Narsimha Pandi¹, Shirish H. Sonawane^1,*, Sarang P. Gumfekar², Anand Kishore Kola¹, Pramod H. Borse³, Swapnil B. Ambade⁴, Sripadh Guptha¹, Muthupandian Ashokkumar⁵

Journal of Renewable Materials, Vol.7, No.12, pp. 1279-1293, 2019, DOI:10.32604/jrm.2019.07609

Abstract The present study deals with the intensified synthesis of starchpolyaniline (starch-PANI) nanocomposite using an ultrasound-assisted method. Starch is a key component in this nanocomposite, which acts as a backbone of the nucleation of PANI. The Electrochemical property of the nanocomposite arises due to the addition of PANI. This is one of green approach for the synthesis of bio nanocomposite using ultrasound. The crystallinity of the composite is evaluated using the Scherrer Formula. The starch-PANI nanocomposite was characterized by XRD, FT-IR, Raman, XPS and TEM. The composite nanoparticles show spherical morphology. The elemental composition of starch-PANI More >

Junbo Wang^*, Leiting Dong

The International Conference on Computational & Experimental Engineering and Sciences, Vol.21, No.4, pp. 75-75, 2019, DOI:10.32604/icces.2019.04820

Abstract In this study, two/three-dimensional computational grains are developed for micromechanical modeling of heterogeneous materials with nanoscale inhomogeneities, considering the interface stress effect. Two types of computational grains are developed, depending on the types of inhomogeneity in each element. Each computational grain can include alternatively a spherical void or a spherical elastic inclusion. In these computational grains, an inter-element compatible displacement field is assumed along the element outer-boundary, and interior displacement fields in the matrix as well as in the inclusion are independently assumed as T-Trefftz trial functions. For planar problems, complex potentials are used to… More >

Kahina Iggui^1,2,*, Mustapha Kaci¹, Mohamed Mahlous³, Nicolas Le Moigne⁴, Anne Bergeret⁴

Journal of Renewable Materials, Vol.7, No.9, pp. 807-820, 2019, DOI:10.32604/jrm.2019.06778

Abstract In this paper, the effects of gamma irradiation on Cast poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) and PHBV/Cloisite 30B (C30B) (3 wt%) bionanocomposite prepared by melt compounding, were evaluated at various doses, i.e., 5, 15, 20, 50 and 100 kGy at room temperature in air. Changes in molecular weight, morphology and physical properties were investigated. The study showed that the main degradation mechanism occurring in gamma irradiation in both Cast PHBV and C-PHBV/3C30B bionanocomposite is chain scission, responsible for the decrease of molecular weight. Differential scanning calorimetry (DSC) data indicated a regular decrease in crystallization temperature, melting temperature and… More >

Le Van Hai^1,2, Lindong Zhai¹, Hyun Chan Kim¹, Jung Woong Kim¹, Jaehwan Kim^1,*

Journal of Renewable Materials, Vol.7, No.7, pp. 621-629, 2019, DOI:10.32604/jrm.2019.06466

Abstract This paper reports green nanocomposites made by blending polyvinyl alcohol (PVA) with cellulose nanofiber (CNF) isolated from recycled deinked copy/printing paper (DIP). The reinforcement effect of DIPCNF in the nanocomposites is compared with other CNFs isolated from native cotton and hardwood by means of TEMPO-oxidation. The prepared PVA-CNF nanocomposites are characterized in terms of morphology, chemical interaction, structural, thermal and mechanical properties. X-ray diffraction and Fourier transform infrared spectroscopy confirm the reinforcing ability of cellulose nanofibers into PVA. By blending CNFs into PVA matrix, the thermal stability of the nanocomposites is improved and DIPCNF shows More >

Marcia Cristina Branciforti^1,*, Caroline Faria Bellani², Carolina Lipparelli Morelli², Alice Ferrand³, Nadia Benkirane-Jessel³, Rosario Elida Suman Bretas²

Journal of Renewable Materials, Vol.7, No.3, pp. 269-277, 2019, DOI:10.32604/jrm.2019.01833

Abstract Although nanocomposites have recently attracted special interest in the tissue engineering area, due to their potential to reinforce scaffolds for hard tissues applications, a number of variables must be set prior to any clinical application. This manuscript addresses the evaluation of thermo-mechanical properties and of cell proliferation of cellulose nanocrystals (CNC), poly(butylene adipate-co-terephthalate) (PBAT), poly(ε-caprolactone) (PCL) films and their bionanocomposites with 2 wt% of CNC obtained by casting technique. Cellulose nanocrystals extracted from Balsa wood by acid hydrolysis were used as a reinforcing phase in PBAT and PCL matrix films. The films and pure CNC… More >

