Weijun Yang^1†, Xiaomin Zhao^2†, Elena Fortunati¹, Franco Dominici¹, Jose M. Kenny¹, Debora Puglia^1*, De-Yi Wang^2*

Journal of Renewable Materials, Vol.5, No.5, pp. 423-434, 2017, DOI:10.7569/JRM.2017.634146

Abstract Presented herein is a deep investigation of the fire, mechanical and thermal performances of poly(lactic acid) (PLA)-based nanocomposites, which were obtained by combining cellulose nanocrystals (CNC) with various contents of N,N’-diallyl-phenylphosphoricdiamide (P-AA) via a two-steps masterbatch melt extrusion process (glycidyl methacrylate grafting on PLA and CNC premixing with PLA). Results have shown that the value of the limiting oxygen index (LOI) increased to 28.8% and a V-0 rating in UL94 test was obtained when 2 wt% of P-AA was added in the presence of cellulose nanocrystals (3 wt%). The incorporation of CNC induced a decrease More >

Liqing Wei¹, Shupin Luo², Armando G. McDonald², Umesh P. Agarwal¹, Kolby C. Hirth¹, Laurent M. Matuana³, Ronald C. Sabo^1* , Nicole M. Stark^1*

Journal of Renewable Materials, Vol.5, No.5, pp. 410-422, 2017, DOI:10.7569/JRM.2017.634144

Abstract Cellulose nanocrystals (CNCs) are renewable and sustainable filler for polymeric nanocomposites. However, their high hydrophilicity limits their use with hydrophobic polymer for composite materials. In this study, freeze-dried CNCs were modified by transesterification with canola oil fatty acid methyl ester to reduce the hydrophilicity. The transesterified CNCs (CNCFE) were compounded with PLA into nanocomposites. CNCFE with long-chain hydrocarbons plays a role as plasticizer. Increasing CNCFE loadings resulted in clear plasticizing effects. Lower Tg and Tm were achieved for CNCFE-based nanocomposites. Plasticizing nanocomposite melt with CNCFE can mitigate the degradation of CNCs during thermal processing. The More >

Samantha Andrade Vale de Sousa¹, Mercês Coelho da Silva², Orlando Gama da Silva Júnior³, Artur Caron Mottin⁴, Rodrigo Lambert Oréfice³, Eliane Ayres^1*

Journal of Renewable Materials, Vol.5, No.3-4, pp. 251-257, 2017, DOI:10.7569/JRM.2017.634115

Abstract Buriti or miriti (Mauritia flexuosa) is a palm tree found in the Brazilian cerrado. Herein buriti petiole, part of the trunk that supports the leaves, was ground and used without any treatment as low density load to prepare poly(lactic acid) biocomposites. X-ray microtomography of buriti petiole showed its porous structure, with a wide pore size distribution determined with the aid of SEM. The obtained biocomposites with 1, 5 and 10 wt% of buriti petiole particles were investigated by their sessile drop contact angle, FTIR, TGA and tensile test. The tensile properties indicated poor adhesion between More >

F. Luzi¹, E. Fortunati^1*, A. Jiménez², D. Puglia¹, A. Chiralt², L. Torre¹

Journal of Renewable Materials, Vol.5, No.2, pp. 103-115, 2017, DOI:10.7569/JRM.2016.634135

Abstract Poly(lactic acid) (PLA) based nanocomposites reinforced with 1 wt% of surfactant-modified cellulose nanocrystals (s-CNC) extracted from Posidonia oceanica plant waste and zinc oxide nanoparticles (ZnO NPs) at different concentrations (0.1 and 0.5 wt%) were prepared by solvent casting process. Their thermal, morphological, optical, mechanical and water vapor permeability properties were investigated. Tensile testing showed increased values for strength and deformation at break in PLA based formulations reinforced with s-CNC and ZnO NPs as a consequence of better nanofiller dispersion compared to binary films reinforced only with ZnO NPs. Moreover, the effect of s-CNC and ZnO More >

Jose Luis Orellana, Michael Mauhar, Christopher L. Kitchens^*

Journal of Renewable Materials, Vol.4, No.5, pp. 340-350, 2016, DOI:10.7569/JRM.2016.634126

Abstract Polylactic acid (PLA) is one of the most widely used biodegradable polymers due to the ability to synthesize it economically at industrial scale and its favorable properties for many consumer products. However, the rigid nature of PLA is not desirable for specific applications, requiring the incorporation of effective bioderived additives in order to enhance the PLA toughness and broaden applications. In this work, PLA was modified by graft polymerization of polyacrylic acid (PLA-g-PAA) to increase the hydrophilicity to promote compatibilization of cellulose nanocrystals (CNCs) or high molecular polyethylene glycol (PEG). CNCs were found to act More >

