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  • Open Access

    ARTICLE

    Novel C/MoS2 hollow nanocomposites enhance lithium storage in battery anodes

    J. Liua, Y. X. Liub, J. N. Dingb, W. Yanb, Y. C. Weib, J. Xub,*

    Chalcogenide Letters, Vol.21, No.7, pp. 499-511, 2024, DOI:10.15251/CL.2024.217.499

    Abstract With society's rapid progress, there is an increasing need for electricity among individuals, but the prevailing source of electricity is still mainly obtained through the burning of nonrenewable fossil fuels, which are not renewable and pose serious environmental hazards. Lithium-ion batteries are used widely for excellent rechargeable capabilities and high energy density. Recently, researchers have become increasingly interested in transition metal sulfides owing to their cost-effectiveness and remarkable specific capacity. However, their commercialization has been hindered by the expansion of material volume and low electrical conductivity during charging and discharging. We have successfully designed and More >

  • Open Access

    ARTICLE

    Electrochemical analysis on SnSeO3/ZnSeO3 nanocomposite

    N. G. Basil Ralpha, S. Shanmugha Soundareb, D. Yamunaa, S. Ariponnammala,*

    Chalcogenide Letters, Vol.21, No.9, pp. 729-746, 2024, DOI:10.15251/CL.2024.219.729

    Abstract Nanocomposite SnSeO3/ZnSeO3 has been synthesized by hydrothermal method. X-ray powder diffraction confirms formation of SnSeO3/ZnSeO3 nanocomposite. It exhibits an interesting morphology of needle like nanorod structure. Thermal analysis reveals the thermal stability, decomposition behavior and critical temperatures where significant weight loss occurs. X-ray photoemission explains the role of the chemical state Sn, Zn, Se and O in SnSeO3/ZnSeO3. Electrochemical study has been made in both three electrode and two electrode system. In three electrode system, cyclic voltammetry exhibits a bell-shaped curve and the operational potential window is 0.8 V. The specific capacitance is 78.65 F/g for 5… More >

  • Open Access

    ARTICLE

    MoS2-CZTS: a 2D-3D nanocomposite to enhance the photocatalytic performance in degradation of methylene blue dye

    R. N. Mondala,b,*, S. Sahab1

    Chalcogenide Letters, Vol.21, No.10, pp. 771-783, 2024, DOI:10.15251/CL.2024.2110.771

    Abstract Cu2ZnSnS4 nanocrystals (CZTS NCs), MoS2 nanosheet (NS) and MoS2-CZTS nanocomposite (NC) have been synthesized using solvothermal route. Structural characterization of samples have been done by XRD, Raman spectroscopy, HR-TEM. Samples have optically characterized by UV-Vis absorption, photoluminescence (PL) and time co-related single photon counting (TCSPC) study. The XRD, HR-TEM and Raman spectroscopy established tetragonal kesterite phase for both CZTS NCs and MoS2-CZTS NC. Enhancement of efficiency of CZTS NCs to degrade methylene blue (MB) dye, illuminated by visible light, have been observed by loading 1 wt.% MoS2 NS and found to be ~100% in only 15 minutes. More >

  • Open Access

    ARTICLE

    Nanocomposites of reduced graphen oxideand cadimium sulfide(rGO/CdS) as affective photoanode for dye sentisized solar cells(DSSCs) by doctor blade deposition technique

    Z. J. Kadhima, O. A. Hatemb,*, D. M. Al Khafafc

    Chalcogenide Letters, Vol.21, No.11, pp. 945-952, 2024, DOI:10.15251/CL.2024.2111.945

    Abstract The synthesis and characterization of reduced graphene oxide/cadmium sulfide (rGO/CdS) are the primary topics covered in this paper. The construction of a photoanode in dyesensitized solar cells (DSSCs) using synthetic materials is subsequently proposed. Here, graphene oxide (GO) was synthesized using the Hummer's method, and green tea leaves were employed to reduce GO. The rGO/CdS nanocomposites were prepared using a hydrothermal method. A photoanode was fabricated from the as-prepared rGO/CdS nanocomposite paste using doctor blade deposition techniques.
    The performance of the fabricated DSSCs was evaluated using current density-voltage (JV) curves. Transmission electron microscopy (TEM), X-ray… More >

  • Open Access

    ARTICLE

    Probing SnSO3/ZnSO3 nanocomposites by optical and magnetic perspective

    R. Gayathria, S. Shanmugha Soundareb, K. Harithaa, S. Ariponnammala,*

    Chalcogenide Letters, Vol.21, No.12, pp. 1001-1009, 2024, DOI:10.15251/CL.2024.2112.1001

    Abstract SnSO3/ZnSO3 nanocomposite has been synthesized using the hydrothermal process. The complete formation of the SnSO3/ZnSO3 nanocomposite is confirmed by XRD and EDAX. It displays a fascinating rectangular bar shape. The measured particle size is 100.4 nm. It will be a promising option for optoelectronic devices. Energy gap of the SnSO3/ZnSO3 nanocomposite is 5.85 eV. The refractive index of the nanocomposite through its energy gap is found to be 1.883. The ultraviolet (~387.2 nm) area of the PL emission spectrum exhibits the strong efficient emission, while the green (~522.1 nm) region and the red (~789.4 nm) region show More >

  • Open Access

    ARTICLE

    Bio-Nanocomposites Based on Polyvinyl Alcohol and Fuller Earth Nanoclay: Preparation, Properties and Its Application in Food Packaging