Larissa Stieven Montagna, Isabela CÉSAR Oyama, Rita de CÁSSIA Barbosa Camargo Lamparelli, Ana Paula Silva, THAÍS Larissa do Amaral Montanheiro, Ana Paula Lemes^*

Journal of Renewable Materials, Vol.7, No.2, pp. 117-128, 2019, DOI:10.32604/jrm.2019.00036

Abstract Biodegradable polymers have been increasingly used for scientific and commercial applications because they are similar to some conventional thermoplastics and exhibit the ability of self-degradation. Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) nanocomposites films with 1 and 2 wt% of carbon nanotubes (CNT) were prepared by solution mixing, followed by solvent evaporation. In this work, PHBV/CNT nanocomposites were submitted to biodegradation in an aqueous medium for 34 days through a respirometric system. Then, the PHBV films were analyzed by the CO2 production and mineralization as a response of a microbial attack, which was monitored by back titration during all the… More >

Samir Kamel^1,*, Ahmed A. Haroun², Amany M. El-Nahrawy³, Mohamed A. Diab¹

Journal of Renewable Materials, Vol.7, No.2, pp. 193-203, 2019, DOI:10.32604/jrm.2019.00144

Abstract In this work, conducting composites of nanocellulose (NC)/polypyrrole nanoparticles (NPPy) and silver nanoparticles (AgNPs), i.e., NC/NPPyAg, were synthesized for the first time, to the best of our knowledge, via in situ emulsion polymerization of pyrrole in the presence of surfactant dopants. The AgNPs acted as an oxidizing agent to simultaneously incorporate nanoparticles into the prepared composites. The structures and morphologies of the prepared composites were studied using Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), UV-Vis Spectra, thermogravimetric analysis (TGA), and scanning and transmission electron microscopy (SEM and TEM) techniques. Additionally, the prepared composites were characterized More >

B. Benobeidallah¹, A. Benhamida¹, A. Dorigato^2,*, A. Sola³, M. Messori³, A. Pegoretti²

Journal of Renewable Materials, Vol.7, No.1, pp. 89-102, 2019, DOI:10.32604/jrm.2019.00136

Abstract Various amounts (up to 10 wt%) of palygorskite nanofibers functionalized by 3-aminopropyltriethoxysilane (APTES) coupling agent were used to reinforce polyamide 11 nanocomposites prepared by melt compounding. The covalent bonding of the silane on the palygorskite surface was confirmed by infrared spectroscopy and thermogravimetric analysis. X-ray diffraction revealed the retention of the α-form of polyamide crystals upon the addition of both natural and silane treated palygorskite nanorods. All the investigated nanocomposites showed an improvement of the thermal stability, especially when surface treated palygorskite nanofibers were considered. Tensile tests and dynamic mechanical thermal analyses on the prepared More >

Xiaojian Zhou^1,2, Hui Wang¹, Jun Zhang², Zhifeng Zheng¹, Guanben Du^1,2,*

Journal of Renewable Materials, Vol.6, No.1, pp. 68-74, 2018, DOI:10.7569/JRM.2017.634150

Abstract Pineapple leaf nanofibers (PLNFs) extracted from pineapple leaf fiber were used for reinforcing biobased polyurethane foam (BPU). The dispersion performance of PLNF in the foaming mixture system, nanocomposite foaming behavior, cell morphology, cell size, density, compressive strength and dimensional stability were investigated. The viscosity of the mixtures increased with increasing the PLNF content. The addition of a tiny amount of PLNF did not influence the exothermic temperature of the foam system, but reduced the expansion and gel time of the nanocomposite foams. This reduced time was found to increase the production efficiency. Scanning electron More >

Sawsan Dacrory^1*, Hussein Abou-Yousef¹, Ragab E. Abou-Zeid¹, Samir Kamel¹, Mohamed S. Abdel-Aziz², Mohamed Elbadry³

Journal of Renewable Materials, Vol.6, No.5, pp. 536-547, 2018, DOI:10.7569/JRM.2017.634190

Abstract Carboxymethyl cellulose hydrogels were developed through crosslinking process using eco-friendly crosslinkers such as maleic, succinic, and citric acids. Carboxymethyl cellulose was prepared from the cellulosic fraction of olive industry residues. A series of hydrogels with varying crosslinker acid concentrations, reaction times, and reaction temperatures was produced to study the swelling capacities and gel fraction of the obtained hydrogels. Additional study pertains to the preparation of antimicrobial nanocomposite hydrogels through in-situ incorporation of the silver nanoparticles during the crosslinking reaction. Silver nanoparticles were prepared by reduction of AgNO3with leaves of Ricinus communis. The particle size of More >