R. VENKATESAN^*, S. R. DARSON IMMANUEL JOHN, N. RAJESWARI

Journal of Polymer Materials, Vol.36, No.3, pp. 261-273, 2019, DOI:10.32381/JPM.2019.36.03.6

Abstract Nanocomposite films of chitosan (CH) incorporated with different wt. % of the polyoligomericsilsesquioxane (POSS) were prepared by solution casting. The thermal, mechanical, morphological and antimicrobial properties of the nanocomposites were examined. TGA analyses of the nanocomposites indicate that the filler enables the enhancement of thermal stability of chitosan. The tensile strength of the nanocomposite films is enhanced (10.9 MPa for neat chitosan to 24.0MPa for 5wt. % filled chitosan) by the addition of POSS while the elongation at break is reduced. The nanocomposite films exhibited excellent antimicrobial activity against both gram positive and gram negative bacteria. This activity increases with… More >

RUBY AHMED¹, MOHAMMAD OMAISH ANSARI², FARMAN ALI¹, SHAHID PERVEZ ANSARI^1,*

Journal of Polymer Materials, Vol.36, No.3, pp. 243-251, 2019, DOI:10.32381/JPM.2019.36.03.4

Abstract Polyaniline (PANI) and molybdenum disulphide (MoS₂ ) were used to prepare nanocomposites by in-situ oxidative polymerization of acidified aniline in presence of dispersed MoS₂ in the reaction mixture. Electron Microscopy (SEM & TEM), Fourier Transform Infrared (FTIR) spectroscopy, Ultraviolet-Visible (UV-Vis) spectroscopy, and X-ray diffraction (XRD) were used to characterize these nanocomposites. SEM micrographs showed that PANI is present on the layers of MoS₂ which were exfoliated during the preparation and the presence of MoS₂ is also confirmed by XRD peaks. The nanocomposites were studied for their electrical conductivity and stability of electrical conductivity in terms of d.c. electrical conductivity retention.… More >

KAVITA^*, R.K. TIWARI

Journal of Polymer Materials, Vol.36, No.2, pp. 195-205, 2019, DOI:10.32381/JPM.2019.36.02.7

Abstract The effect of poly (vinyl butyral) and acid functionalized multiwalled carbon nanotubes (f-MWCNT) on the thermal and mechanical performance of Kevlar fiber reinforced novolac epoxy nanocomposites was investigated and presented in this paper. Nanocomposite containing 1.5 wt. % poly (vinyl butyral) and 0.5 wt. % f-MWCNT exhibited best thermal and mechanical properties (except flexural strength) among all the nanocomposites reported here. It showed ~5%, 27% and 126 % improvement in tensile strength, young’s modulus and impact strength respectively as compared to the neat novolac epoxy Kevlar composite.Nanocomposite containing 0.5 wt. % f- MWCNT and 2 wt. % poly (vinyl butyral)… More >

NALINI SHARMA^1,*, AJAY SINGH², RAJ KUMAR DUTTA³

Journal of Polymer Materials, Vol.37, No.1-2, pp. 1-15, 2020, DOI:10.32381/JPM.2020.37.1-2.1

Abstract Controlled Release fertilizers (CRFs) are new generation agrochemicals which aid in decreasing environmental pollution. In the present study, novel CRF beads are synthesized by the technique of sol-gel polymerization. CMC polymer at various concentrations was used as a matrix and kaolin was used as a binder to enhance mechanical properties of the beads. The study also reveals the incorporation of Kaolin at different concentrations and optimization of the same. Fe3+ was used as a cross-linker to obtain spherical beads. Also, a study was done to optimize the cross linking time and concentration of cross linking solution. The usage of polymers… More >

İBRAHIM KARTERI^a,b,*, MUSTAFA ÖZYEŞILDAĞ^b

Journal of Polymer Materials, Vol.38, No.1-2, pp. 167-177, 2021, DOI:10.32381/JPM.2021.38.1-2.13

Abstract This study aims to provide a comprehensive account of chemically reduced graphene oxide (RGO) and decabromodiphenyl ethane (DBDPE) filled acrylonitrile-butadiene-styrene (ABS) multifunctional filaments for fused deposition modeling (FDM) applications. ABS/RGO with DBDPE nanocomposites (ABS-GDM) were fabricated by single-screw extrusion at a diameter of 1.75 mm. The proportion of RGO and DBDPE for the ABS-GDM filaments was set to 0.75 wt%. The properties of the ABS-GDM were determined using optical, mechanical, thermal, and morphological characteristics (using scanning electron microscopy). A three-dimensional (3D) model was successfully printed using the developed ABS-GDM filaments for FDM 3D printing. These ABS-GDM have the potential to… More >

