XIAOYAN LIU^a,*, XU CHEN^a, HONGXING ZHANG^b, CHANGJUN ZHANG^a, SHIYUAN YANG^a, GUANGQUAN LI^a

Journal of Polymer Materials, Vol.36, No.2, pp. 121-132, 2019, DOI:10.32381/JPM.2019.36.02.2

Abstract In this work, three in situ impact polypropylene copolymer(IPC) samples were prepared through Ziegler-Natta catalyst only changing the feed composition (ethylene to ethylene and propylene molar ratio, C2/C2+C3) in gas-phase polymerization reactor. Polymer (IPC) were characterical by solvent classification, gel permeation chromatography (GPC), differential scanning calorimetry (DSC), successive self-nucleation and annealing (SSA), nuclear magnetic resonance(13C-NMR) and scanning electron microscopy(SEM). The mechanical properties of IPC samples were tested.The results indicate that with similar ethylene content, the feed composition which determines the content and structure of EPR and EbP component in IPC, further impacts the rubber phase size and distribution in IPC,… More >

KRISHAN KUMAR PATEL, RAJESH PUROHIT

Journal of Polymer Materials, Vol.36, No.1, pp. 23-37, 2019, DOI:10.32381/JPM.2019.36.01.3

Abstract Microwave (MV)-induced thermo-responsive shape memory thermoplastic polyurethane (SMTPU)/ MWCNT composites were prepared in micro-compounder. Composites containing different amount of multiwall Carbon nanotube (MWCNT) varying from 0 to 1.5 phr in SMTPU matrix were prepared. Maximum stretching strength, recovery force and tensile strength for 1.5 CNTPU (1.5 phr MWCNT in SMTPU matrix) was increased by 120%, 100% and 24% respectively as compared to SMTPU. MV-induced shape memory is a novel approach for fast, clean and remote heating during operation. MWCNT is strong absorber of microwave irradiation so that SMTPU/ MWCNTs nanocomposites successfully triggered by microwave. More >

D. MURALI MANOHAR^1,*, B.C. CHAKRABORTY², S. SHAMSHATH BEGUM³

Journal of Polymer Materials, Vol.37, No.1-2, pp. 91-107, 2020, DOI:10.32381/JPM.2020.37.1-2.7

Abstract In search of improved materials for efficient shock and vibration mounts for machineries, graphite loaded NBR and NBR/PVC blend were made and investigated. The scorch time was seen to be reduced and vulcanization rate was enhanced due to graphite inclusion. Scanning electron microscopy images have shown homogenous dispersion of graphite powder. NBRgraphite showed a gradual increase in the hardness, tensile strength, Young’s modulus, and tear values with increasing graphite loading. In the case of NBR/PVC-graphite composition, a drop in the tensile strength and increase in the Young’ modulus and tear strength was observed. Various mathematical models were used to investigate… More >

ZHAO JUN^a, LIU AIQIN^a, ZHOU HONG^a, LUO JUN^b,*, AND LIU YUAN^b,*

Journal of Polymer Materials, Vol.37, No.1-2, pp. 29-42, 2020, DOI:10.32381/JPM.2020.37.1-2.3

Abstract Heteroatoms (N, O, and F) and hydrogen groups are important elements for forming the H-bonds. It is well known that a large number of hydrogen groups are formed after curing reaction of epoxy. However, literatures about epoxy resins containing heteroaromatic ring and the H-bonds after cure reaction of the epoxy resins are seldom published. To bridge the gap, a kind of new epoxy monomer containing pyridine ring (EMP) has been synthesized in this work, andit is further cured by 4,4-diaminodiphenyl methane (DDM). The properties of cured EMP/ DDM are evaluated by DSC, DMA, and static contact angle measurement. Moreover, the… More >

GOBI NALLATHAMBI, BHARGAVI RAM THIMMIAH^*

Journal of Polymer Materials, Vol.37, No.3-4, pp. 189-200, 2020, DOI:10.32381/JPM.2020.37.3-4.6

Abstract The aim of this study is to optimize the process parameters of alkali treated Saharan aloe vera cactus fibres using of Box-behnken experimental design. The Saharan aloe vera cactus fibres were treated with different concentration of NaOH, soaking time and temperature which affect the properties of fibres and plays main role in removal of lignin, hemicellulose, pectin and wax content. The chemical composition of untreated and treated fibres was analyzed by standard methods. XRD result shows the improvement in the crystallinity index of fibres due to alkali treatment. ATR-FTIR analysis shows that hemicellulose and lignin were decreased in all alkali… More >

