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  • Open Access

    ARTICLE

    Enzymatic Hydrolysis of Sugarcane Biomass and Heat Integration as Enhancers of Ethanol Production

    Reynaldo Palacios-Bereche1, Adriano Ensinas2, Marcelo Modesto1, Silvia Nebra1,3,*

    Journal of Renewable Materials, Vol.6, No.2, pp. 183-194, 2018, DOI:10.7569/JRM.2017.634175

    Abstract The aim of this study is to assess the possibility of increasing ethanol production by introducing the bagasse hydrolysis process into conventional distilleries. Simulations were performed for mass and energy balances using Aspen Plus® software. It was assumed that sugarcane trash and lignin cake—hydrolysis process residues—are available as supplementary fuel. Several cases were evaluated, including: (a) conventional ethanol distillery, (b) conventional plant combined with a hydrolysis process without heat integration, with different solid contents in the hydrolysis reactor, and (c) conventional plant combined with the hydrolysis process applying heat integration by pinch analysis. The highest ethanol yield was achieved in… More >

  • Open Access

    ARTICLE

    Alternatives of Small-Scale Biorefineries for the Integrated Production of Xylitol from Sugarcane Bagasse

    Nicolás M. Clauser1*, Soledad Gutiérrez2, María C. Area1, Fernando E. Felissia1, María E. Vallejos1

    Journal of Renewable Materials, Vol.6, No.2, pp. 139-151, 2018, DOI:10.7569/JRM.2017.634145

    Abstract Small-scale biorefinery from sugarcane bagasse offers new possibilities to the sugar and ethanol industries. The aim of this study was to evaluate the feasibility of a small-scale biorefinery for the production of xylitol from sugarcane bagasse. The liquid fraction from the autohydrolysis treatment was selected as the source of sugars for xylitol and two scenarios were analyzed for the residual solid: ethanol or pellet production. A technical-economic analysis of alternatives was applied. The internal rate of return (IRR) was used to compare the selected proposals. The highest IRR values were obtained when processing 70,000 dry tons per year of bagasse.… More >

  • Open Access

    ARTICLE

    Production of Polyhydroxybutyrate (PHB) by Bacillus megaterium DSM 32 from Residual Glycerol of the Bioenergy Industry

    Enzo Alvarado-Cordero1, Gabriela Montes de Oca-Vásquez2, Reinaldo Pereira-Reyes2, José Vega-Baudrit2, Marianelly Esquivel-Alfaro1*

    Journal of Renewable Materials, Vol.5, No.3-4, pp. 323-331, 2017, DOI:10.7569/JRM.2017.634123

    Abstract Biodegradable polymers from renewable resources are generating growing interest in the plastic industry because they have properties similar to synthetic polymers. Polyhydroxyalkanoates, mainly polyhydroxybutyrate (PHB), have mechanical and physicochemical properties very similar to their synthetic counterparts. This work explores the use of residual glycerol from the bioenergy industry for the production of PHB by Bacillus megaterium DSM 32. The glycerol works as a source of carbon and energy. Raw glycerol was purified with sulfuric acid in order to neutralize saponified fatty acids. The purification process generated three different phases. One of the phases was the glycerol-rich layer; this layer was… More >

  • Open Access

    ARTICLE

    Production of Starch Films Using Propolis Nanoparticles as Novel Bioplasticizer

    Karolina Villalobos1, Hider Rojas1, Rodolfo González-Paz2, Daniel Brenes Granados2, Jeimmy González-Masís2, José Vega Baudrit1,3, Yendry Regina Corrales-Ureña1*

    Journal of Renewable Materials, Vol.5, No.3-4, pp. 189-198, 2017, DOI:10.7569/JRM.2017.634109

    Abstract Because starch is a biodegradable polymer with low cost and wide availability it is an attractive material for producing edible films for fruits. Films produced with pure starch have the disadvantage of being fragile. To overcome this issue, propolis nanoparticles were used as a novel plasticizer. Mechanical, thermal and morphological properties of the films containing 0.5, 1 and 3 wt.% propolis nanoparticles were evaluated. The best performance was obtained using 0.5 wt.% propolis, increasing the Young’s modulus and decreasing the glass transition temperature (Tg), showing their plasticizing effect. The results of scanning electron microscopy (SEM) and atomic force microscopy (AFM)… More >

  • Open Access

    ARTICLE

    Polyols Based on Poly(ethylene terephthalate) and Tall Oil: Perspectives for Synthesis and Production of Rigid Polyurethane Foams

    A. Ivdre1*, G.D. Soto2, U. Cabulis1

    Journal of Renewable Materials, Vol.4, No.4, pp. 285-293, 2016, DOI:10.7569/JRM.2016.634122

