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  • Open Access

    ARTICLE

    VOC Sensing Studies on Electrically Conductive Polyaniline@MoS2 Nanocomposites

    RUBY AHMED1, MOHAMMAD OMAISH ANSARI2, FARMAN ALI1, SHAHID PERVEZ ANSARI1,*

    Journal of Polymer Materials, Vol.36, No.3, pp. 243-251, 2019, DOI:10.32381/JPM.2019.36.03.4

    Abstract Polyaniline (PANI) and molybdenum disulphide (MoS2 ) were used to prepare nanocomposites by in-situ oxidative polymerization of acidified aniline in presence of dispersed MoS2 in the reaction mixture. Electron Microscopy (SEM & TEM), Fourier Transform Infrared (FTIR) spectroscopy, Ultraviolet-Visible (UV-Vis) spectroscopy, and X-ray diffraction (XRD) were used to characterize these nanocomposites. SEM micrographs showed that PANI is present on the layers of MoS2 which were exfoliated during the preparation and the presence of MoS2 is also confirmed by XRD peaks. The nanocomposites were studied for their electrical conductivity and stability of electrical conductivity in terms of d.c. More >

  • Open Access

    ARTICLE

    Influence of Poly (vinyl butyral) Modification on the Mechanical and Thermal Properties of Kevlar Fiber Reinforced Novolac epoxy/multiwalled carbon nanotube nanocomposites

    KAVITA*, R.K. TIWARI

    Journal of Polymer Materials, Vol.36, No.2, pp. 195-205, 2019, DOI:10.32381/JPM.2019.36.02.7

    Abstract The effect of poly (vinyl butyral) and acid functionalized multiwalled carbon nanotubes (f-MWCNT) on the thermal and mechanical performance of Kevlar fiber reinforced novolac epoxy nanocomposites was investigated and presented in this paper. Nanocomposite containing 1.5 wt. % poly (vinyl butyral) and 0.5 wt. % f-MWCNT exhibited best thermal and mechanical properties (except flexural strength) among all the nanocomposites reported here. It showed ~5%, 27% and 126 % improvement in tensile strength, young’s modulus and impact strength respectively as compared to the neat novolac epoxy Kevlar composite.Nanocomposite containing 0.5 wt. % f- MWCNT and 2 More >

  • Open Access

    ARTICLE

    Microwave–Induced Thermo-Responsive Shape Memory Polyurethane/MWCNTs Composites and Improved their Shape Memory and Mechanical Properties

    KRISHAN KUMAR PATEL, RAJESH PUROHIT

    Journal of Polymer Materials, Vol.36, No.1, pp. 23-37, 2019, DOI:10.32381/JPM.2019.36.01.3

    Abstract Microwave (MV)-induced thermo-responsive shape memory thermoplastic polyurethane (SMTPU)/ MWCNT composites were prepared in micro-compounder. Composites containing different amount of multiwall Carbon nanotube (MWCNT) varying from 0 to 1.5 phr in SMTPU matrix were prepared. Maximum stretching strength, recovery force and tensile strength for 1.5 CNTPU (1.5 phr MWCNT in SMTPU matrix) was increased by 120%, 100% and 24% respectively as compared to SMTPU. MV-induced shape memory is a novel approach for fast, clean and remote heating during operation. MWCNT is strong absorber of microwave irradiation so that SMTPU/ MWCNTs nanocomposites successfully triggered by microwave. More >

  • Open Access

    ARTICLE

    Objets et relations spatiales composites et prise en compte du vague pour interpréter un référencement spatial indirect

    Mattia Bunel, Ana-Maria Olteanu-Raimond, Cécile Duchêne

    Revue Internationale de Géomatique, Vol.29, No.1, pp. 81-106, 2019, DOI:10.3166/rig.2019.00075

    Abstract Cet article propose une méthodologie destinée à transformer une description de position exprimée dans un référentiel indirect en une position absolue dans un référentiel direct. Cette problématique nécessite une formalisation des éléments de localisation relatifs, ici sous la forme d’un modèle en triplets, utilisé ensuite comme base de référencement, et un questionnement sur la prise en compte de l’imperfection du langage naturel dans le processus de modélisation. Nous proposons de faire appel aux objets spatiaux flous et nous comparons leurs implémentations afin d’identifier l’approche la plus adaptée au contexte du secours en montagne. More >

  • Open Access

    ARTICLE

    Nonlinear Micromechanical Modelling of Transverse Tensile Damage Behavior in Fiber-Reinforced Polymer Composites

    Nian Li*

    Structural Durability & Health Monitoring, Vol.13, No.4, pp. 331-346, 2019, DOI:10.32604/sdhm.2019.07521

    Abstract The investigation focusing on the mechanical behaviors at the microstructural level in composite materials can provide valuable insight into the failure mechanisms at larger scales. A micromechanics damage model which comprises the coupling of the matrix constitutive model and the cohesive zone (CZM) model at fiber-matrix interfaces is presented to evaluate the transverse tensile damage behaviors of unidirectional (UD) fiber-reinforced polymer (FRP) composites. For the polymeric matrix that exhibits highly non-linear mechanical responses, special focus is paid on the formulation of the constitutive model, which characterizes a mixture of elasticity, plasticity as well as damage.… More >

