ZHIHUI HUANG¹, JIAMIAO CHEN¹, YANPING HUO¹, JINGWEI ZHAO²

Journal of Polymer Materials, Vol.38, No.3-4, pp. 257-269, 2021, DOI:10.32381/JPM.2021.38.3-4.7

Abstract The effect of the ether/keto ratios on the thermal properties, mechanical performances and crystallization behavior of the Poly(aryl ether ketone)s (PAEK) were investigated. A formula was proposed the estimate the melting temperatures of the PAEKs with high accuracy. Glass transition temperatures were affected by the ether/keto ratios and molecular weights, and were related with the brittle-tough transition of the PAEKs. Mechanical performances of tensile, impact, flexural and compressive strength decreased with the increase of ether/keto ratios, while elongation had a trend of increase. The non-isothermal crystallization curves exhibited well linearity when treated with Jeziorny’s model, and two crystallization processes were… More >

SORAYA SEGHIER^1,2,*, MOHAMMED BELBACHIR¹

Journal of Polymer Materials, Vol.38, No.3-4, pp. 205-218, 2021, DOI:10.32381/JPM.2021.38.3-4.3

Abstract In the present paper, we report the synthesis of a new amino polymer made of oxazolidinone using an efficient ecocatalyst called Maghnite-H⁺. The synthesis process contains two steps: the first consists to the preparation of an amino oxiran 3-(oxiran-ylmethyl) oxazolidin- 2-one (OMO) by a substitution reaction of epichlorhydrin by 2-oxazolidinone, the second step concerns a green polymerization of the resultant oxiran by a ring opening reaction catalysed by Maghnite-H⁺. The polymer have been successfully prepared and characterized by various techniques, such as ¹H NMR, ¹³C NMR, IR, which were used to elucidate the structural characteristics of the resulting polymers. The… More >

VRINDA GOEL¹, RUCHIKA TANWAR¹, AJOY KUMAR SAIKIA², UTTAM KUMAR MANDAL^1,*

Journal of Polymer Materials, Vol.39, No.3-4, pp. 283-305, 2022, DOI:10.32381/JPM.2022.39.3-4.8

Abstract The commercially available Polysulfone (PSF) membrane surface was modified by solution polymerization of aniline using different oxidation catalysts i.e., FeCl₃, CuCl₂, and APS. Modified membranes were then characterized with respect to physio-chemical properties like surface chemistry, porosity, wettability, surface roughness, morphology, etc. It was observed that the hydrophilicity/ wettability of membranes was increased upon surface modification by polyaniline which again depended on the nature of the oxidation catalyst used. Membranes developed using FeCl₃ and CuCl₂ as oxidants exhibit improved permeation, protein rejection, and antifouling properties, whereas decrement was observed in modified membrane performance using APS as an oxidant. Among all… More >

GAURAV AGARWAL

Journal of Polymer Materials, Vol.39, No.3-4, pp. 255-267, 2022, DOI:10.32381/JPM.2022.39.3-4.6

Abstract Studies were conducted to observe the effect of fracture toughness and damping response on fabric reinforced epoxy polymer composites. The samples of glass fabric, kevlar fabric and carbon fabric having 15wt%, 25wt%, 35wt%, 45wt% and 55wt % fabric content were prepared and tested following ASTM standards. Fracture toughness, peak load and increase in energy absorption are determined for the fabric-epoxy composites. Effect of temperature on storage modulus, loss modulus and tan delta values for various percentages of fabric epoxy composites are noticed and corresponding damping response behaviour is determined. The results revealed that reduction in strength at higher percentage of… More >

MUHAMAD SOFFI BIN MANDA^1,2, MOHD RUZAIMI BIN MAT REJAB¹, SHUKUR ABU HASSAN^3,4, MAT UZIR BIN WAHIT^3,4, JOSEPH SELVI BINOJ^5,*, BRIGHT BRAILSON MANSINGH⁶, SITI SAFARAH BINTI AMIRNUDDIN³, ALAMRY ALI⁷, KHENG LIM GOH^8,9, DIDIK NURHADIYANTO¹⁰

Journal of Polymer Materials, Vol.39, No.3-4, pp. 241-253, 2022, DOI:10.32381/JPM.2022.39.3-4.5

Abstract This study investigates the potential of Tin Slag Polymer Concrete (TSPC) strengthening through confinement using basalt fiber reinforced polymer (BFRP) and aramid fiber reinforced polymer (AFRP) confinement. TSPC short cylindrical column samples have been wrapped with BFRP and AFRP in a single layer (30 mm overlap) using Sikadur-330 epoxy and final samples were coded as TSPC-UC, TSPC-BF and TSPC-AF for unconfined, BFRP and AFRP for confined respectively. After curing for 30 days at room temperature, compressive test has been performed to know the strength, modulus, strain, fracture energy and failure modes of unconfined and confined TSPC. Test result shows that… More >

