GENG SU, YA-JIE JIANG, HONG-BIN JU, YA-KUI WANG, TAO GENG^*

Journal of Polymer Materials, Vol.36, No.4, pp. 293-304, 2019, DOI:10.32381/JPM.2019.36.04.1

Abstract Two kinds of poly quaternary ammonium salts (PQAS) namely PDMC (poly (methacryloxyethyl trimethyl ammonium chloride)), CPAM (methacryloxyethyl trimethyl ammonium chloride / acrylamide copolymer) were prepared. The chemical structures of the PQAS were characterized by Fourier transform infrared (FT-IR), nuclear magnetic resonance (¹ H NMR) spectrum, thermogravimetric analysis (TGA), and scanning electron microscope (SEM). The antibacterial activity of PQAS against three kinds of bacteria and one kind of fungus, was evaluated by the method described in QB/T 2738-2012. Antibacterial tests showed that the antibacterial activity increased with the increase of cationicity and molecular weight on PQAS. It shows the antimicrobial activity… More >

AYÇA BAL ÖZTÜRK^1,2,*, ZEHRA ÖZBA޳, BENGİ ÖZKAHRAMAN⁴, SERKAN EMİK⁵

Journal of Polymer Materials, Vol.36, No.2, pp. 161-173, 2019, DOI:10.32381/JPM.2019.36.02.5

Abstract A functionalized hydrogel composed of 2-(hydroxyethyl) methacrylate (HEMA) and acrylamide (AAm) was synthesized by amination and saponification reactions, respectively, and its functionality was examined for the elimination of copper(II) ions. The maximum adsorption capacity for copper(II) ions was 0.617 mmol g^-1 before saponification, whereas it was 1.2225 mmol g^-1 after saponification. The adsorption data was analyzed with pseudo-first-order (r² =0.8867), intra-particle diffusion (r² =0.9453), Elovich (r²=0.9489) and pseudo-secondorder(r² =0.9999) kinetic models. Based on the adsorption equilibrium experimental data Freundlich(r² =0.9964), Langmuir(r²=0.998) and Dubinin–Radushkevich (D-R) (r² =0.9960) adsorption isotherms provided good fits for all of experimental results. Finally, the datas of… More >

FATMA LOUZRI, SADJIA BENNOUR

Journal of Polymer Materials, Vol.37, No.1-2, pp. 55-76, 2020, DOI:10.32381/JPM.2020.37.1-2.5

Abstract Poly(N,N-dimethymethylacrylamide -co-crotonic acid) (P(DMA-CAx)) hydrogels were prepared by free radical polymerization, using N,N- methylenebisacrylamide (NMBA) as cross-linking agent. The synthesized hydrogels were characterized by Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA). The effects of comonomer composition and pH of the medium on the swelling behavior of hydrogels were investigated. The obtained results showed that the swelling capabilities of hydrogels increased as crotonic acid content and pH increased. In order to evaluate the controlled release potential of the polymeric matrix, it was loaded with potassium nitrate and ammonium nitrate as fertilizers and the release kinetics was studied as a… More >

ARCHANA KUMARI, KHEYANATH MITRA, SAMBHAV VISHWAKARMA, SOUROV MONDAL, SHIKHA SINGH, RAJSHREE SINGH, JAYDEEP SINGH, BISWAJIT MAITI, SUSANTA KUMAR SEN GUPTA, BISWAJIT RAY^*

Journal of Polymer Materials, Vol.37, No.3-4, pp. 143-164, 2020, DOI:10.32381/JPM.2020.37.3-4.3

Abstract A new acrylamide monomer N-(3-(hexylamino)-N-(3-(isopropylamino)-3-oxopropyl) acrylamide (HA-NIPAM-AM) and a new RAFT agent O-propionyl-2-(N,N-diphenylcarbamothioylthio) propanoate have successfully been synthesized and used for the synthesis of poly(HA-NIPAM-AM) homopolymers via RAFT polymerization. The formed homopolymers have been characterized by GPC, ¹ H NMR, FTIR, contact angle measurement, TG-DTA, DSC, and PXRD. Numberaveragemolar masses of the prepared polymers are in the range of 2,500 – 11,500 g/mol. Selfassembly of homopolymer has been studied viacmc determination in water using pyrene as fluorescence probe, HRTEM and DLS. Polymeris thermally stable up to 300 °C and has a glass transition temperature at 85.3 °C. XRD study reveals… More >

DIBYENDU S. BAG^*, SHILPI TIWARI, AKANSHA DIXIT, KM. MEENU

Journal of Polymer Materials, Vol.40, No.1-2, pp. 105-123, 2023, DOI:10.32381/JPM.2023.40.1-2.9

Abstract In this paper, we report the microstructural investigation and influence of H-bonding on the thermal behavior e.g., glass transition (T_g ) and thermal degradation of chiral copolymers of (R)- N-(1-phenyl-ethyl) methacrylamide (R-NPEMAM) and 2-hydroxy ethyl methacrylate (HEMA). The T_g increases with the increase of chiral unit content in the copolymers and then attains optimum at around 25 mole % of chiral content. Thereafter it decreases with the increase of chiral content. The effect of copolymer composition and secondary interaction associated with the Hbonding on the thermal properties of these copolymers was also studied. Secondary interaction, specifically H-bonding has been interpreted… More >

