, DL-lactic acid-grafted-MFC (MFC-g-DL) was used to improve the compatibility with PLA. Reinforced composites were prepared by melt extrusion and hot-cold pressing. The tensile strength of the PLA/MFC-g-DL composite increased by 22.1% compared with that of PLA after adding 1% MFC-g-DL. Scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and dynamic thermomechanical analysis (DMA) were used to explore… More > Graphic Abstract

Abir Razzak^1,2, Faten Mannai¹, Ramzi Khiari^3,4,5, Younes Moussaoui^2,6, Mohamed N. Belgacem^5,*

Journal of Renewable Materials, Vol.10, No.10, pp. 2593-2606, 2022, DOI:10.32604/jrm.2022.021706

Abstract The exploitation of biomass represents a major environmental challenge related to the protection of the environment and the progressive exhaust of fossil resources. In this perspective, the main objective of this work is the extraction and the characterization of natural lignocellulosic fibers from the Schinus molle. The cellulose fibre extraction was investigated employing conditions of alkali treatment. After the alkaline steps, a bleaching treatment was done and let to a yield about 45% pure cellulose. The identification of the chemical composition of Schinus molle reveals that this raw material contains a high level of biopolymers with a cellulose rate of… More >

Heru Suryanto^1,2,*, Bili Darnanto Susilo³, Jibril Maulana³, Aminnudin³, Uun Yanuhar⁴, Surjani Wonorahardjo^2,5, Husni Wahyu Wijaya^2,5, Abu Saad Ansari⁶

Journal of Renewable Materials, Vol.10, No.9, pp. 2455-2465, 2022, DOI:10.32604/jrm.2022.020478

Abstract Waste is the main problem for the environment. Handling waste for various useful applications has a benefit for the future. This work has been studied for handling pineapple peel waste to make composite film bacterial cellulose nanocomposite membrane (BCNM) with addition graphite nanoplatelet (GNP). The concentration of GNP in the membrane influence the membrane properties. The bacterial cellulose (BC) pellicle was synthesized by using media from pineapple peel waste extract. BC pellicle is cleaned with water and NaOH solution to be free from impactors. BCNM is synthesized through the mechanical disintegration stage. The results of disintegration using high pressure homogenizer… More > Graphic Abstract

Ningli An¹, Jingxuan Qin¹, Xing Zhou¹, Quandai Wang², Changqing Fang^1,*, Jiapeng Guo², Bin Nan²

Journal of Renewable Materials, Vol.10, No.9, pp. 2319-2334, 2022, DOI:10.32604/jrm.2022.021030

Abstract Flexible sensors are attractive due to potential applications in body exercise and ambient gas monitoring systems. Cellulose and its derivatives have combined superiorities such as intrinsic and structural flexibility, ease of chemical functionalization, moisture sensitivity, and mechanical stability, enabling them to be promising candidates as flexible supporting substrates and flexible sensitive materials. Significant progress consequently has been achieved to improve mechanical, electrical, and chemical performance. The latest advance in materials synthesis, structure design, fabrication control, and working mechanism of novel cellulose-based flexible sensors are reviewed and discussed, including strain sensors, humidity sensors, and harmful gas sensors. Various strategies were summarized… More > Graphic Abstract

Qianqian Li¹, Qi Zhao^1,2,*, Xinzhuan Yao¹, Baohui Zhang¹, Litang Lu^1,2,*

Phyton-International Journal of Experimental Botany, Vol.91, No.10, pp. 2163-2189, 2022, DOI:10.32604/phyton.2022.021530

Abstract The cellulose synthase gene superfamily, including Cellulose synthase A (CesA) and cellulose synthase-like (Csl) gene families, is responsible for the synthesis of cellulose and hemicellulose, respectively. The CesA/Csl genes are vital for abiotic stress resistance and shoot tenderness regulation of tea plants (Camellia sinensis). However, the CesA/Csl gene family has not been extensively studied in tea plants. Here, we identified 53 CsCesA/Csl genes in tea plants. These genes were grouped into five subfamilies (CsCesA, CsCslB, CsCslD, CsCslE, CsCslG) based on the phylogenetic relationships with Arabidopsis and rice. The analysis of chromosome distribution, gene structure, protein domain and motif revealed that… More >

Mohammad Jawaid¹, Lau Kia Kian¹, Hassan Fouad², Ramzi Khiari^3,4,5,*, Othman Y. Alothman⁶, Mohamed Hashem⁷

Journal of Renewable Materials, Vol.10, No.6, pp. 1459-1470, 2022, DOI:10.32604/jrm.2022.018415

Abstract Cellulose nanocrystal (CNC) is a biomaterial derived from plant lignocellulosic components, widely applied in various industrial fields. Concurrently, with the growth of awareness in developing green nanomaterial, the explored Washingtonia fibre could be alternative biomass for obtaining CNC products. In the present work, different acid concentrations of 5%, 15%, and 25% hydrochloric solutions were employed to produce CNCs from Washingtonia fibre. With the chemical treatments, the yield of the CNC product was successfully retained at 21.6%−25.1%. Individually separated and needle-shaped CNC particles could be observed under the microscopic viewing with the increased acid concentrations. From elemental analysis, a relatively pure… More > Graphic Abstract

Xiaozheng Sun^1,*, Yu Yang¹, Qiang He², Jianye Li¹, Rui Li¹, Haitao Chen¹

Journal of Renewable Materials, Vol.10, No.3, pp. 751-766, 2022, DOI:10.32604/jrm.2022.016933

Abstract The accumulation of Cu²⁺ in water is a potential threat to human health and environment. Dicarboxylic nanocellulose (DNC) with rich carboxyl groups was prepared through the NaIO₄–NaClO₂ sequential oxidation method to efficiently remove copper ions, and the Cu²⁺ adsorption properties and cost were studied. The maximum adsorption capacity reached 184.2 mg/g at pH 6 and an adsorbent dose of 5 g/L. Theoretically, the maximum adsorption capacities of monocarboxylic nanocellulose (MNC), DNC, and tricarboxylic nanocellulose (TNC) with carboxyl groups as the main adsorption sites were calculated to be 228.7, 261.3, and 148.1 mg/g, respectively. The Cu²⁺ adsorption costs of MNC, DNC, and TNC were… More > Graphic Abstract

Hongmei Zhang^1,*, Quancheng Zhou²

FDMP-Fluid Dynamics & Materials Processing, Vol.17, No.6, pp. 1101-1111, 2021, DOI:10.32604/fdmp.2021.017202

Abstract Huge amounts of Xanthoceras sorbifolia husks (XSH) are typically discarded after oil extraction. Since pyrolysis represents a promising solution to harness the bio-energy of XSH, in the present work the pyrolytic and kinetic characteristics of XSH and related crude cellulose extract (CCE) were studied considering different rates of heating (10, 30 and 50°C min⁻¹). The pyrolysis activation energy, pre-exponential factors and mechanism function were computed using different models namely Popescu, FWO (Flynn-Wall-Ozawa) and KAS (Kissinger-Akahira-Sunose). The pyrolysis process was articulated into three stages: dehydration (Stage I), primary devolatilization (Stage II), residual decomposition (Stage III). Marked variations in the average activation… More >