Mingyan He1,2, Jiayu Fu1,2, Fangyu Guo1,2, Dawei Jiang1,2,*, Ting Yang1,2, Miaojun Xu1,2,*, Zijian Wu3, Bin Li1,2,*
Journal of Polymer Materials, Vol.43, No.1, 2026, DOI:10.32604/jpm.2026.075379
- 03 April 2026
Abstract Phenolic resins are widely used in thermal protection, yet achieving simultaneous improvement in thermal stability and mechanical strength remains challenging. In this work, a vinyl-modified silicone resin (VMTQ) was synthesized and incorporated into a boron phenolic resin (BPF) matrix. Three composite ceramic fillers, Al2O3–SiO2–ZrO2 (ASZ), Al2O3–SiO2–TiO2 (AST), and Al2O3–SiO2–MgO (ASM), were further introduced to construct a multi-oxide synergistic reinforcement system. Thermogravimetric analysis shows that the maximum decomposition rate decreases by 0.2–0.3%·min−1, while the ASM/V3/BPF-3 composite exhibits a 74.53% increase in char yield at 800°C and a 163.3°C increase in initial decomposition temperature, confirming its significantly enhanced thermal More >