Wen Qi¹, Yu-Fei Du¹, Bo-Han Chen², Gui-Lei An^1,3,*, Chun Lu^4,*

CMC-Computers, Materials & Continua, Vol.85, No.2, pp. 2763-2780, 2025, DOI:10.32604/cmc.2025.069505 - 23 September 2025

Abstract In the production process of silicone sealant, mineral oil is used to replace methyl silicone oil plasticizer in silicone sealant to reduce costs and increase efficiency. However, the silicone sealant content in mineral oil is prone to premature aging, which significantly reduces the mechanical properties of the silicone sealant and severely affects its service life. At the same time, there are few reports on the simulation research of the performance of silicone sealant. In this study, three mixed system models of crosslinking silicone sealant/plasticizer are constructed by the molecular dynamics simulation method, and the effect… More >

RAZIEH MOMEN-MESGIN¹, JAFAR REZAIE^2,*, VAHID NEJATI¹, PEYMAN NAJAFI MOGHADAM³

Oncology Research, Vol.33, No.3, pp. 665-674, 2025, DOI:10.32604/or.2024.054487 - 28 February 2025

Abstract Objectives: Due to systematic side effects, there is a growing interest in nanoparticle formulation of anticancer drugs. Here, we aimed to synthesize poly (styrene-alt-maleic anhydride) cross-linked by melamine (PSMA/Me) and coated with magnetite nanoparticles (MNPs) PSMA/Me/Fe₃O₄. In addition, we aimed to load paclitaxel (PTX) into PSMA/Me/Fe₃O₄ for drug delivery and anticancer investigations. Methods: Novel PSMA/Me was synthesized via free radical copolymerization, coated with Fe₃O₄, and then used as a transporter for PTX delivery. Fabricated copolymer was characterized using SEM, TGA, and XRD techniques. Drug release rate and loading efficiency were investigated. Human ovarian cancer cells (Skov-3) and… More >

Xianzhi Chen¹, Dong Niu^1,*, Hongtao Gao¹, Mu Du^2,3,*

Frontiers in Heat and Mass Transfer, Vol.22, No.6, pp. 1743-1760, 2024, DOI:10.32604/fhmt.2024.058274 - 19 December 2024

Abstract Thermosensitive hydrogel can integrate vapor molecular capture, in-situ liquefaction, and thermal-induced water release for freshwater capture. This study aimed to examine the dynamic behavior of poly (N-isopropylacrylamide) (PNIPAM) single chain and cross-linking thermosensitive hydrogel through molecular dynamics simulation. Specifically, the impact of lower critical solution temperature (LCST) on the conformation of polymer chain and the interaction between water and polymer chain were also investigated. The polymer chain conformation underwent a transition from coil to globule when the temperature exceeded the LCST, indicating the temperature responsiveness of PNIPAM. Additionally, thermosensitive hydrogel samples with different cross-linking degrees (DOC) More > Graphic Abstract

Bengang Zhang^1,*, Antonio Pizzi^2,*, Mathieu Petrissans¹, Anelie Petrissans¹, Colin Baptiste¹

Journal of Renewable Materials, Vol.11, No.12, pp. 4097-4121, 2023, DOI:10.32604/jrm.2023.029761 - 10 November 2023

Abstract Aminated tannins were prepared by reacting mimosa condensed tannin extract with ammonia yielding the substitution of many, if not all of the tannin hydroxyl groups with –NH₂ groups. A tannin-aminated tannin (ATT) particleboard coating was then prepared by reacting raw tannin extract with aminated tannin extract and thus cross-liking the two by substituting tannin’s hydroxyl groups with the –NH₂ groups on the aminated tannin to form –NH-bridges between the two. The resulting particleboard coating gave encouraging results when pressed at 180°C for 3 min. Conversely, the system in which tannin was reacted/cross-liked with urea (ATU) by… More >

Henky Muljana^*, Ivana Hasjem, Merianawati Sinatra, Dicky Joshua Pesireron, Michael Wilbert Puradisastra, Ryan Hartono, Kevin Yovan Hermanto, Tony Handoko

Journal of Renewable Materials, Vol.11, No.12, pp. 4039-4060, 2023, DOI:10.32604/jrm.2023.031261 - 10 November 2023

Abstract This research paper describes the synthesis of thermo-reversible cross-linking of sago starch by grafting a furan pendant group (methyl 2-furoate) onto the starch backbone, followed by a Diels-Alder (DA) reaction of the furan functional group with 1,1′-(methylenedi-4,1-phenylene) bismaleimide (BM). The proof of principles was provided by FTIR and ¹H-NMR analyses. The relevant FTIR peaks are the carbonyl peak (υ C=O sym) at 1721 cm⁻¹ ; the two peaks appeared after DA cross-linking, i.e., at 1510 cm⁻¹ (corresponding to υ CH=CH BM aromatic rings, stretching vibrations), and at 1173 cm⁻¹ (assigned to cycloadduct (C-O-C, δ DA ring)) while More > Graphic Abstract

