Tobias Drieschner^1,2,*, Andreas Kandelbauer¹, Bernd Hitzmann², Karsten Rebner¹

Journal of Renewable Materials, Vol.11, No.4, pp. 1643-1660, 2023, DOI:10.32604/jrm.2023.024429

Abstract For optimization of production processes and product quality, often knowledge of the factors influencing the process outcome is compulsory. Thus, process analytical technology (PAT) that allows deeper insight into the process and results in a mathematical description of the process behavior as a simple function based on the most important process factors can help to achieve higher production efficiency and quality. The present study aims at characterizing a well-known industrial process, the transesterification reaction of rapeseed oil with methanol to produce fatty acid methyl esters (FAME) for usage as biodiesel in a continuous micro reactor set-up. To this end, a… More >

Aman Santoso^*, Sumari Sumari, Muhammad Roy Asrori

Energy Engineering, Vol.119, No.6, pp. 2255-2276, 2022, DOI:10.32604/ee.2022.021596

Abstract Biodiesel research has been carried out via transesterification. However, biodiesel products (methyl esters) have not encountered new insights, because feedstocks have been explored and studied. Various optimum conditions on transesterification reaction could produce different methyl ester type with different compound. So, this review describes various oil feedstock that were to find new insights about methyl ester type. The review took the results of study that has been published with experience for 10 years. The results of the study reviewed on the transesterification method, characterization of methyl esters, and its components. The component reviewed and correlated to the literature, structure, and… More > Graphic Abstract

Sumari Sumari^*, Mega Murti, Aman Santoso, Muhammad Roy Asrori

Journal of Renewable Materials, Vol.10, No.12, pp. 3659-3670, 2022, DOI:10.32604/jrm.2022.022995

Abstract Kapok seed oil is an environmentally friendly biodiesel feedstock. The problem of the best catalyst for transesterification of Kapok seed oil still continues today. The research developed a base-heterogeneous catalyst with the effect of ultrasonic waves during transesterification. So, the study aims: (1) to determine the type of natural zeolite used, (2) to determine the characteristics of the synthesized CaO:BaO/ANZ catalyst, and (3) to determine the effectiveness of the CaO:BaO/ANZ catalyst in the biodiesel production process through sono-transesterification of kapok seed oil. The research stages consisted of: (1) activation of natural zeolite and its characterization, (2) preparation of CaO:BaO/ANZ catalyst,… More > Graphic Abstract

Hamed Younesi-Kordkheili^1,*, Antonio Pizzi²

Journal of Renewable Materials, Vol.10, No.2, pp. 237-246, 2022, DOI:10.32604/jrm.2022.017851

Abstract The aim of this research was to investigate the effect of ionic liquid treated lignin-based polyacid as a catalyst for urea-formaldehyde (UF) resins. Esterification of lignin was carried out, without any catalyst, with anhydride maleic and 1-butyl-3-methylimidazolium hydrogen sulfate [Bmim][HSO₄] as acidic ionic liquid to form maleated lignin-based polyacids (MA-IL). The performance of MA-IL as UF resin catalyst was respectively compared to hyroxymethylated lignin-based polyacid (MA-HL) and to NH₄Cl. The FTIR analysis indicated that the proportion of -COOH and C-O bonds increased due to the esterification of lignin with ionic liquid rather than its hyroxymethylation. Physicochemical tests indicated that the… More >

Nuni Widiarti¹, Yatim Lailun Ni’mah¹, Hasliza Bahruji², Didik Prasetyoko^1,*

Journal of Renewable Materials, Vol.7, No.10, pp. 915-939, 2019, DOI:10.32604/jrm.2019.07183

Abstract Biodiesel is a fossil fuel that is in demand to be developed because it is bio-renewable, biodegradable and environmentally friendly. Biodiesel produced from the transesterification reaction of vege Tab. oil using a base catalyst. CaO is the most developed catalyst for the reaction of transesterification of oil into biodiesel because it is cheap, the process is easy and has a high level of alkalinity. CaO is a cheap catalyst because it is easily obtained from natural ingredients. The use of CaO catalysts in the reaction formation of biodiesel continues to develop through modification with various porous materials and different oxide… More >

Md. Anwar Hossain^1,2, Lee Hwei Voon^1,*

Journal of Renewable Materials, Vol.7, No.8, pp. 731-748, 2019, DOI:10.32604/jrm.2019.04703

