KM. MEENU, DIBYENDU S. BAG^*, REKHA LAGARKHA^a

Journal of Polymer Materials, Vol.36, No.3, pp. 275-292, 2019, DOI:10.32381/JPM.2019.36.03.7

Abstract Functional photoactive polysilane copolymers of poly(methylphenylsilane) (PMPS) and disperse yellow 7 methacrylate (DY7MA) were synthesized using UV-technique. In the same manner functional polysilane copolymers of poly(methylphenylsilane-co-dimethylsilane) (CPS) and disperse yellow 7 methacrylate (DY7MA) were also synthesized. By the UV irradiation polysilanes (PMPS and CPS) give rise to silyl macroradicals which initiate the polymerization of photoactive monomer (DY7MA). The synthesized samples were characterized by FTIR, NMR, and UV-Vis spectroscopy. The molar mass of synthesized photoactive functional polysilane copolymers is of order of 103 gm/mol. They exhibited multimodal optical and photoluminescence functional properties. Optical absorbance was observed at 336 nm due to… More >

MERYEM KORUYUCU^a, FEHMi SALTAN^a,b, GÖKHAN KÖK^a, HAKAN AKAT^a, YEŞIM SALMAN^a,*

Journal of Polymer Materials, Vol.36, No.3, pp. 207-216, 2019, DOI:10.32381/JPM.2019.36.03.1

Abstract The present study has demonstrated that novel acrylic glycopolymers are successfully prepared by using monosaccharides containing an acrylate group (9-12). For this purpose, sugar based acrylate monomers were synthesized via ring opening method (Method B) and homopolymerization of this sugar oxypropylacrylates was performed using free radical polymerization. The characterization of all the monomers and polymers were verified by ¹HNMR, ¹³CNMR, FTIR and GPC techniques. The Glass transition temperatures and thermal characteristics of the polymers were also analyzed by using DSC and TG techniques. The thermal stability of prepared polymers have changed with the stereochemistry of the carbohydrate moiety. Also, the… More >

KAVITA^*, R.K. TIWARI

Journal of Polymer Materials, Vol.36, No.2, pp. 195-205, 2019, DOI:10.32381/JPM.2019.36.02.7

Abstract The effect of poly (vinyl butyral) and acid functionalized multiwalled carbon nanotubes (f-MWCNT) on the thermal and mechanical performance of Kevlar fiber reinforced novolac epoxy nanocomposites was investigated and presented in this paper. Nanocomposite containing 1.5 wt. % poly (vinyl butyral) and 0.5 wt. % f-MWCNT exhibited best thermal and mechanical properties (except flexural strength) among all the nanocomposites reported here. It showed ~5%, 27% and 126 % improvement in tensile strength, young’s modulus and impact strength respectively as compared to the neat novolac epoxy Kevlar composite.Nanocomposite containing 0.5 wt. % f- MWCNT and 2 wt. % poly (vinyl butyral)… More >

FEHMI SALTAN^1,2, AYLIN PALAMUTLU², HAKAN AKAT^2,*

Journal of Polymer Materials, Vol.36, No.2, pp. 133-147, 2019, DOI:10.32381/JPM.2019.36.02.3

Abstract In this work, tetraphenylporphyrin (TPP) compound was first synthesized by the condensation reaction of pyrrole and benzaldehyde using Adler method. Then, the synthesized tetraphenylporphyrin was nitrated with sodium nitrite. Nitro-functionalized porphyrin (TPP-NO₂ ) compound was reduced to amine-functional using ammonia and this amine- functionalized porphyrin was reacted with methacryloyl chloride to obtain porphyrin-derived radical monomer (TPP-MAO). Copolymer was synthesized with obtained porphyrin functional monomer and styrene by free radical polymerization method. Structural characterization and spectroscopic studies of the synthesized compounds were carried out by FTIR, H¹ -NMR, UV spectroscopy. The molecular weight and thermal properties of the copolymer were determined… More >

ASIS K. MANDAL¹, DEBABRATA CHAKRABORTY², MAHUYA DAS³, SAMIR K SIDDHANTA^4,*

Journal of Polymer Materials, Vol.38, No.1-2, pp. 21-34, 2021, DOI:10.32381/JPM.2021.38.1-2.3

Abstract Elastomeric chlorosulfonated polyethylene (Hypalon) and thermoplastic polypropylene (PP) based thermoplastic Vulcanizates (TPVs) were prepared in presence of different doses of partial methyl ester of styrene-maleic anhydride copolymer (PMES-MA) as compatibilizer employing dynamic vulcanization technique. The mechanical analysis of the prepared TPVs exhibited significant improvements in stress at 25% modulus, ultimate tensile strength (UTS), and hardness values. FTIR studies revealed that a chemical interaction had taken place between hypalon and compatibilizer during the process of dynamic vulcanization which led to an enhancement of interfacial adhesion between them. The two-phase morphologies were clearly observed by scanning electron microscopic studies. The Tg values… More >

