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  • Open Access

    ARTICLE

    Robust Color Fastness of Dyed Silk Fibroin Film By Coupling Modification Dyeing with Aniline Diazonium Salt

    ZONGQIAN WANG, HAIWEI YANG, JIAN XING, ZHI LIU*

    Journal of Polymer Materials, Vol.36, No.2, pp. 149-159, 2019, DOI:10.32381/JPM.2019.36.02.4

    Abstract Colored silk fibroin (SF) film can change the proportion of transmitted light composition and therefore shows potential application in optoelectronics area. However, few methods are reported for the preparation of colored SF film with good color fastness. Herein, colored SF film was prepared by coupling modification dyeing (CM-dyeing) of SF tyrosine residues in solution. SF film shows excellent color fastness due to the formation of the azo covalent bond formed by electrophilic substitution reaction between SF tyrosine residues and aniline diazonium salt. Furthermore, compared with the undyed film, the dyed SF film is effectively preserved its mechanical property by the… More >

  • Open Access

    ARTICLE

    Rheological Study on Blend Solutions of Non-mulberry Silk Fibroin and Gelatin Biopolymers

    PRITI1,*, RADHA SACHAN2, ROLI PURWAR3

    Journal of Polymer Materials, Vol.40, No.3-4, pp. 205-214, 2023, DOI:10.32381/JPM.2023.40.3-4.6

    Abstract In current research work, we have studied the blending effect of non-mulberry silk fibroin (10% weight/volume basis) and gelatin (20% weight/volume basis) in formic acid. Several blends as SF10G0, SF2G8, SF3G7, SF5G5 and SF0G10 have been made and their rheological behaviour was investigated. The blend solutions were subjected to a steady shear rheological study in the variety of range of shear rates, namely 0.01–500 sec-1 and the viscosities of blend solutions were noticed to decrease in comparison to pure silk solution. The frequency sweep was employed in dynamic rheological tests to determine complex viscosity of these solutions from range of… More >

  • Open Access

    ARTICLE

    Biodegradable and Biocompatible Polyvinyl alcohol/ Silk Fibroin-Based Composite with Improved Strength

    XINGMIN XU1, QINGQING SUN2, AIRONG XU2, XINBAO GUO2

    Journal of Polymer Materials, Vol.39, No.1-2, pp. 167-181, 2022, DOI:10.32381/JPM.2022.39.1-2.11

    Abstract Silk fibroin (SF) with renewability, biocompatibility and biodegradability shows potential application in various fields including biomedicine, tissue engineering, and wearable electronic devices. Herein, SF is used to exert effective reinforcement of polyvinyl alcohol (PVA) composite film to further improve its practicability. As such, PVA/SF composite films were prepared for the first time using a facile approach. The films were characterized to investigate possible interaction of PVA with SF. Meanwhile, systematic investigations have also been completed to explore the influences of PVA/SF mass ratio on the mechanical properties (tensile strength, elongation at break), biodegradability and biocompatibility, the morphology, crystallinity, chemical structure… More >

  • Open Access

    ARTICLE

    Fabrication of High Toughness Silk Fibroin/Tungsten Disulfide Nanoparticles Hybrid Fiber and Self-Heating Textile by Wet Spinning

    Jianjun Guo1,2, Lingling Jia3, Sandra Senyo Fometu4, Qiang Ma5, Jinjin Wang1, Hang Li1, Lei Jiang5, Guohua Wu1,*

    Journal of Renewable Materials, Vol.10, No.12, pp. 3373-3389, 2022, DOI:10.32604/jrm.2022.021087

    Abstract Traditionally, silkworm silk has been used to make high-quality textiles. Nevertheless, various wastes from silkworm silk textiles that are no longer used are increasing, which is also causing considerable waste and contamination. This issue is causing widespread concern in countries that use more silk. Regenerated silk fibroin (RSF) fibers have been shown to be fragile and tender, which prohibits RSF from being widely used as a structural component. Therefore, enriching the function of silk and enhancing the RSF mechanical properties are important directions to expand the comprehensive utilization of silk products. In the present research, wet spinning was used to… More >

