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  • Open Access

    ARTICLE

    Acidic Magnetic Biocarbon-Enabled Upgrading of Biomass-Based Hexanedione into Pyrroles

    Zhimei Li1, Kuan Tian2, Keping Wang2, Zhengyi Li2, Haoli Qin1,*, Hu Li2,*

    Journal of Renewable Materials, Vol.11, No.11, pp. 3847-3865, 2023, DOI:10.32604/jrm.2023.030122

    Abstract Sustainable acquisition of bioactive compounds from biomass-based platform molecules is a green alternative for existing CO2-emitting fossil-fuel technologies. Herein, a core–shell magnetic biocarbon catalyst functionalized with sulfonic acid (Fe3O4@SiO2@chitosan-SO3H, MBC-SO3H) was prepared to be efficient for the synthesis of various N-substituted pyrroles (up to 99% yield) from bio-based hexanedione and amines under mild conditions. The abundance of Brønsted acid sites in the MBC-SO3H ensured smooth condensation of 2,5-hexanedione with a variety of amines to produce N-substituted pyrroles. The reaction was illustrated to follow the conventional PallKnorr coupling pathway, which includes three cascade reaction steps: amination, loop closure and dehydration. The… More > Graphic Abstract

    Acidic Magnetic Biocarbon-Enabled Upgrading of Biomass-Based Hexanedione into Pyrroles

  • Open Access

    ARTICLE

    Hydroprocessing and Blending of a Biomass-Based DTG-Gasoline

    David Graf, Philipp Neuner, Reinhard Rauch*

    Energy Engineering, Vol.119, No.6, pp. 2169-2192, 2022, DOI:10.32604/ee.2022.022759

    Abstract The number of annually registered internal-combustion vehicles still exceeds electric-driven ones in most regions, e.g., Germany. Ambitious goals are disclosed with the European Green Deal, which calls for new technical approaches and greenhouse gas neutral transition technologies. Such bridging technologies are synthetic fuels for the transportation sector, e.g., using the bioliq® process for a CO2-neutral gasoline supply. Fuels must meet the applicable national standards to be used in existing engines. Petrochemical parameters can be variably adapted to their requirements by hydroprocessing. In this work, we considered the upgrading of aromatic-rich DTG gasoline from the bioliq® process. The heavy gasoline was… More >

  • Open Access

    ARTICLE

    Fuzzy Multi-criteria Decision Making for Decision Support in Port Capacity Upgrade

    Chia-Nan Wang, Tien–Lin Chao*

    CMC-Computers, Materials & Continua, Vol.73, No.2, pp. 2485-2494, 2022, DOI:10.32604/cmc.2022.026682

    Abstract In many port capacity upgrade projects, choosing a supplier of equipment is a complicated decision, project managers must consider many criteria to choose a supplier to ensure the project is completed on time, optimal in terms of benefit and cost. Therefore, selecting the equipment supplier in this project is a multi-criteria decision-making process. The multi-criteria decision-making (MCDM) model is applied in many fields to select the optimal solution, but there are very few studies using the MCDM model to support project managers in evaluating and selecting optimal solutions in port capacity upgrade project. In this research, the authors combine Fuzzy… More >

  • Open Access

    ARTICLE

    Upgrading the Quality of Solid Fuel Made from Nyamplung (Calophyllum inophyllum) Wastes Using Hydrothermal Carbonization Treatment

    Riina Syivarulli1,2, Nugroho Agung Pambudi2,*, Mochamad Syamsiro3, Lip Huat Saw4

    Energy Engineering, Vol.118, No.1, pp. 189-197, 2021, DOI:10.32604/EE.2020.010493

    Abstract One of the major problems faced in managing biomass waste to higher quality products is choosing the right technology. Wastes are used as an alternative fuel, with increase in the calorific value. Hydrothermal carbonization (HTC) is a biomass conversion technology, used to obtain solid fuel. This study aims to utilize of Calophyllum inophyllum as an alternative solid fuel through HTC. The calorific value and proximate of the hydrochar will be determined and analyzed to find out its quality. The experiments were carried out at temperature variations of 160°C, 190°C, and 220°C and holding times of 30 and 60 minutes. The… More >

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