ZHIHUI HUANG¹, JIAMIAO CHEN¹, YANPING HUO¹, JINGWEI ZHAO²

Journal of Polymer Materials, Vol.38, No.3-4, pp. 257-269, 2021, DOI:10.32381/JPM.2021.38.3-4.7

Abstract The effect of the ether/keto ratios on the thermal properties, mechanical performances and crystallization behavior of the Poly(aryl ether ketone)s (PAEK) were investigated. A formula was proposed the estimate the melting temperatures of the PAEKs with high accuracy. Glass transition temperatures were affected by the ether/keto ratios and molecular weights, and were related with the brittle-tough transition of the PAEKs. Mechanical performances of tensile, impact, flexural and compressive strength decreased with the increase of ether/keto ratios, while elongation had a trend of increase. The non-isothermal crystallization curves exhibited well linearity when treated with Jeziorny’s model, and two crystallization processes were… More >

DIBYENDU S. BAG^*, SHILPI TIWARI, AKANSHA DIXIT, KM. MEENU

Journal of Polymer Materials, Vol.40, No.1-2, pp. 105-123, 2023, DOI:10.32381/JPM.2023.40.1-2.9

Abstract In this paper, we report the microstructural investigation and influence of H-bonding on the thermal behavior e.g., glass transition (T_g ) and thermal degradation of chiral copolymers of (R)- N-(1-phenyl-ethyl) methacrylamide (R-NPEMAM) and 2-hydroxy ethyl methacrylate (HEMA). The T_g increases with the increase of chiral unit content in the copolymers and then attains optimum at around 25 mole % of chiral content. Thereafter it decreases with the increase of chiral content. The effect of copolymer composition and secondary interaction associated with the Hbonding on the thermal properties of these copolymers was also studied. Secondary interaction, specifically H-bonding has been interpreted… More >

Muhammad Abaid Ur Rehman^1,*, Muhammad Asif Farooq¹, Ahmed M. Hassan²

Frontiers in Heat and Mass Transfer, Vol.22, No.1, pp. 263-286, 2024, DOI:10.32604/fhmt.2023.044587

Abstract This paper proposes a mathematical modeling approach to examine the two-dimensional flow stagnates at over a heated stretchable sheet in a porous medium influenced by nonlinear thermal radiation, variable viscosity, and MHD. This study’s main purpose is to examine how thermal radiation and varying viscosity affect fluid flow motion. Additionally, we consider the convective boundary conditions and incorporate the gyrotactic microorganisms equation, which describes microorganism behavior in response to fluid flow. The partial differential equations (PDEs) that represent the conservation equations for mass, momentum, energy, and microorganisms are then converted into a system of coupled ordinary differential equations (ODEs) through… More >

Melanie Patrick^a, Messiha Saad^a,*

Frontiers in Heat and Mass Transfer, Vol.3, No.4, pp. 1-8, 2012, DOI:10.5098/hmt.v3.4.3007

Abstract Thermal characterization is essential to the proper assignment of composites to specific applications. Specific heat, thermal diffusivity, and thermal conductivity are critical in the engineering design process and in the analysis of aerospace vehicles, space systems, power generation, transportation systems, and energy storage devices including fuel cells. This paper examines the thermal properties through the thickness of Carbon-Carbon and the impact of Graphitization is explored. Following ASTM standards, the Flash Method and Differential Scanning Calorimetry measured thermal diffusivity and specific heat respectively. These measurements and density data allowed for the computation of thermal conductivity. More >

Jiachen Li^1,2, Wenlong Deng³, Shan Qing^1,2,*, Yiqin Liu⁴, Hao Zhang^1,2, Min Zheng^1,2

FDMP-Fluid Dynamics & Materials Processing, Vol.19, No.8, pp. 2181-2200, 2023, DOI:10.32604/fdmp.2023.027299

Abstract In this study, comparing multiple models of machine learning, a multiple linear regression (MLP), multilayer feed-forward artificial neural network (BP) model, and a radial-basis feed-forward artificial neural network (RBF-BP) model are selected for the optimization of the thermal properties of TiO₂/water nanofluids. In particular, the least squares support vector machine (LS-SVM) method and radial basis support vector machine (RB-SVM) method are implemented. First, curve fitting is performed by means of multiple linear regression in order to obtain bivariate correlation functions for thermal conductivity and viscosity of the nanofluid. Then the aforementioned models are used for a predictive analysis of the… More >