Juan P. Correa^1,2*, Alejandro Bacigalupe^2,3, Jorge Maggi⁴, Patricia Eisenberg^2,3

Journal of Renewable Materials, Vol.4, No.4, pp. 258-265, 2016, DOI:10.7569/JRM.2016.634117

Abstract Poly(lactic acid)/poly(butylene adipate-co-terephthalate) (PLA/PBAT)-based nanocomposites were prepared by melt blending of PLA and PBAT with 5 wt% of unmodified (Cloisite Na) and modified (Cloisite 30B) montmorillonites. X-ray diffraction (XRD) revealed an intercalated structure in both nanocomposites. The extent of the intercalation was higher for nanocomposites based on modified clays (OMMT) with chemical affinity with the polymer matrix. Rheological measurements have shown an increase in viscosity and a better degree of clay dispersion for nanocomposites containing OMMT. Nanocomposites with OMMT showed lower PBAT separated phase particle size and improvements in thermal stability, mechanical properties and water More >

Sudhakar Muniyasamy^1,2, Osei Ofosu^1,2, Maya Jacob John^1,2, Rajesh D. Anandjiwala^1,2*

Journal of Renewable Materials, Vol.4, No.2, pp. 133-145, 2016, DOI:10.7569/JRM.2016.634104

Abstract The present study investigates the mineralization of poly(lactic acid) (PLA) and poly(3-hydroxybutyrate-covalerate) (PHBV), and PLA/PHBV blend in compost and soil burial environments. The mineralization was assayed on the basis of carbon dioxide (CO2) release from the test materials incubated in compost and soil for a period of 200 days. The degradation was followed by means of fragmentation, thermogravimetric (TGA), FTIR spectroscopy and scanning electron microscopy (SEM) analyses. The results showed that PLA, PHBV and blend of PLA/PHBV achieved almost 90% biodegradation under composting conditions, while PHBV, PLA/PHBV blend and PLA respectively achieved only 35%, 32% More >

Xiaoqing Zhang^*, Simon Schmidt^φ, Nick Rigopoulos, Januar Gotama, Eustathios Petinakis

Journal of Renewable Materials, Vol.3, No.2, pp. 91-100, 2015, DOI:10.7569/JRM.2014.634135

Abstract The behavior of a biodegradable CO₂ -based polymer polypropylene carbonate (PPC) as polymer matrix of wood fi ber (WF) composites was examined and compared with that of using poly(lactic acid) (PLA) as the matrix. The PPC/WF composites displayed poor mechanical properties as compared to PLA/WF composites because PPC is an amorphous polymer with low T_g and poor thermal stability. However, when PPC was used in conjunction with PLA in WF composites, the mechanical strength and modulus of the composites could match or even exceed the level of PLA/WF composites. The strong intermolecular interactions between PPC and More >

David Grewell^1,*, Gowrishankar Srinivasan¹, Eric Cochran²

Journal of Renewable Materials, Vol.2, No.3, pp. 157-165, 2014, DOI:10.7569/JRM.2014.634112

Abstract Presented in this study is a novel recycling strategy for poly(lactic acid) (PLA) in which the depolymerization is rapidly promoted by the base-catalyzed hydrol-/alcohol-ysis of the terminal ester bonds under mild conditions. Post-consumer PLA water bottles were cut into approximately 6 x 2 mm plastic chips and heated to 50–60o C in water, ethanol, or methanol as the depolymerization medium. A variety of carbonate salts and alkaline metal oxides were screened as potential catalysts. High-power ultrasound was also investigated as a means to accelerate the PLA decomposition. Both mass loss and HPLC analysis of the More >

Hedieh Teymoorzadeh¹, Denis Rodrigue^2,*

Journal of Renewable Materials, Vol.2, No.4, pp. 270-277, 2014, DOI:10.7569/JRM.2014.634127

Abstract This work investigates the effect of the addition of fl ax fi ber (15, 25, and 40 wt%) on the mechanical, morphological, rheological, and thermal properties of polylactic acid (PLA). In the fi rst step, no coupling agent was used to produce fully biodegradable and biobased composites. In particular, fl exural tests were performed on the composites to evaluate their mechanical properties, while density, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and rheological tests were also carried out. Scanning electron microscopy images (SEM) show good fl ax fi ber dispersion in the PLA matrix along More >