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  • Open Access

    ABSTRACT

    Coupling Atomistic and Continuum Finite Element Models: Multi-Scale Simulations of Nanotribological Contacts of Nanometer Scale Coatings

    Baolin Wang1

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.8, No.2, pp. 81-84, 2008, DOI:10.3970/icces.2008.008.081

    Abstract When the size of a physical system is smaller than its characteristic dimensions, the macroscopic viewpoint may not be applicable. In addition, experiments at micro/nanometer scale are difficult and the analysis of nano-experimental data is far from simple. This is mostly due to the lack of effective models that are able to study the structural characteristics and mechanics behavior of the micro/nanometer physical systems. Atomic simulation simulation has been used extensively in the investigation of nanoscale phenomena. However, the size limit of atomic simulation is far short to reach the macroscale because of the limitation in computer capacity. Therefore, the… More >

  • Open Access

    ARTICLE

    Edible Coatings Based on Apple Pectin, Cellulose Nanocrystals, and Essential Oil of Lemongrass: Improving the Quality and Shelf Life of Strawberries (Fragaria Ananassa)

    Ingrid Souza Vieira da Silva1, Natália Soares Prado1, Patrícia Gontijo de Melo2, Danilo Campion Arantes3, Mara Zeni Andrade4, Harumi Otaguro1, Daniel Pasquini1,*

    Journal of Renewable Materials, Vol.7, No.1, pp. 73-87, 2019, DOI:10.32604/jrm.2019.00042

    Abstract In this work, nine different types of edible coating based on pectin, cellulose nanocrystals, glycerol, and essential oil of lemongrass were prepared and used to coat strawberries with a film formed directly on the surface of the coated fruit. The effects of the different edible coatings on refrigerated fruits in terms of weight loss, titratable acidity, total soluble solids, pH, and anthocyanin content was evaluated after 2 days, 4 days, 6 days, and 8 days of storage. Application of the edible coatings reduced the weight loss of the coated strawberries and the anthocyanin content. The total soluble solids content of… More >

  • Open Access

    ARTICLE

    Synthesis and Characterization of Novel Castor Oil-Based Polyol for Potential Applications in Coatings

    Azam Sardari1,2, Ali Asghar Sabbagh Alvani1,2,3,*, Seyed Reza Ghaffarian1,2

    Journal of Renewable Materials, Vol.7, No.1, pp. 31-40, 2019, DOI:10.32604/jrm.2019.00045

    Abstract In this study, three sorts of polyols were successfully synthesized from castor oil using a Dean-Stark quick, eco-friendly and high-efficiency method. For this purpose, castor oil was epoxidized in the presence of two types of catalysts including γ-alumina and formic acid, named as ECOAl and ECOF, respectively. Epoxidized castor oils were then characterized by use of hydrogen nuclear magnetic resonance (H-NMR) and oxirane oxygen content analysis. The relative percentages of conversion double bond to oxirane were obtained 96% and 74% for ECOAl and ECOF, respectively. Ring opening reaction of ECOAl was performed by two types of saponified castor oil as… More >

  • Open Access

    ARTICLE

    Properties of Polyurethane Coatings Based on Linseed Oil Phosphate Ester Polyol

    A. Abolins*, V. Yakushin and D. Vilsone

    Journal of Renewable Materials, Vol.6, No.7, pp. 737-745, 2018, DOI:10.32604/JRM.2018.00119

    Abstract Linseed oil was epoxidized using hydrogen peroxide (H2O2), acetic acid (AcOH) and ion exchange resin Amberlite IR-120 as a catalyst. Epoxidized oil was separately dissolved in isopropyl alcohol (IPA) or diethylene glycol butyl ether (DGBE) and phosphorylated with different amounts of phosphoric (H3PO4) acid (1%, 2%, 3% and 5%). The formation of phosphate polyesters was confirmed by Fourier-transform infrared (FTIR) and 31P nuclear magnetic resonance (NMR) spectra. Based on the synthesized polyols, polyurethane (PU) coatings were prepared. PU coating based on linseed oil diethylene glycol ester polyol was used as the reference. For the characterization of coatings, mechanical tests and… More >