    Yvonne Achieng Ouma1, Supriti Sundari Nayak1, Smrutirekha Mishra2, Harekrishna Panigrahi1,*

    Journal of Polymer Materials, Vol.41, No.4, pp. 281-297, 2024, DOI:10.32604/jpm.2024.056470 - 16 December 2024

    Abstract Fuller earth (FE) nanoclay is a naturally occurring mineral with a high surface area, is highly abundant, and has a low purchasing cost, making it an excellent candidate for nanocomposite production. The study highlights the novelty of using FE nanoclay in combination with polyvinyl alcohol (PVA) to create a bio-nanocomposite that meets the need for sustainable packaging solutions, underscoring its potential to reduce environmental impact while maintaining product quality in food packaging applications. The solvent casting process, a reliable way to evenly disperse nanofillers in polymer matrices, has been employed in this work to incorporate… More >

  • Open Access

    ARTICLE

    Impact Behaviour of Hybrid Jute/Epoxy Composites at Different Temperature Conditions

    Somasundaram Karthiyaini1, Mohan Sasikumar2,*, Abraham Jebamalar3, P. A. Prasob2

    Journal of Polymer Materials, Vol.41, No.4, pp. 219-237, 2024, DOI:10.32604/jpm.2024.053829 - 16 December 2024

    Abstract This manuscript presents the projectile impact behavior of hybrid jute/epoxy composite laminates using an instrumented air gun impact setup with the projectile moving in the vertical direction. An approach based on the stiffness change is used to predict the projectile impact response of hybrid jute epoxy-filled laminates impacted with a stainless-steel projectile. The experimental validation of the parameters like dynamic hardness (Hd) coefficient of restitution (COR), natural frequency, damping factor, and loss factor was used to analyze the impact behavior of jute/epoxy composites strengthened with fillers ZrO2, ZnO, and TiO2. The free vibration tests of the More >

  • Open Access

    ARTICLE

    Encapsulation of Clove Oil Nanoemlusion in Chitosan-Based Nano-Composite: In Vitro and in Vivo Antifungal Activity against Rhizoctonia solani and Sclerotium rolfsii

    Ahmed Mahmoud Ismail1,2,3,*, Eman Said Elshewy3, Isra H. Ali4,5, Naglaa Abd Elbaki Sallam Muhanna3, Eman Yehia Khafagi3

    Phyton-International Journal of Experimental Botany, Vol.93, No.11, pp. 2787-2811, 2024, DOI:10.32604/phyton.2024.057518 - 30 November 2024

    Abstract Rhizoctonia solani Kühn and Sclerotium rolfsii Sacc. are the primary soil-borne plant diseases responsible for significant reductions in global crop yields. The primary goal of this study was to investigate the antifungal potentials of clove essential oil (CEO), nanoemulsion form (CEONE) and chitosan/nanoemulsion nanocomposite (CS/CEONE) against R. solani and S. rolfsii through in vitro and in vivo trials. Both CEONE and CS/CEONE were prepared and investigated for their physical chemical and morphological characterization. The poisoned medium method was utilized to evaluate the inhibitory effects of CEO, CEONE and CS/CEONE on the mycelial growth and enzymatic activity of R. solani and S. rolfsii. The… More >

  • Open Access

    PROCEEDINGS

    Multiscale Modeling and Application of Strain-Dependent Piezoresistive Behavior in Porous MWCNT/Polymer Nanocomposites

    Zefu Li1, Weidong Yang1,*

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.29, No.1, pp. 1-1, 2024, DOI:10.32604/icces.2024.011671

    Abstract For composite materials incorporating porous structures with multi-walled carbon nanotubes (MWCNTs), the effects of pores and MWCNT agglomeration significantly impact electrical conductivity. Theoretical modeling of the piezoresistive behavior is crucial for understanding the electromechanical response of porous MWCNT/polymer nanocomposites. Currently, there is limited theoretical modeling that considers the combined effects of porosity and MWCNT agglomeration on the electrical conductivity and piezoresistive performance of porous MWCNT/polymer composites. Addressing this gap, this paper presents a multiscale modeling approach for the strain-dependent piezoresistive behavior of porous MWCNT/polymer nanocomposites. The model considers the influence of porosity and MWCNT agglomeration, More >

  • Open Access

    ARTICLE

    Quasi-Static and Low-Frequency Dynamic Mechanical Analysis Characterization of Graphene Nanoplatelets/Glass Fabric/Bisphenol-A-Based Epoxy Nanocomposites

    Santhanakrishnan Mamallan1, Venkateshwaran Narayanan1,*, Canungo Bhimarao Ragothaman2

    Journal of Polymer Materials, Vol.41, No.3, pp. 105-116, 2024, DOI:10.32604/jpm.2024.056744 - 30 September 2024

    Abstract Glass fabric/polymer composites are widely used in various industrial applications due to their lightweight, exceptional strength, and fatigue resistance. Graphene nanoplatelets, a recently developed type of carbon material, stand out as unique nanofillers due to their 2D quantum confinement and expansive surface area within a polymer matrix. These features make them more effective than traditional carbon nanofillers at enhancing a range of properties. In this study, 3-weight % of graphene nanoplatelets with epoxy resin were used for investigation by varying sonication durations (0, 20, 40, and 60 min) using an ultrasonic bath sonicator. The laminates More >

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