Lei Liu^*, Shenao Pang, Zhuhui Luo

Journal of Renewable Materials, Vol.11, No.11, pp. 3891-3906, 2023, DOI:10.32604/jrm.2023.028192 - 31 October 2023

Abstract The recycling of carbon fibers and protection from unwanted microwave radiation are two important environmental issues that need to be addressed in modern society. Herein, branched carbon nanofibers (CNFs) were grown in-situ on recycled carbon fibers (RCFs) through the chemical vapor deposition method using nickel as catalysts and thiophene as aided-catalysts. The effect of thiophene on the growth morphology of CNFs was investigated. Correspondingly, branched CNFs-RCFs and straight CNFs-RCFs were respectively obtained in the presence and absence of thiophene. The microstructure and electromagnetic behaviour investigations have shown that the branched CNFs possess a typical multi-branched structure, More > Graphic Abstract

Yuhui Huang¹, Zhiyuan Yin^1,2, Ming Liu¹, Meng Li¹, Yingfeng Zuo¹, Yan Qing¹, Yiqiang Wu^1,*

Journal of Renewable Materials, Vol.11, No.9, pp. 3417-3431, 2023, DOI:10.32604/jrm.2023.028511 - 20 July 2023

Abstract The poor bonding performance between aqueous adhesives represented by melamine-urea formaldehyde (MUF) resins and reed straw hinders their applications in the field of non-wood-based panels. Multi-hydroxyl polymers are highly reactive and are often used as crosslinkers. This study fabricated a resin with a strengthened cross-linked structure by combining a multi-hydroxyl polymer and MUF resin prepolymer. The reed particleboard was prepared by using this resin as an adhesive and reed stalk as the matrix. The results show that neighboring molecules combined to form C–O–C bonds that strengthened the cross-linked structure of the resin. In addition, the… More >

Yalin Li^1,*, Lei Liu¹, Wenbao Huang¹, Junpu Xie², Zhaoxia Song¹, Shuna Guo¹, Enci Wang¹

Journal of Renewable Materials, Vol.11, No.7, pp. 3001-3023, 2023, DOI:10.32604/jrm.2023.026604 - 05 June 2023

Abstract To achieve optimal recovery and value-added utilisation of cellulose in peanut shells, the cellulose in peanut shells was first extracted using the sodium hydroxide-sodium chlorite method. Then, cellulose hydrogel was prepared by graft copolymerisation using N, N’-methylenebisacrylamide as the cross-linking agent, sodium persulfate as the initiator, and acrylic acid as the monomer. Orthogonal optimisation experiments were designed to obtain optimal process parameters for hydrogel preparation with the cellulose dosage of 0.40 g, initiator dosage of 0.20 g, polymerisation temperature of 70°C, cross-linking agent of 0.25 g, and monomer dosage of 3.0 mL. The effect of initiator… More > Graphic Abstract

Xueyu Zhao^*

FDMP-Fluid Dynamics & Materials Processing, Vol.19, No.7, pp. 1897-1905, 2023, DOI:10.32604/fdmp.2023.025247 - 08 March 2023

Abstract A method for the treatment of hazardous waste drilling fluids, potentially leading to environmental pollution, is considered. The waste drilling fluid is treated with an inorganic flocculant, an organic flocculant, and a pH regulator. The profile control agent consists of partially hydrolyzed polyacrylamide, formaldehyde, hexamethylenetetramine, resorcinol, phenol, and the treated waste drilling fluid itself. For a waste drilling fluid concentration of 2500 mg/L, the gelling time of the profile control agent is 25 h, and the gelling strength is 32,000 mPa.s. Compared with the profile control agent prepared by recirculated water under the same conditions, the present More >

Eglė Malachovskienė^1,*, Danguolė Bridžiuvienė¹, Jolita Ostrauskaitė², Justina Vaičekauskaitė², Gailė Žalūdienė³

Journal of Renewable Materials, Vol.11, No.3, pp. 1255-1269, 2023, DOI:10.32604/jrm.2022.023574 - 31 October 2022

Abstract The biodegradation of polymeric biocomposites formed from epoxidized linseed oil and various types of fillers (pine needles, pine bark, grain mill waste, rapeseed cake) and a control sample without filler was studied during 180 days of exposure to two types of forest soil: deciduous and coniferous. The weight loss, morphological, and structural changes of polymer composites were noticed after 180 days of the soil burial test. The greatest weight loss of all tested samples was observed in coniferous forest soil (41.8%–63.2%), while in deciduous forest soil, it ranged between 37.7% and 42.3%. The most significant… More >