Jithin Joy^1,2,3, Cintil Jose³, Srirama B. Varanasi⁴, Lovely Mathew P.^2,3, Sabu Thomas², Srikanth Pilla^1,5*

Journal of Renewable Materials, Vol.4, No.5, pp. 351-364, 2016, DOI:10.7569/JRM.2016.634128

Abstract Isora nanofibers (INF) were produced by a combined thermal-chemical-mechanical method from Helicteres isora plant. The resulting fibers were analyzed using transmission electron microscopy and scanning electron microscopy, which showed a network-like structure with a length of 600 nm, width of 50 nm and an aspect ratio of 12. Fourier transform infrared spectroscopy indicated that chemical treatments progressively removed noncellulosic constituents. X-ray diffraction analysis revealed that crystallinity increased with successive chemical treatments. Using the synthesized isora nanofibers, poly(butylene succinate) (PBS)-based biodegradable nanocomposites were prepared. The nanocomposites were processed using a Brabender twin-screw compounder and an injection molding machine. Effects of INF… More >

Jose Luis Orellana, Michael Mauhar, Christopher L. Kitchens^*

Journal of Renewable Materials, Vol.4, No.5, pp. 340-350, 2016, DOI:10.7569/JRM.2016.634126

Abstract Polylactic acid (PLA) is one of the most widely used biodegradable polymers due to the ability to synthesize it economically at industrial scale and its favorable properties for many consumer products. However, the rigid nature of PLA is not desirable for specific applications, requiring the incorporation of effective bioderived additives in order to enhance the PLA toughness and broaden applications. In this work, PLA was modified by graft polymerization of polyacrylic acid (PLA-g-PAA) to increase the hydrophilicity to promote compatibilization of cellulose nanocrystals (CNCs) or high molecular polyethylene glycol (PEG). CNCs were found to act as a nucleating agent for… More >

Juan P. Correa^1,2*, Alejandro Bacigalupe^2,3, Jorge Maggi⁴, Patricia Eisenberg^2,3

Journal of Renewable Materials, Vol.4, No.4, pp. 258-265, 2016, DOI:10.7569/JRM.2016.634117

Abstract Poly(lactic acid)/poly(butylene adipate-co-terephthalate) (PLA/PBAT)-based nanocomposites were prepared by melt blending of PLA and PBAT with 5 wt% of unmodified (Cloisite Na) and modified (Cloisite 30B) montmorillonites. X-ray diffraction (XRD) revealed an intercalated structure in both nanocomposites. The extent of the intercalation was higher for nanocomposites based on modified clays (OMMT) with chemical affinity with the polymer matrix. Rheological measurements have shown an increase in viscosity and a better degree of clay dispersion for nanocomposites containing OMMT. Nanocomposites with OMMT showed lower PBAT separated phase particle size and improvements in thermal stability, mechanical properties and water vapor barrier when compared with… More >

Itxaso Algar¹, Clara Garcia-Astrain¹, Alba Gonzalez², Loli Martin³, Nagore Gabilondo¹, Aloña Retegi^1*, Arantxa Eceiza^1*

Journal of Renewable Materials, Vol.4, No.1, pp. 57-65, 2016, DOI:10.7569/JRM.2015.634124

Abstract Bacterial cellulose/montmorillonite (BCMMT) hybrid bionanocomposite membranes were prepared by in-situ assembling or one-step biosynthesis process. The presence of MMT in BC membranes was confi rmed by thermogravimetric analysis and quantifi ed by mass spectrometry, resulting in bionanocomposites with MMT contents between 7–13 wt%. The incorporation of MMT during BC biosynthesis modifi ed BC morphology and led to lower porosity, even though higher water holding capacity was achieved. Bionanocomposites showed improved thermal stability and water vapor and oxygen gas barrier properties up to 70 and 80% with respect to neat BC membranes. This improvement was related to the tortuous path of… More >

G. Lasko^∗, I. Schäfer^∗, Z. Burghard^†, J. Bill^†, S. Schmauder^∗, U. Weber^∗, D. Galler^‡

Molecular & Cellular Biomechanics, Vol.10, No.1, pp. 27-42, 2013, DOI:10.3970/mcb.2013.010.027

