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  • Open Access

    ARTICLE

    A Vanillin-Derived, DOPO-Contained Bisphenol as a Reactive Flame Retardant for High-Performance Epoxy Thermosets

    Li Wang1,2,#, Rongbai Tong3,#, Juanli Wang1,2,*, Jintao Wan1,2,*, Yuhu Li1,2, Pujun Jin1,2, Daodao Hu1,2

    Journal of Renewable Materials, Vol.10, No.5, pp. 1349-1364, 2022, DOI:10.32604/jrm.2022.019372

    Abstract Quest for bio-based halogen-free green flame retardant has attracted many concerns in recent years. Herein a reactive functional flame retardant containing phosphorus VDP is synthesized from vanillin, 9,10-dihydro-9-oxa-10-phosphophene-10-oxide (DOPO) and phenol via a facile way. VDP is characterized with 1H NMR, 31P NMR, FTIR and Time of Flight Mass Spectrometry, and used as a new reactive flame retardant for bisphenol epoxy thermosets. Thermogravimetry analysis shows that when the VDP loading is only 0.5P% (based on phosphorus content), the residue increases from 14.2% to 21.1% at 750°C in N2 compare with neat DGEBA. Correspondingly, the limit oxygen index increased to 29.6%,… More >

  • Open Access

    ARTICLE

    Modeling and Optimization of Surface Roughness of Epoxy/Nanoparticles Composite Coating

    A. F. Mohamed1,2, J. Abu Alsoud1, Mujahed Al-Dhaifallah3,*, Hegazy Rezk4,5, Mohamed K. Hassan1,6

    CMC-Computers, Materials & Continua, Vol.71, No.1, pp. 71-83, 2022, DOI:10.32604/cmc.2022.019257

    Abstract In power plants, flue gases can cause severe corrosion damage in metallic parts such as flue ducts, heat exchangers, and boilers. Coating is an effective technique to prevent this damage. A robust fuzzy model of the surface roughness (Ra and Rz) of flue gas ducts coated by protective composite coating from epoxy and nanoparticles was constructed based on the experimental dataset. The proposed model consists of four nanoparticles (ZnO, ZrO2, SiO2, and NiO) with 2%, 4%, 6%, and 8%, respectively. Response surface methodology (RSM) was used to optimize the process parameters and identify the optimal conditions for minimum surface roughness… More >

  • Open Access

    ARTICLE

    Dynamic Mechanical and Chemorheology Analysis for the Blended Epoxy System with Polyurethane Modified Resin

    Xue Xin1,#, Yu Rong1,#, Linping Su1, Zhengmei Qiu1, Chenjun Yang1, Ming Liang1,*, Ping Ji2, Guoqiang Zhong3, Zhanyong Yao1,*

    Journal of Renewable Materials, Vol.10, No.4, pp. 1081-1095, 2022, DOI:10.32604/jrm.2022.018021

    Abstract As the important matrix material, epoxy resin has been widely used in the composites for various fields. On account of the poor toughness of epoxy resin limiting their suitability for advanced applications, considerable interests have been conducted to modify the epoxy resin to meet the engineering requirements. In this study, the bio-based polyurethane (PU) modified resin was adopted to modify the pure bisphenol-A epoxy by blending method with various proportions. Aiming to illuminate the curing behavior, mechanical and thermal properties, the blended epoxy systems were characterized by viscosity-time analysis, dynamic mechanical analysis (DMA) at different frequencies and temperatures, mechanical tensile… More >

  • Open Access

    ARTICLE

    Simulation of Elastic and Fatigue Properties of Epoxy/SiO2 Particle Composites through Molecular Dynamics

    Gaoge Zhao, Jianzhong Chen, Yong Lv*, Xiaoyu Zhang, Li Huang

    CMES-Computer Modeling in Engineering & Sciences, Vol.128, No.1, pp. 339-357, 2021, DOI:10.32604/cmes.2021.015388

    Abstract The influence of different nanoparticle sizes on the elastic modulus and the fatigue properties of epoxy/SiO2 nanocomposite is studied in this paper. Here, the cross-linked epoxy resins formed by the combination of DGEBA and 1,3-phenylenediamine are used as the matrix phase, and spherical SiO2 particles are used as the reinforcement phase. In order to simulate the elastic modulus and long-term performance of the composite material at room temperature, the simulated temperature is set to 298 K and the mass fraction of SiO2 particles is set to 28.9%. The applied strain rate is 109/s during the simulation of the elastic modulus.… More >

  • Open Access

    ARTICLE

    Fiber Loading of Date Palm and Kenaf Reinforced Epoxy Composites: Tensile, Impact and Morphological Properties

    Syed Waheedullah Ghori1,*, G. Srinivasa Rao2

    Journal of Renewable Materials, Vol.9, No.7, pp. 1283-1292, 2021, DOI:10.32604/jrm.2021.014987

    Abstract Date palm fiber (DPF) and kenaf fiber were reinforced in epoxy having various fiber loading 40%, 50%, and 60% by weight. These hybrid samples were manufactured by hot press technique and then characterized for tensile, impact, and morphological behavior to evaluate the ratio of fibers in the hybrid composites; the addition of kenaf improved the tensile properties, Scanning Electron Microscopy (SEM) revealed the interfacial bonding of fiber/matrix, and dispersion and void content in composites. Impact test studies reflected the effect of natural fiber with epoxy, level of stress transfer from matrix to reinforced material, and reinforced material’s role in absorbing… More > Graphic Abstract

