FATMA LOUZRI, SADJIA BENNOUR

Journal of Polymer Materials, Vol.37, No.1-2, pp. 55-76, 2020, DOI:10.32381/JPM.2020.37.1-2.5

Abstract Poly(N,N-dimethymethylacrylamide -co-crotonic acid) (P(DMA-CAx)) hydrogels were prepared by free radical polymerization, using N,N- methylenebisacrylamide (NMBA) as cross-linking agent. The synthesized hydrogels were characterized by Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA). The effects of comonomer composition and pH of the medium on the swelling behavior of hydrogels were investigated. The obtained results showed that the swelling capabilities of hydrogels increased as crotonic acid content and pH increased. In order to evaluate the controlled release potential of the polymeric matrix, it was loaded with potassium nitrate and ammonium nitrate as fertilizers and the release kinetics was studied as a… More >

DENIZ AKIN SAHBAZ^1,*, BETUL TURP KAYA²

Journal of Polymer Materials, Vol.38, No.3-4, pp. 247-256, 2021, DOI:10.32381/JPM.2021.38.3-4.6

Abstract The objective of this study is to develop chitosan-based films containing Hypericum perforatum L. and/or Citrus limon L. oils and to investigate their suitability as novel wound dressing materials. The morphology of the chitosan-based films were observed by means of employing the scanning electron microscopy (SEM) and the chemical structure characterization was performed via Fourier Transform Infrared Spectroscopy (FTIR). Hypericum perforatum L. and/or Citrus limon L. were successfully incorporated to the chitosan films. Antibacterial, swelling, and mechanical properties of these films were investigated. The antibacterial property was enhanced by incorporating Hypericum perforatum L. and Citrus limon L. oils in the… More >

Yalin Li^1,*, Lei Liu¹, Wenbao Huang¹, Junpu Xie², Zhaoxia Song¹, Shuna Guo¹, Enci Wang¹

Journal of Renewable Materials, Vol.11, No.7, pp. 3001-3023, 2023, DOI:10.32604/jrm.2023.026604

Abstract To achieve optimal recovery and value-added utilisation of cellulose in peanut shells, the cellulose in peanut shells was first extracted using the sodium hydroxide-sodium chlorite method. Then, cellulose hydrogel was prepared by graft copolymerisation using N, N’-methylenebisacrylamide as the cross-linking agent, sodium persulfate as the initiator, and acrylic acid as the monomer. Orthogonal optimisation experiments were designed to obtain optimal process parameters for hydrogel preparation with the cellulose dosage of 0.40 g, initiator dosage of 0.20 g, polymerisation temperature of 70°C, cross-linking agent of 0.25 g, and monomer dosage of 3.0 mL. The effect of initiator dosage on hydrogel synthesis was… More > Graphic Abstract

Yalin Li^1,2,*, Yu Huang², Lei Liu¹, Haozhao Liu¹, Haiyang He¹, Dongxue Lu¹, Tingting Dong¹

Journal of Renewable Materials, Vol.11, No.3, pp. 1237-1253, 2023, DOI:10.32604/jrm.2022.022972

Abstract

In this study, hydrogels were prepared from municipal sludge to recycle and realize the value-added utilization of the carbon components in this abundant waste material. The carbon sources were extracted from the municipal sludge using synthesised nano CaO₂ as an oxidant, and the carbon sources were graft copolymerised with acrylic acid monomer using N, N′-methylenebisacrylamide as a crosslinking agent and ammonium persulfate as an initiator. The factors influencing the hydrogel preparation were investigated by single-factor experiments. Based on the results of the single-factor experiments, a hydrogel with a swelling ratio of up to 19768.4% at 12 h was prepared with… More > Graphic Abstract

Shuangsheng Zhang, Bin Sun, Siyu Li, Xiangyu Lin, Muhua Chen^*, Xu Xu^*

Journal of Renewable Materials, Vol.11, No.2, pp. 853-865, 2023, DOI:10.32604/jrm.2022.022901

Abstract Hydrogels have been widely applied in agricultural drought-resistance, pollution regulation, drug delivery and so on. Acrylamide (AM) is usually used as raw material to synthesize acrylamide hydrogels. However, inherently low mechanical strength greatly limits their applications in some special areas. Therefore, it is necessary to choose suitable functional monomers to optimize acrylamide hydrogels and improve their mechanical performances. In this paper, a novel acrylamide monomer modified by rosin was synthesized, and then polyacrylamide/rosin-based acrylamide (RAM) composite hydrogels were prepared via free radical polymerization using potassium persulfate as initiator, N, N′-methylene-bisacrylamide (MBA) as a crosslinker. The influence of RAM monomer was… More > Graphic Abstract