Abstract Synthesizing polyol-based ester from biomass feedstocks for the preparation of biolubricant overcomes the dependence on petroleum oil usage. Albeit biomass-derived bio-oil is an alternative for the production of polyol ester, upgrading is essential prior to use as biolubricant. Levulinic acid (LA), obtained from bio-oil was applied for the catalytic esterification with two polyols, e.g., trimethylolpropane (TMP) and pentaerythritol (PE), in the presence of mixed-ligand Ni(II), Co(II), and Fe(II) complexes as catalyst. New mixed-ligand coordination complexes with empirical formula; [Ni(Phe)(Bpy)Cl].H2O, [Co(Phe)(Bpy)Cl].H2O, and [Fe(Phe)(Tyr)Cl].H2O were synthesized by the reaction of ligands [L-phenylalanine (Phe), 4,4'-bipyridine (Bpy), and L-tyrosine (Tyr)] with metal chloride salts… More >

Nívia do Nascimento Marques¹, Caroline Suzy do Nascimento Garcia¹, Liszt Yeltsin Coutinho Madruga¹, Marcos Antônio Villetti², Men de SáMoreira de Souza Filho³, Edson Noriyuki Ito⁴, Rosangela de Carvalho Balaban^1,*

Journal of Renewable Materials, Vol.7, No.2, pp. 139-152, 2019, DOI:10.32604/jrm.2019.00040

Abstract After industrial mango processing, tons of residues such as peels and kernels are discarded as waste. Nevertheless, almost 60% of the mango kernel is due to starch on a dry weight basis. Herein, starch from mango (Manguifera Indica L.) kernel was applied to obtain a starch fatty ester with vinyl laurate, in DMSO, under basic catalysis. FTIR, 1H and 13C NMR confirmed that a starch ester with a degree of modification of 2.6 was produced. TGA showed that the modified starch has higher thermal stability than its precursors and higher than a vinyl laurate/starch physical blend. SEM data showed that… More >

D. Vassilev^1,*, N. Petkova², M. Koleva¹, P. Denev²

Journal of Renewable Materials, Vol.6, No.7, pp. 707-714, 2018, DOI:10.32604/JRM.2018.00015

Abstract The paper presents the findings of an experimental study on the microwave synthesis (MW) of inulin acetate and its possible application as bio-additive in poly(vinyl chloride) (PVC). The obtained inulin acetate has been identified and characterized by spectroscopic methods. Advantages of the MW compared with the conventional synthesis were defined. In order to evaluate possible application of the product as bio-based additive for polymers, effect of the inulin ester on PVC behavior and characteristics has been investigated by differential scanning calorimetry (DSC) and deformation upon extension. Experimental results show that in concentration range up to 30.0 wt. % the inulin… More >

Hassen Mohamed Sbihi^1,*, Hamid Shaikh², Lahssen El Blidi², Imed Arbi Nehdi¹, Ubair Abdus Samad², Moufida Romdhani-Younes³, Saud Ibrahim Al-Resayes¹

Journal of Renewable Materials, Vol.6, No.6, pp. 651-661, 2018, DOI:10.7569/JRM.2018.634105

Abstract In this study, different samples of alkyd resins based on Citrullus colocynthis seed oil (CCSO)—which has a high content of linoleic acid—were prepared as a renewable raw material. Short (I), medium (II), and long (III) alkyd resins were synthesized using oil, glycerol, and phthalic anhydride (PA) in different proportions. Prunus mahaleb seed oil (PMSO), which contains conjugated linolenic acid, was blended with CCSO in different proportions to examine the effect of PMSO on the film properties of alkyd resins (IV and V). All synthesized resins were characterized by FTIR and 1H NMR spectroscopic analysis. These resins were also cured by… More >

A.G. Gouater Issola¹, A. Ngueteu Kamlo², A.M. Cheumani Yona^1,*, M. Kor Ndikontar¹

Journal of Renewable Materials, Vol.6, No.6, pp. 642-650, 2018, DOI:10.7569/JRM.2018.634108

Abstract Chemical modification of cassava starch by transesterification of a vegetable oil (palm kernel oil) using aluminum chloride as a Lewis acid catalyst was achieved under relatively mild conditions (temperature 60–110 °C; atmospheric pressure). The reaction was carried out without any additional solvent. The modified starch was characterized by degree of substitution (DS), FTIR, X-ray diffraction and thermal analysis. DS of 0.09 to 0.53 were obtained. The cassava starch presented an X-ray diffraction pattern of a type A starch. X-ray analyses showed that the reaction did not significantly affect the crystallinity of starch. The modified starch films (MStF) adsorbed less water… More >