    Fiber Loading of Date Palm and Kenaf Reinforced Epoxy Composites: Tensile, Impact and Morphological Properties

  • Open Access

    ARTICLE

    Evaluation of Mechanical and Physical Properties of Pressed Coir Fiber/Epoxy Composite with NaOH and Microwave Treatment of Fiber

    Ilyas Renreng1, Bakri Bakri2,*, Sri Chandrabakty2, Naharuddin2

    Journal of Renewable Materials, Vol.9, No.2, pp. 325-335, 2021, DOI:10.32604/jrm.2021.012774

    Abstract In this study, the influence of sodium hydroxide (NaOH) treatment and microwave treatment of coir fibers on the mechanical and physical properties of pressed coir fiber/epoxy composite were evaluated. The composite was fabricated with a hand lay-up method with compression molding. Before composite fabrication, pressed coir fiber was treated with NaOH and microwave treatments. Mechanical testing (tensile, flexural, and impact testing) of the composite was conducted. Then, water absorption and thickness swelling testing are also performed. The fractured composite surface morphology after the tensile test was analyzed by scanning electronic microscopy (SEM). The results revealed that tensile, flexural, and impact… More >

  • Open Access

    ARTICLE

    Simulation Analysis on Mechanical Property Characterization of Carbon Nanotubes Reinforced Epoxy Composites

    Dan Li1, Li Ding1, Zhengang Liu2, Qiang Li3, Kaiyun Guo1, Hailin Cao1,4,*

    CMES-Computer Modeling in Engineering & Sciences, Vol.125, No.1, pp. 145-171, 2020, DOI:10.32604/cmes.2020.010822

    Abstract Carbon nanotube (CNT)-reinforced composites have ultra-high elastic moduli, low densities, and fibrous structures. This paper presents the multi-scale finite element modeling of CNT-reinforced polymer composites from micro- to macro-scales. The nanocomposites were modeled using representative volume elements (RVEs), and finite element code was written to simulate the modeling and loading procedure and obtain equivalent mechanical properties of the RVEs with various volume fractions of CNTs, which can be used directly in the follow-up simulation studies on the macroscopic model of CNT-reinforced nanocomposites. When using the programming to simulate the deformation and fracture process of the CNT-reinforced epoxy composites, the mechanical… More >

  • Open Access

    ARTICLE

    Synthesis of Bio-Plasticizer from Soybean Oil and Its Application in Poly(Vinyl Chloride) Films

    Xiao Luo1,*, Hongying Chu2, Mengqi Liu1

    Journal of Renewable Materials, Vol.8, No.10, pp. 1295-1304, 2020, DOI:10.32604/jrm.2020.011026

    Abstract Herein, epoxidized soybean oil methyl ester (ESOM) plasticizer was synthesized for the preparation of plasticized poly(vinyl chloride) (PVC) films by the alcoholysis and epoxidation. The chemical structure of ESOM was investigated by infrared spectrum and 1H nuclear magnetic resonance. The effect of content of ESOM and petroleum based plasticizer di-2-ethylhexyl phthalate (DEHP) on the performance of plasticized PVC films was studied. The result showed that substituting DEHP with ESOM can improve the thermal stability of plasticized PVC films. When the weight ratio of ESOM and PVC is fixed at 1:2, plasticized PVC film presents higher elongation at break (350.8% vs.… More >

  • Open Access

    ARTICLE

    Component Optimization and Seepage Simulation Method of Resin Based Permeable Brick

    Xiaofu Wang1,*, Xiong Zhang1, Yan He2, Chunming Lian3

    Journal of Renewable Materials, Vol.8, No.8, pp. 947-968, 2020, DOI:10.32604/jrm.2020.011327

    Abstract In order to solve the problem of urban surface runoff, it is necessary to study permeable brick deeply. Tensile test and DMA test were used to study the binder material of permeable brick, and a material with the best mechanical properties was selected as the binder of resin based permeable brick; The permeable brick with single gradation and continuous gradation and porosity of 0.1–0.5 gradient is constructed by 3D modeling method. The particle composition and the seepage simulation results of permeable brick under different design parameters were analyzed; A resin-based permeable brick with micro-pores was prepared using the selected binder… More >

  • Open Access

    ARTICLE

    Experimental Study on the Influence Mechanism of Carbon Fiber/Epoxy Composite Reinforcement and Matrix on Its Fire Performance

    Lei Zhang1, Haiyan Wang1,*, Junpeng Zhang1, Zhi Wang2, Zuohui Xu1, Xinyu Gao1

    Journal of Renewable Materials, Vol.8, No.3, pp. 219-237, 2020, DOI:10.32604/jrm.2020.09096

    Abstract The effects of the number of layers, the arrangement of carbon fiber (CF) tow and the epoxy resin (ER) matrix on the fire performance of carbon fiber/epoxy composites (CFEC) were studied by a variety of experimental methods. The results show that the number of layers of CF tow has influence on the combustion characteristics and fire propagation of the composites. The arrangement of CF tow has influence on flame propagation rate and high temperature mechanicalproperties. The mechanism of the influence of the number of layers of CF tow on the composite is mainly due to the different thermal capacity of… More >

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