R.M. MISHRAA, R. VIJAYVARGIYAA, K.N. PANDEYA, J.S.P. RAIB

Journal of Polymer Materials, Vol.37, No.3-4, pp. 179-188, 2020, DOI:10.32381/JPM.2020.37.3-4.5

Abstract The present investigation is targeted to prepare nanocomposites based on binary blends of polyetherimide (PEI)-silicone rubber incorporated with varied loadings of nanotitanium dioxide particles. Nanocomposites have been prepared by melt blending process using twin screw extruder. Thermal properties of the developed nanocomposites have been investigated with the help of thermogravimetric analyzer (TGA) and dynamic mechanical analyzer (DMA). Scanning electron microscopy (SEM) is used to analyze the morphological properties of the nanocomposites. Mechanical properties (tensile strength, tensile modulus, elongation at break, impact strength) of the nanocomposites have been evaluated by universal testing machine (UTM). Mechanical testing results reveal that there is… More >

HULYA SEMA KOKER¹, HÜLYA YAVUZ ERSAN¹, AYSE AYTAC^2,3,*

Journal of Polymer Materials, Vol.37, No.3-4, pp. 165-177, 2020, DOI:10.32381/JPM.2020.37.3-4.4

Abstract Chitosan (CH) and low-density polyethylene (PE) blend films were produced by a twin-screw extruder and heat press with different plasticizers glycerol (GLY), sorbitol (SOR) and polyethylene glycol (PEG). The tensile strength decreased and elongation at break increased with the incorporation of plasticizer for blends with 10 wt% of CH. The thermal stability of the films was slightly higher for films containing GLY and PEG as compared to SOR. Contact angles reduced from CH-PE film to the films containing PEG, SOR and GLY in decreasing order, respectively. Fourier transform infrared spectroscopy revealed no interactions between CH and PE in CH-PE film… More >

RAJEEV KUMAR

Journal of Polymer Materials, Vol.37, No.3-4, pp. 131-142, 2020, DOI:10.32381/JPM.2020.37.3-4.2

Abstract The optical, electrical and acoustical properties of a polymer solution based on polyvinyl pyrrolidone (PVP) doped with different concentration of cupric sulphate (CuSO₄ ) were studied.UVVIS spectroscopy results reflected that absorption increases in asymmetric manner and the absorption peak showed red shift with increasing Cu ions concentration. The optical band gap (direct and indirect) was found to decrease with increase in Cu ions concentration in the polymer due to increase in the density of localized states in the band-gap.The value of Urbach energy is also evaluated from the transmission spectra and the activation energies are also evaluated from the conductivity… More >

ANIL KUMAR VEERAPANENI¹, CHANDRASEKAR KUPPAN^2,*, MURTHY CHAVALI^3,*

Journal of Polymer Materials, Vol.37, No.3-4, pp. 121-130, 2020, DOI:10.32381/JPM.2020.37.3-4.1

Abstract The mechanical properties of hybrid nanocomposites made of epoxy/glass fibre dispersed with nano-α-Al₂ O₃ powder at different weight percentages were studied.The effect of nano-α- Al₂O₃ size and wt% on mechanical properties like tensile, flexural, interlaminar shear stress and hardness enhanced because of their higher surface area and interfacial polymer-metal interaction. The nanoparticle embedded laminates have shown improvement in flexural strength,and hardness when compared to laminate without nano-α-Al₂ O₃. The properties varied with the loading and size of the nanoparticles. The tensile strength was highest for 0.5 wt% of 200nm nano-α-Al₂O₃, which is 167.80 N/m₂.The highest flexural strength was observed for… More >

İBRAHIM KARTERI^a,b,*, MUSTAFA ÖZYEŞILDAĞ^b

Journal of Polymer Materials, Vol.38, No.1-2, pp. 167-177, 2021, DOI:10.32381/JPM.2021.38.1-2.13

Abstract This study aims to provide a comprehensive account of chemically reduced graphene oxide (RGO) and decabromodiphenyl ethane (DBDPE) filled acrylonitrile-butadiene-styrene (ABS) multifunctional filaments for fused deposition modeling (FDM) applications. ABS/RGO with DBDPE nanocomposites (ABS-GDM) were fabricated by single-screw extrusion at a diameter of 1.75 mm. The proportion of RGO and DBDPE for the ABS-GDM filaments was set to 0.75 wt%. The properties of the ABS-GDM were determined using optical, mechanical, thermal, and morphological characteristics (using scanning electron microscopy). A three-dimensional (3D) model was successfully printed using the developed ABS-GDM filaments for FDM 3D printing. These ABS-GDM have the potential to… More >