  • Open Access

    ARTICLE

    Silk Fibroin-Based Hydrogel for Multifunctional Wearable Sensors

    Yiming Zhao1,2, Hongsheng Zhao3, Zhili Wei4, Jie Yuan1, Jie Jian1, Fankai Kong1, Haojiang Xie1, Xingliang Xiong1,2,*

    Journal of Renewable Materials, Vol.10, No.11, pp. 2729-2746, 2022, DOI:10.32604/jrm.2022.019721

    Abstract The flexible wearable sensors with excellent stretchability, high sensitivity and good biocompatibility are signifi- cantly required for continuously physical condition tracking in health management and rehabilitation monitoring. Herein, we present a high-performance wearable sensor. The sensor is prepared with nanocomposite hydrogel by using silk fibroin (SF), polyacrylamide (PAM), polydopamine (PDA) and graphene oxide (GO). It can be used to monitor body motions (including large-scale and small-scale motions) as well as human electrophysiological (ECG) signals with high sensitivity, wide sensing range, and fast response time. Therefore, the proposed sensor is promising in the fields of rehabilitation, motion monitoring and disease diagnosis. More >

  • Open Access

    ARTICLE

    A Promising Wound Dressing from Regenerated Silk Fibroin Sponge with Sustain-ed Release of Silver Nanoparticles

    Yang Li#, Xiaoying Zha#, Xingliang Xiong, Yan Zhang, Ying Feng, Haojiang Xie, Linqing Zhang, Qifeng Jiang*

    Journal of Renewable Materials, Vol.9, No.2, pp. 295-310, 2021, DOI:10.32604/jrm.2021.012271

    Abstract A silk fibroin (SF) spongy wound dressing incorporated with silver nanoparticles (Ag-NPs) was developed for biomedical applications. Ag-NPs were efficiently synthesized in situ via ultra violet (UV) with AgNO3 as precursor and silk fibroin as reducing and protecting agent, respectively. After lyophilization, the formed silk fibroin spongy wound dressing (SFWD) exhibited polyporous morphology and inner lamellae structures, with uniform dispersion of Ag-NPs. The porous structure provided SFWD with the ability to absorb tissue exudatealmost 6 times of its own weight, which could guarantee the sustained release of Ag-NPs. By methanol treatment, SFWD showed much improved mechanical properties and more stable… More >

  • Open Access

    ARTICLE

    The Effect of Processing Temperature on Mechanical Properties of Novel Silk Fibroin and Chitosan Blend Scaffolds for Musculoskeletal Regeneration

    C. N. Rios1, J. N. Augustine1, A. B. Mathur1

    Molecular & Cellular Biomechanics, Vol.3, No.4, pp. 173-174, 2006, DOI:10.32604/mcb.2006.003.173

    Abstract This article has no abstract. More >

  • Open Access

    ARTICLE

    Theoretical Prediction and Experimental Testing of Mechanical Properties for 3D Printed Silk Fibroin-Type II Collagen Scaffolds for Cartilage Regeneration

    Lilan Gao1,2,*, Qingxian Yuan1,2, Ruixin Li3,*, Lei Chen1,2, Chunqiu Zhang1,2, Xizheng Zhang1,2

    Molecular & Cellular Biomechanics, Vol.15, No.2, pp. 85-98, 2018, DOI: 10.3970/mcb.2018.00329

    Abstract Silk fibroin-typeⅡcollagen scaffold was made by 3D printing technique and freeze-drying method, and its mechanical properties were studied by experiments and theoretical prediction. The results show that the three-dimensional silk fibroin-typeⅡ collagen scaffold has good porosity and water absorption, which is (89.3%+3.26%) and (824.09%+93.05%), respectively. With the given strain value, the stress of scaffold decreases rapidly firstly and then tends to be stable during the stress relaxation. Both initial and instantaneous stresses increase with increase of applied strain value. The creep strains of scaffold with different stress levels show the two stages: the rapidly increasing stage and the second stable… More >

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