  • Open Access

    ARTICLE

    Cardanol-Based Polyurethane Coatings via Click Chemistry: An Eco-friendly Approach

    Kunal Wazarkar, Anagha Sabnis*

    Journal of Renewable Materials, Vol.6, No.5, pp. 517-528, 2018, DOI:10.7569/JRM.2017.634181

    Abstract This research work discloses the preparation of polyurethane coatings from cardanol modified using thiolene chemistry, wherein unsaturated long alkyl chain of cardanol was successfully utilized via thiol-ene click reaction to synthesize polyol. For this purpose, cardanol and thioglycerol was reacted in the presence of Irgacure 184 (photoinitiator) and 1,8-Diazabicyclo[5.4.0]undec-7-ene (catalyst) and exposed to UV light for 12 h at 80 °C. One mole of thioglycerol was successfully added across the double bond of fatty chain of cardanol and confirmed by chemical and spectroscopic analysis. Further, the polyol thus prepared was cured with various polyisocyanates, viz., N-75 (HDI based), L-67/BA (TDI… More >

  • Open Access

    ARTICLE

    Thermal Stress Analysis of Multi-layer Thin Films and Coatings by an Advanced Boundary Element Method

    Xiaolin Chen, Yijun Liu1

    CMES-Computer Modeling in Engineering & Sciences, Vol.2, No.3, pp. 337-350, 2001, DOI:10.3970/cmes.2001.002.337

    Abstract An advanced boundary element method (BEM) is developed in this paper for analyzing thin layered structures, such as thin films and coatings, under the thermal loading. The boundary integral equation (BIE) formulation for steady-state thermoelasticity is reviewed and a special case, that is, the BIE for a uniform distribution of the temperature change, is presented. The new nearly-singular integrals arising from the applications of the BIE/BEM to thin layered structures under thermal loading are treated in the same way as developed earlier for thin structures under the mechanical loading. Three 2-D test problems involving layered thin films and coatings on… More >

  • Open Access

    ARTICLE

    Modeling a Discontinuous CVD Coating Process: I. Model Development and Validation

    Joseph G. Lawrence, Arunan Nadarajah1

    FDMP-Fluid Dynamics & Materials Processing, Vol.3, No.3, pp. 247-254, 2007, DOI:10.3970/fdmp.2007.003.247

    Abstract A simplified 2D pseudo steady state model was developed for an atmospheric chemical vapor deposition (CVD) process on glass. This is used to study the feasibility of converting a continuous coating process to one with discrete glass plates with a gap between them. A preliminary estimate employing mass transfer correlations suggested that there would be significant concentration variations due to the gap between the plates. More detailed studies were done by solving the model numerically employing a finite difference scheme with a vorticity-stream function formulation, and employing the commercial computational fluid dynamics program FIDAP which employs a finite element scheme.… More >

  • Open Access

    ARTICLE

    Effects of TGO Roughness on Indentation Response of Thermal Barrier Coatings

    Taotao Hu1, gping Shen1,2

    CMC-Computers, Materials & Continua, Vol.17, No.1, pp. 41-58, 2010, DOI:10.3970/cmc.2010.017.041

    Abstract In this paper, an axisymmetric indentation model is set up to calculate the effects of the roughness of the thermally grown oxide (TGO) layer, which was modeled as a sinusoidal wave, on the indentation response of the thermal barrier coatings. It is found that the amplitude, wavelength, and thickness of the thermally grown oxide layer have obvious influences on the indentation response, while the effect of the indenter position can be neglected. In the top coating layer, residual stress mainly occurs below the indenter and around the nearest two peaks of the thermally grown oxide layer to the indenter. Only… More >

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