ARUN KUMAR M, JAYAKUMARI LS^*, RAMJI CHANDRAN

Journal of Polymer Materials, Vol.40, No.3-4, pp. 141-156, 2023, DOI:10.32381/JPM.2023.40.3-4.2

Abstract Nanocomposites are very important materials because it imparts superior properties than other composites with low level of filler loading. Styrene butadiene rubber (SBR) is a non-polar rubber which acts as an insulator and has low electrical conductivity. Graphene platelet nano-powder from 0.1 to 1.25 phr level is incorporated into SBR rubber in order to improve the electrical properties. Comparative studies on electrical and mechanical properties of styrene butadiene rubber with graphene platelet nano-powder (GPN) by varying the filler content are made. The incorporation of Graphene platelet nano-powder increases the electrical conductivity in styrene butadiene rubber. It has been observed that… More >

S. ARULMURUGAN^a,*, N. VENKATESHWARAN^a, S. KUMAR^a, P. CHANDRASEKAR^a

Journal of Polymer Materials, Vol.40, No.1-2, pp. 83-91, 2023, DOI:10.32381/JPM.2023.40.1-2.7

Abstract In this research, the effect of UV light on the mechanical properties of jute polymer nanocomposites was evaluated. Due to the fact that photodegradation is a surface process and is confined to the degradation of the mechanical characteristics of polyester resin, this study focuses on the resin quality. Therefore, test samples comprised of fibre-reinforced polyester nanoclay composites were fabricated different weight ratios of nanoclay. They were put through UV exposure in an Ultraviolet (UV) chamber. Tensile testing samples were made in accordance with ASTMD638 and had a minimum thickness of 3 mm. Additionally, specimens for Flexural and Impact testing were… More >

R. J. Johnson^∗, R. Pitchumani^†

Frontiers in Heat and Mass Transfer, Vol.1, No.1, pp. 1-9, 2010, DOI:10.5098/hmt.v1.1.3007

Abstract Much research is currently being performed with carbon nanotube additives to neat resin systems to enhance properties such as thermal and electrical conductivity, strength, modulus and damping. Fabrication of parts based on carbon nanotube filled resin systems requires information on their cure kinetics and rheology, which has been relatively less studied so far. This work presents an extensive experimental study that systematically characterizes the cure kinetics and viscosity as a function of degree of cure and temperature of EPON 815C/EPICURE 3274 epoxy resin system laden with carbon nanotubes. Studies are conducted to determine the effects of the carbon nanotube loading… More >

Marta Martínez-Sanz, Amparo López-Rubio, Maria José Fabra, José M. Lagaron^*

Journal of Renewable Materials, Vol.2, No.2, pp. 107-117, 2014, DOI:10.7569/JRM.2014.634106

Abstract Due to their high crystallinity and aspect ratio, bacterial cellulose nanowhiskers (BCNW) represent an appealing choice for the development of fully biobased nanocomposite materials with high barrier performance. However, their strong tendency to self-associate, together with their highly hydrophilic character, has restricted the production of nanocomposites containing cellulose nanowhiskers by industrial processing techniques such as melt compounding. Th is article presents an overview of the latest published results carried out within our group and also in other relevant literature, which have led to the development of an effi cient strategy for the incorporation of highly dispersed BCNW by melt compounding… More >

John Paul¹, K. Kadirgama¹, M. Samykano^2,*, R. Saidur³, A. K. Pandey³, R. V. Mohan⁴

Energy Engineering, Vol.119, No.4, pp. 1299-1325, 2022, DOI:10.32604/ee.2022.019172

Abstract

Buildings contribute to 33% of total global energy consumption, which corresponds to 38% of greenhouse gas emissions. Enhancing building’s energy efficiency remains predominant in mitigating global warming. Advancements in thermal energy storage (TES) techniques using phase change material (PCM) have gained much attention among researchers, primarily to minimize energy consumption and to promote the use of renewable energy sources. PCM technology stays as the most promising technology for developing high-performance and energy-efficient buildings. The major drawback of PCM is its poor thermal conductivity which limits its potential use which could be resolved by dispersing conductive nanofillers. The acquired database on… More > Graphic Abstract