Sihan Wang, Reza Masoodi^*, Janet Brady, Brian R. George

Journal of Renewable Materials, Vol.1, No.4, pp. 279-288, 2013, DOI:10.7569/JRM.2013.634122

Abstract Recycled natural fi bers and biopolymers with sustainable, eco-friendly, and biodegradable properties are receiving increased attention. The moisture absorption and swelling of natural fi ber composites adversely infl uence their mechanical properties and applications. In this research, bio-based epoxy polymers that are reinforced with recycled woven jute fabrics were subjected to water immersion tests in order to study the effect of water absorption on their mechanical and geometrical properties. For comparison, petroleum-based epoxy polymers that are reinforced with new woven jute fabrics were also subjected to the same tests. The effect of fi ber percentage on water absorption, thickness swelling,… More >

Xin Han^1,4, Zhichao Lou^1,3,4,*, Chenglong Yuan^1,4, Xinwu Wu^1,4, Jie Liu^1,4, Fujin Weng², Yanjun Li^1,4,*

Journal of Renewable Materials, Vol.10, No.12, pp. 3313-3334, 2022, DOI:10.32604/jrm.2022.021066

Abstract With the aim of utilizing reconstituted bamboo as a carbon cycle-oriented material, the improvement of physical and mechanical properties has been actively studied to solve using problems. The saturated steam heat treatment process has been widely used in worldwide. With the development and exploration of this technology, two-step saturated steam heat treatment process appears in some practical production, that is, after a period of saturated steam heat treatment at a lower temperature, the bamboo bundles are taken out and seasoned for a period of time, and then put back into the heat tank again, and heated at a higher temperature… More >

Diego David Pinzón-Moreno^*, Eder Clidio Vicuña-Galindo, José Vulfrano González-Fernández, José Luis Soto-Gonzales, María Verónica Carranza-Oropeza^*

Journal of Renewable Materials, Vol.10, No.8, pp. 2179-2201, 2022, DOI:10.32604/jrm.2022.019793

Abstract Several hydrogels were synthesized by free-radical polymerization in an aqueous medium based on potato starch (PS), poly(vinyl alcohol) (PVA), and N,N′-Methylenebisacrylamide (MBAm), being possible to study these hydrogels as a function of the proportion of components incorporated. In this way, the products generated from the synthesis were characterized by swelling and deswelling kinetics, the first swelling being verified with Schott and statistical models, allowing to contrast the proximity between the experimental and theoretical behavior. Additionally, water retention in soil (R%), spectroscopy (FTIR), morphological (SEM), and thermal (TGA and DSC) analysis allowing to know the intrinsic characteristics of the material, increasing… More >

Xing Zhou^*

Journal of Renewable Materials, Vol.10, No.6, pp. 1623-1639, 2022, DOI:10.32604/jrm.2022.018935

Abstract A facile method, focusing on emulsification, chain extension and dispersion process in preparing waterborne polyurethane, was developed to prepare emulsion with rod-like nanoparticles. The facile method involves a water addition procedure by in situ generated water to react with polyurethane prepolymer instead of the external water addition process. As a comparison, waterborne polyurethane was synthesized through the external water addition process. According to the characterization methods including FTIR, ¹H-NMR, TEM and water swelling experiments, it is suggested there are two kinds of hydrogen bonds interactions in hard/soft domain of the novel polyurethane, and the phase separation of hard/soft domains increases… More > Graphic Abstract

Xiushao Zhao¹, Qijing Yang^1,2,*, Jianglong Rao¹, Daxin Geng¹, Zhouyong Tan¹

Journal of Renewable Materials, Vol.10, No.1, pp. 203-218, 2022, DOI:10.32604/jrm.2021.015854

Abstract Completely weathered phyllite (CWP) soil is a kind of special soil with high swell potential, while red clay is a special soil with high shrinkage. This means that these two kinds of special soils are usually not suitable for direct use as subgrade fill. To reduce the swell index of the CWP soil and the shrinkage of red clay at the same time, it was proposed to blend the CWP soil with red clay to improve their basic characteristics. A series of swell index tests and dry-wet cycle tests of the blended soils have been carried out at varying blending… More > Graphic Abstract