Shuangsheng Zhang, Bin Sun, Siyu Li, Xiangyu Lin, Muhua Chen^*, Xu Xu^*

Journal of Renewable Materials, Vol.11, No.2, pp. 853-865, 2023, DOI:10.32604/jrm.2022.022901

Abstract Hydrogels have been widely applied in agricultural drought-resistance, pollution regulation, drug delivery and so on. Acrylamide (AM) is usually used as raw material to synthesize acrylamide hydrogels. However, inherently low mechanical strength greatly limits their applications in some special areas. Therefore, it is necessary to choose suitable functional monomers to optimize acrylamide hydrogels and improve their mechanical performances. In this paper, a novel acrylamide monomer modified by rosin was synthesized, and then polyacrylamide/rosin-based acrylamide (RAM) composite hydrogels were prepared via free radical polymerization using potassium persulfate as initiator, N, N′-methylene-bisacrylamide (MBA) as a crosslinker. The influence of RAM monomer was… More > Graphic Abstract

Diego David Pinzón-Moreno^*, Eder Clidio Vicuña-Galindo, José Vulfrano González-Fernández, José Luis Soto-Gonzales, María Verónica Carranza-Oropeza^*

Journal of Renewable Materials, Vol.10, No.8, pp. 2179-2201, 2022, DOI:10.32604/jrm.2022.019793

Abstract Several hydrogels were synthesized by free-radical polymerization in an aqueous medium based on potato starch (PS), poly(vinyl alcohol) (PVA), and N,N′-Methylenebisacrylamide (MBAm), being possible to study these hydrogels as a function of the proportion of components incorporated. In this way, the products generated from the synthesis were characterized by swelling and deswelling kinetics, the first swelling being verified with Schott and statistical models, allowing to contrast the proximity between the experimental and theoretical behavior. Additionally, water retention in soil (R%), spectroscopy (FTIR), morphological (SEM), and thermal (TGA and DSC) analysis allowing to know the intrinsic characteristics of the material, increasing… More >

Lingqin Zhang, Qifeng Jiang, Yiming Zhao, Jie Yuan, Xiaoying Zha, Haojiang Xie, Fankai Kong, Xingliang Xiong^*

Journal of Renewable Materials, Vol.10, No.2, pp. 415-430, 2022, DOI:10.32604/jrm.2022.016650

Abstract The hydrogel is a preferred material for flexible wearable sensors. In practical application, it should have high-efficiency mechanical toughness and self-healing performance. Besides, hydrogel requires good affinity and adhesion because of its contact with the skin. In this experiment, we made an ultra-tough hydrogel with excellent cell affinity and adhesion. We used sodium alginate (SA) and polyacrylamide (PAm) mixture as a flexible base fluid. Polydopamine reduce graphene oxide (prGO) was used as conductive nanofiller, and then PAm-prGO-SA semi-interpenetrating network hydrogel was formed through Am radical polymerization. The presence of prGO endows the hydrogels with excellent electrical conductivity. Simultaneously, some non-reduced… More >

Shengquan Zhou¹, Minjie Shi^1,*, Wei Chen¹, Yongfei Zhang¹, Weijian Wang¹, Haojin Zhang¹, Dongwei Li²

Journal of Renewable Materials, Vol.9, No.11, pp. 1941-1957, 2021, DOI:10.32604/jrm.2021.015693

Abstract The characteristics of soil treated with cationic polyacrylamide (CPAM) mass content of 0%, 0.2%, 0.4%, 0.6%, 0.8%, and 1% were investigated through a series of laboratory tests to explore the practical engineering effect of an expansive soil amended with environmental protection material CPAM. The results indicate that with the increasing CPAM content, the liquid limit and plasticity index of soil decrease, the plastic limit increases, and the free swelling ratio and loaded swelling ratio decrease. Besides, the improved soil has less disintegrating property and better water stability. The shear strength increases as the content increases, and the optimal content is… More > Graphic Abstract

Zheng Cao^1,2,3,4,*, Yang Zhang², Keming Luo², Yinqiu Wu², Hongxin Gao², Junfeng Cheng^2,*, Chunlin Liu^2,3, Guoliang Tao², Qingbao Guan¹, Lei Zhang⁵

Journal of Renewable Materials, Vol.9, No.8, pp. 1447-1462, 2021, DOI:10.32604/jrm.2021.015593

Abstract

The preparation and application of functional hydrogels based on natural polysaccharides have always been a hot research topic. In this study, using acrylamide (AM) monomer, N, N'-methylene bisacrylamide (MBA) as cross-linking agent, potassium persulfate (K₂S₂O₈) as initiator, in the presence of natural polysaccharide sodium alginate (SA), the PAM/SA hydrogel was prepared by free radical polymerization. Fourier transform infrared spectroscopy (FT-IR), swelling performance tests, scanning electron microscope (SEM), thermogravimetric analysis (TGA), UV-visible spectrophotometer, mechanical property measurements were carried out to analyze the composition, morphology, and performance of the hydrogels. The swelling behavior, dye adsorption performance, and the mechanical properties of PAM/SA… More >