    Abstract This study presents the synthesis of novel polyols made from tall oil (TO) and poly(ethylene terephthalate) (PET) with different TO/PET molar ratios. Rigid polyurethane foams based on these synthesized polyols were obtained and characterized to evaluate polyols’ suitability for the development of light materials with insulating properties. The effect of TO/PET molar ratios on the physical, morphological and mechanical properties of the obtained foams, as well as their thermal insulation characteristics, were evaluated. Increasing amounts of PET in polyurethane foams resulted in higher compression strength and closed cell content, while water absorption was not affected. Results indicated that certain TO/PET… More >

  • Open Access

    ARTICLE

    Valorization of Agricultural Wastes for the Production of Protein-Based Biopolymers

    Nuria Burgos, Arantzazu Valdés, Alfonso Jiménez*

    Journal of Renewable Materials, Vol.4, No.3, pp. 165-177, 2016, DOI:10.7569/JRM.2016.634108

    Abstract In this study we provide an overview of the latest developments on the extraction, production, modification and applications of fruit residues and by-products in the formation of protein-based biopolymers, in particular for the formulation of edible films. Our aim was mainly to demonstrate the highly transdisciplinary character of these topics by giving an overview of the main developments and research topics in the chemistry and engineering aspects of protein-based biopolymers. These innovative raw materials have been evaluated for the production of biomaterials to be used in some key sectors, such as food packaging. More >

  • Open Access

    REVIEW

    The Three Filament Model of Skeletal Muscle Stability and Force Production

    Walter Herzog, Tim Leonard, Venus Joumaa, Michael DuVall§, Appaji Panchangam

    Molecular & Cellular Biomechanics, Vol.9, No.3, pp. 175-192, 2012, DOI:10.3970/mcb.2012.009.175

    Abstract Ever since the 1950s, muscle force regulation has been associated with the cross-bridge interactions between the two contractile filaments, actin and myosin. This gave rise to what is referred to as the "two-filament sarcomere model". This model does not predict eccentric muscle contractions well, produces instability of myosin alignment and force production on the descending limb of the force-length relationship, and cannot account for the vastly decreased ATP requirements of actively stretched muscles. Over the past decade, we and others, identified that a third myofilament, titin, plays an important role in stabilizing the sarcomere and the myosin filament. Here, we… More >

  • Open Access

    ARTICLE

    Viscoelasticity of Living Materials: Mechanics and Chemistry of Muscle as an Active Macromolecular System

    Hong Qian*

    Molecular & Cellular Biomechanics, Vol.5, No.2, pp. 107-118, 2008, DOI:10.3970/mcb.2008.005.107

    Abstract At the molecular and cellular level, mechanics and chemistry are two aspects of the same macromolecular system. We present a bottom-up approach to such systems based on Kramers' diffusion theory of chemical reactions, the theory of polymer dynamics, and the recently developed models for molecular motors. Using muscle as an example, we develop a viscoelastic theory of muscle in terms of an simple equation for single motor protein movement. Both A.V. Hill's contractile component and A.F. Huxley's equation of sliding-filament motion are shown to be special cases of the general viscoelastic theory of the active material. Some disparity between the… More >

  • Open Access

    ARTICLE

    Application of Artificial Neural Networks in Design of Steel Production Path

    Igor Grešovnik1,2, Tadej Kodelja1, Robert Vertnik2,3, Bojan Senčič3,2,3, Božidar Šarler1,2,4

    CMC-Computers, Materials & Continua, Vol.30, No.1, pp. 19-38, 2012, DOI:10.3970/cmc.2012.030.019

    Abstract Artificial neural networks (ANNs) are employed as an alternative to physical modeling for calculation of the relations between the production path process parameters (melting of scrap steel and alloying, continuous casting, hydrogen removal, reheating, rolling, and cooling on a cooling bed) and the final product mechanical properties (elongation, tensile strength, yield stress, hardness after rolling, necking) of steel semi products. They provide a much faster technique of response evaluation complementary to physical modeling. The Štore Steel company process path for production of steel bars is used as an example for demonstrating the approach. The applied ANN is of a multilayer… More >

  • Open Access

    ARTICLE

    Lattice Boltzmann Simulation of a Gas-to-Solid Reaction and Precipitation Process in a Circular Tube

    Matthew D. Lindemer1, Suresh G. Advani2,*, Ajay K. Prasad2

    CMES-Computer Modeling in Engineering & Sciences, Vol.117, No.3, pp. 527-553, 2018, DOI:10.31614/cmes.2018.00481

    Abstract The lattice Boltzmann method (LBM) is used to simulate the growth of a solid-deposit on the walls of a circular tube resulting from a gas-to-solid reaction and precipitation process. This process is of particular interest for the design of reactors for the production of hydrogen by the heterogeneous hydrolysis of steam with Zn vapor in the Zn/ZnO thermochemical cycle. The solid deposit of ZnO product on the tube wall evolves in time according to the temporally- and axially-varying convective-diffusive transport and reaction of Zn vapor with steam on the solid surface. The LBM is well-suited to solving problems with coupled… More >

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