  • Open Access

    ARTICLE

    Electrochemical Performance of Starch-Polyaniline Nanocomposites Synthesized By Sonochemical Process Intensification

    Narsimha Pandi1, Shirish H. Sonawane1,*, Sarang P. Gumfekar2, Anand Kishore Kola1, Pramod H. Borse3, Swapnil B. Ambade4, Sripadh Guptha1, Muthupandian Ashokkumar5

    Journal of Renewable Materials, Vol.7, No.12, pp. 1279-1293, 2019, DOI:10.32604/jrm.2019.07609

    Abstract The present study deals with the intensified synthesis of starchpolyaniline (starch-PANI) nanocomposite using an ultrasound-assisted method. Starch is a key component in this nanocomposite, which acts as a backbone of the nucleation of PANI. The Electrochemical property of the nanocomposite arises due to the addition of PANI. This is one of green approach for the synthesis of bio nanocomposite using ultrasound. The crystallinity of the composite is evaluated using the Scherrer Formula. The starch-PANI nanocomposite was characterized by XRD, FT-IR, Raman, XPS and TEM. The composite nanoparticles show spherical morphology. The elemental composition of starch-PANI More >

  • Open Access

    ARTICLE

    Value-Added Utilization of Agro-Waste Derived Oil Palm Ash in Epoxy Composites

    Samsul Rizal1, Fizree, H. M.2, Chaturbhuj K. Saurabh3, Deepu A. Gopakumar2, N. A. Sri Aprilia4, D. Hermawan5, A. Banerjee6, Fazita M. R. M2, Haafiz M. K. M.2, Abdul Khalil H. P. S.2,*

    Journal of Renewable Materials, Vol.7, No.12, pp. 1269-1278, 2019, DOI:10.32604/jrm.2019.07227

    Abstract Oil palm ash (OPA) is an agro-industry waste and it has disposable problems. In the present study, an effort was made for value addition to OPA by incorporating it as a micro-filler in different concentration (0, 10, 20, 30, 40, and 50%) and sizes (100, 200, and 300 mesh size particles) in the epoxy matrix. Prepared micro OPA was having a crystallinity index of 65.4%, high inorganic elements, and smooth surface morphology. Fabricated composites had higher void content as compared to neat epoxy matrix. Mechanical properties of fabricated composites had a maximum value at 30%… More >

  • Open Access

    ARTICLE

    Material Selection of a Natural Fibre Reinforced Polymer Composites using an Analytical Approach

    M. Noryani1, 3, 5, S. M. Sapuan1, 2,*, M. T. Mastura4, 5, M. Y. M. Zuhri1, E. S. Zainudin1

    Journal of Renewable Materials, Vol.7, No.11, pp. 1165-1179, 2019, DOI:10.32604/jrm.2019.07691 - 14 July 2021

    Abstract Material selection has become a critical part of design for engineers, due to availability of diverse choice of materials that have similar properties and meet the product design specification. Implementation of statistical analysis alone makes it difficult to identify the ideal composition of the final composite. An integrated approach between statistical model and micromechanical model is desired. In this paper, resultant natural fibre and polymer matrix from previous study is used to estimate the mechanical properties such as density, Young’s modulus and tensile strength. Four levels of fibre loading are used to compare the optimum More >

  • Open Access

    ARTICLE

    Development of Biocomposites of MCC Extracted From Non-Wood Sources

    T. Dipin1, T. V. Jinitha1, E. Purushothaman1,*

    Journal of Renewable Materials, Vol.7, No.11, pp. 1109-1119, 2019, DOI:10.32604/jrm.2019.07636 - 14 July 2021

    Abstract The present work mainly focuses on the estimation of various components and the extraction of microcrystalline cellulose (MCC) from non- wood sources like Country Almond/Badam shell through acid hydrolysis. This hydrolyzed MCC was successfully used as reinforcement for development of biocomposites. Country Almond/Badam trees are found all over Kerala, India and they give nuts once in a year. Usually the nut shells are discarded and are becoming one of the sources of agricultural waste. During this investigation various components were isolated from the Country Almond shells and they were characterised using different spectral and analytical… More >

  • Open Access

    ARTICLE

    Biocomposites Based on Thermoplastic Starch and Granite Sand Quarry Waste

    María G. Passaretti1,2,*, Mario D. Ninago3,4, Cecilia I. Paulo5, Horacio A. Petit5, Edgardo F. Irassarc5, Daniel A. Vega6, Marcelo A. Villar1,2, Olivia V. López1

    Journal of Renewable Materials, Vol.7, No.4, pp. 393-402, 2019, DOI:10.32604/jrm.2019.04281

    Abstract Granite stone is a by-product of the rock crushing manufacturing. An industrial waste in powder form that causes health problems and environmental pollution. Fine particles fraction can be used as a partial replacement of sand in concrete manufacture. In this work, an alternative exploitation of this waste fraction is proposed. Granite sand (GS) with particles mean size of ~1 μm was employed as thermoplastic starch (TPS) filler at different concentrations. Biocomposites were obtained by melt-mixing and thermo-compression, achieving translucent and easy to handle films. A good GS dispersion within the matrix was evidenced by SEM. More >

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