NEETU TRIPATHI, DIBYENDU S. BAG^*, MAYANK DWIVEDI

Journal of Polymer Materials, Vol.40, No.3-4, pp. 227-269, 2023, DOI:10.32381/JPM.2023.40.3-4.8

Abstract Over the last three decades, there has been considerable interest in the captivating mechanical properties displayed by auxetic materials, highlighting the advantages stemming from their distinct negative Poisson's ratio. The negative Poisson's ratio observed in auxetic polymeric materials is a result of the distinctive geometries of their unit cells. These unit cells, encompassing structures such as chiral, re-entrant, and rotating rigid configurations, are carefully engineered to collectively generate the desired auxetic behaviour. This comprehensive review article explores the field of auxetic polymeric materials, offering a detailed exploration of their geometries, fabrication methods, mechanical properties, and characterisation. The diverse applications of… More >

PRITI^1,*, RADHA SACHAN², ROLI PURWAR³

Journal of Polymer Materials, Vol.40, No.3-4, pp. 205-214, 2023, DOI:10.32381/JPM.2023.40.3-4.6

Abstract In current research work, we have studied the blending effect of non-mulberry silk fibroin (10% weight/volume basis) and gelatin (20% weight/volume basis) in formic acid. Several blends as SF10G0, SF2G8, SF3G7, SF5G5 and SF0G10 have been made and their rheological behaviour was investigated. The blend solutions were subjected to a steady shear rheological study in the variety of range of shear rates, namely 0.01–500 sec-1 and the viscosities of blend solutions were noticed to decrease in comparison to pure silk solution. The frequency sweep was employed in dynamic rheological tests to determine complex viscosity of these solutions from range of… More >

NORHABIBAH MOHAMAD^1,*, NOORDINI M. SALLEH^1,2, HABIBUN NABI MUHAMMAD EKRAMUL MAHMUD¹

Journal of Polymer Materials, Vol.40, No.3-4, pp. 165-189, 2023, DOI:10.32381/JPM.2023.40.3-4.4

Abstract The present study has explored the adsorption properties of polypyrrole-based adsorbents (polypyrrole and polypyrrole-polyethyleneimine composite) as novel conducting polymers in adsorbing methyl orange (MO) (an anionic dye) effectively from aqueous solution. The adsorption characteristics of the prepared polymer-based adsorbents were characterized by BET, FTIR, FESEM, and XRD methods. The effectiveness of PPy-based adsorbents for MO dye adsorption was examined using the batch adsorption method. Different parameters were changed during the adsorption process, including contact time, solution pH, and adsorbent dosage. The highest BET surface area of the PPy-PEI composite was found to be 11.85 m² /g, which is much greater… More >

MARIA JENITA, LALITHAPRIYA U, SUKUMAR M^*

Journal of Polymer Materials, Vol.39, No.1-2, pp. 71-87, 2022, DOI:10.32381/JPM.2022.39.1-2.5

Abstract In this study, a multi-layered green polymer-based packaging composite assembled by active flavonoid Kaempferol grafted with starch-chitosan was prepared, and its characteristics and effect on meat storage, including physicochemical characteristics and antioxidant capacity, were analysed and evaluated at refrigeration conditions given four treatments: CON (control— without coating), SEC (with starch+chitin), P01 (with starch+chitin + 1% of Kaempferol) and P02 (with starch+chitin + 2% of Kaempferol). The addition of Kaempferol increased the antioxidant activity of meat and inhibited the lipid oxidation until day 24 upon migration effect; also improving meat acceptability. The Rancimat induction time confirmed the stability of both P01… More >

DIBYENDU S. BAG^*, SHILPI TIWARI, AKANSHA DIXIT, KM. MEENU

Journal of Polymer Materials, Vol.40, No.1-2, pp. 105-123, 2023, DOI:10.32381/JPM.2023.40.1-2.9

Abstract In this paper, we report the microstructural investigation and influence of H-bonding on the thermal behavior e.g., glass transition (T_g ) and thermal degradation of chiral copolymers of (R)- N-(1-phenyl-ethyl) methacrylamide (R-NPEMAM) and 2-hydroxy ethyl methacrylate (HEMA). The T_g increases with the increase of chiral unit content in the copolymers and then attains optimum at around 25 mole % of chiral content. Thereafter it decreases with the increase of chiral content. The effect of copolymer composition and secondary interaction associated with the Hbonding on the thermal properties of these copolymers was also studied. Secondary interaction, specifically H-bonding has been interpreted… More >