Abstract Owing to the apparent simple morphology and peculiar properties, nacre, an iridescent layer, coating of the inner part of mollusk shells, has attracted considerable attention of biologists, material scientists and engineers. The basic structural motif in nacre is the assembly of oriented plate-like aragonite crystals with a ’brick’ (CaCO₃ crystals) and ’mortar’ (macromolecular components like proteins) organization. Many scientific researchers recognize that such structures are associated with the excellent mechanical properties of nacre and biomimetic strategies have been proposed to produce new layered nanocomposites. During the past years, increasing efforts have been devoted towards exploiting nacre’s structural design principle in… More >

Kunigal N.Shivakumar¹, Shivalingappa Lingaiah², Robert Sadler², Matthew Sharpe²

CMC-Computers, Materials & Continua, Vol.1, No.4, pp. 309-318, 2004, DOI:10.3970/cmc.2004.001.309

Abstract The exfoliation and dispersion of nanoclay (2% by weight) and nanovermiculite (2% by weight) particles in a polymer matrix is analyzed using the Scanning Electron Microscope (SEM) after a low temperature air plasma etch. The plasma etch preferentially removes the polymer to expose the nanoparticles. Both Argon and air have been used as the etching media to study the etching process. SEM analysis illustrate the results of the etching in flat and edge surfaces of both nanoclay (MMT) and nanovermiculite (VMT) filled polymer. Both the MMT and VMT were dispersed using a IKA high shear mixer and a Sonicator. More >

Shasha Yang¹, Shuling Hu¹, Shengping Shen^1,2

CMC-Computers, Materials & Continua, Vol.29, No.3, pp. 279-298, 2012, DOI:10.3970/cmc.2012.029.279

Abstract Due to the large ratio of surface area to volume in nanoscale objects, the property of surfaces and interfaces likely becomes a prominent factor in controlling the behavior of nano-heterogeneous materials. In this work, based on the Gurtin-Murdoch surface/interface elastic theory, a distinct expression is derived for embedded nano-inclusion in an infinite piezoelectric matrix coupled with interface effect. For the problem of a spherical inclusion in transversely isotropic piezoelectric medium, we reach a conclusion that the elastic and electric field are uniform when eigen-strain and eigen-electric field imposed on the inclusion are uniform even in the presence of the interface… More >

J. Zidek^1,2, J. Kucera¹, J. Jancar^1,2

CMC-Computers, Materials & Continua, Vol.28, No.3, pp. 213-230, 2012, DOI:10.3970/cmc.2012.028.213

Abstract The paper presents a combination of worm-like chain numerical models and one with a finite set of nano-particles. The primary objective of the models was to analyze the distribution of space in a system filled by particles. Information on the distribution of space was compared to properties of chains inside the set of particles. The set of nanoparticles was constructed with a tool generating a finite set of particles that is randomly distributed in a given space. The particles have a prescribed volume fraction and uniform size. First, the proportions of chains and particles were compared. The length of chain… More >

B.J. Yang¹, K.J. Cho¹, G.M. Kim¹, H.K. Lee^1,2

CMES-Computer Modeling in Engineering & Sciences, Vol.103, No.5, pp. 343-365, 2014, DOI:10.3970/cmes.2014.103.343

Abstract The addition of carbon nanotubes (CNTs) to a matrix material is expected to lead to an increase in the effective electrical properties of nanocomposites. However, a CNT entanglement caused by the matrix viscosity and the high aspect ratio of the nanotubes often inhibits the formation of a conductive network. In the present study, the micromechanics-based model is utilized to investigate the effect of CNT agglomeration on the electrical conductivity and percolation threshold of nanocomposites. A series of parametric studies considering various shapes and curviness distributions of CNTs are carried out to examine the effects of entanglement on the electrical performance… More >

Soleiman Ghouhestani¹, Farzad Shahabian¹, Seyed Mahmoud Hosseini^2,3

CMES-Computer Modeling in Engineering & Sciences, Vol.100, No.4, pp. 295-321, 2014, DOI:10.3970/cmes.2014.100.295

Abstract In this paper, the meshless local Petrov-Galerkin (MLPG) method is exploited for dynamic analysis of functionally graded nanocomposite cylindrical layered structure reinforced by carbon nanotube subjected to mechanical shock loading. The carbon nanotubes (CNTs) are distributed across radial direction on thickness of cylinder, which can be simulated by linear and nonlinear volume fraction. Free vibration and elastic wave propagation are studied for various value of volume fraction exponent at various time intervals. The layered cylinder is assumed to be under axisymmetric and plane strain conditions. Four types of CNTs distributions including uniform and three kinds of functionally graded distributions along… More >