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  • Open Access

    ARTICLE

    Influence of Intermolecular Forces and Spatial Effects on the Mechanical Properties of Silicone Sealant by Molecular Dynamics Simulation

    Wen Qi1, Yu-Fei Du1, Bo-Han Chen2, Gui-Lei An1,3,*, Chun Lu4,*

    CMC-Computers, Materials & Continua, Vol.85, No.2, pp. 2763-2780, 2025, DOI:10.32604/cmc.2025.069505 - 23 September 2025

    Abstract In the production process of silicone sealant, mineral oil is used to replace methyl silicone oil plasticizer in silicone sealant to reduce costs and increase efficiency. However, the silicone sealant content in mineral oil is prone to premature aging, which significantly reduces the mechanical properties of the silicone sealant and severely affects its service life. At the same time, there are few reports on the simulation research of the performance of silicone sealant. In this study, three mixed system models of crosslinking silicone sealant/plasticizer are constructed by the molecular dynamics simulation method, and the effect… More >

  • Open Access

    ARTICLE

    Synergistic Effect of Silicone Macromolecular Charring Agent and Ammonium Polyphosphate on Improving Flame Retardancy and Mechanical Properties of Ethylene-Butyl Acrylate Copolymer Composites

    Xuan Huo1, Bingchen Wu1, Yuanmeng Lou1, Junlin Zhu1, Cui Li1, Lili Ma1, Ye-Tang Pan2, Chuncheng Hao1,*, Xin Wen1,*

    Journal of Polymer Materials, Vol.42, No.2, pp. 517-530, 2025, DOI:10.32604/jpm.2025.065320 - 14 July 2025

    Abstract Power cables are important pieces of equipment for energy transmission, but achieving a good balance between flame retardancy and mechanical properties of cable sheaths remains a challenge. In this work, a novel intumescent flame retardant (IFR) system containing silicone-containing macromolecular charring agent (Si-MCA) and ammonium polyphosphate (APP) was designed to synergistically improve the flame retardancy and mechanical properties of ethylene-butyl acrylate copolymer (EBA) composites. The optimal mass ratio of APP/Si-MCA was 3/1 in EBA composites (EBA/APP-Si-31), corresponding to the best flame retardancy with 31.2% of limited oxygen index (LOI), V-0 rating in UL-94 vertical burning More > Graphic Abstract

    Synergistic Effect of Silicone Macromolecular Charring Agent and Ammonium Polyphosphate on Improving Flame Retardancy and Mechanical Properties of Ethylene-Butyl Acrylate Copolymer Composites

  • Open Access

    ARTICLE

    Tailored Phosphate Glass Powders for Augmented Flame Retardancy and Ceramicization in Silicone Rubber

    Yanbei Hou1,2, Xu Chang1, Shuming Liu1, Huimin Zhang3, Jianwei Fu3, Jianbin Wu3, Zhiyong Li3, Guoqiang Tang3, Weizhao Hu1,*

    Journal of Polymer Materials, Vol.42, No.2, pp. 531-548, 2025, DOI:10.32604/jpm.2025.065040 - 14 July 2025

    Abstract Silicone rubber (SR) exhibits superior breathability and high-temperature resistance. However, SR is prone to degradation under extreme heat or combustion, limiting its effectiveness in mitigating secondary hazards. In this study, phosphate glass powder was used to calcinate zinc borate, lanthanum oxide, and cerium oxide. Methylphenyl polysiloxane was then grafted onto the surface of the glass powder, resulting in the modified powders designated as Methylphenyl polysiloxane-grafted zinc borate-modified phosphate glass powder (GF-ZnBM), Methylphenyl polysiloxane-grafted lanthanum oxide-modified phosphate glass powder (GF-LaM), and Methylphenyl polysiloxane-grafted cerium oxide-modified phosphate glass powder (GF-CeM). The modified powders were subsequently incorporated into… More > Graphic Abstract

    Tailored Phosphate Glass Powders for Augmented Flame Retardancy and Ceramicization in Silicone Rubber

  • Open Access

    ARTICLE

    Improvement of Surface Electrical Properties of Silicone Rubber Based on Fluorination

    Hanbo Zheng, Yue Peng, Enpeng Qin, Yi Li*

    Journal of Polymer Materials, Vol.42, No.2, pp. 549-568, 2025, DOI:10.32604/jpm.2025.064866 - 14 July 2025

    Abstract Fluorination is a critical surface modification technique for enhancing the electrical performance of composite insulators. This study employs molecular simulations to examine the microstructure and space charge behavior of fluorinated and non-fluorinated silicone rubber under an electric field, with experimental validation. The results show that fluorinated silicone rubber exhibits lower total energy, higher polarization, and stronger dipole moments compared to its non-fluorinated counterpart, shifting the material from an insulating to a conductive state. Under lower electric field strengths, the carbon-silicon bonds in fluorinated silicone rubber are longer, but it maintains geometric stability under higher fields.… More > Graphic Abstract

    Improvement of Surface Electrical Properties of Silicone Rubber Based on Fluorination

  • Open Access

    PROCEEDINGS

    Radio Frequency-Assisted Curing of On-Chip Printed Carbon Nanotube/silicone Heatsinks Produced by Material Extrusion 3D Printing

    Thang Q. Tran1,2, Anubhav Sarmah1, Ethan M. Harkin1, Smita Shivraj Dasari1, Kailash Arole1, Matthew Cupich1, Aniela J. K. Wright1, Hang Li Seet2, Sharon Mui Ling Nai2, Micah J. Green1,3,*

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.31, No.3, pp. 1-2, 2024, DOI:10.32604/icces.2024.012057

    Abstract With the rapid development of high-power integrated electronic devices, many polymer-based thermal management devices have been developed to address the problem of overheating and to improve the reliability and lifetime of electronic devices. Here we demonstrate the material extrusion 3D printing of carbon nanotube (CNT)/silicone heatsinks directly onto electronic devices. CNTs were used as a conductive nanofiller and a rheological modifier to improve thermal and electrical conductivities and the printability of the silicone inks, respectively. Additionally, CNTs are also a radio frequency (RF) susceptor, so the integration of CNTs into the silicone matrix allowed for… More >

  • Open Access

    PROCEEDINGS

    FabriCast: Casting Silicone Structures via Direct Ink Writing on Textiles

    J. M. Tan1, A. Chooi2, C. Chen1, A. Castillo Ugalde2, T. Stalin2, T. Calais2, P. Valdivia y Alvarado1,2,3,*

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.31, No.3, pp. 1-1, 2024, DOI:10.32604/icces.2024.011827

    Abstract In this study two novel forms of textile-assisted direct ink writing (DIW) of room temperature vulcanised (RTV) silicones were explored: Silicone DIW on spandex fabric, and Silicone DIW on dissolvable fabrics. These processes were evaluated by incorporating resulting components into 4 soft robotic devices: impact resistant elbow pads, a soft passive suction cup gripper, and two fiber embedded inflatable tendril-like soft grippers. More >

  • Open Access

    ARTICLE

    Molecular Dynamics Simulation of Interface Properties between Water-Based Inorganic Zinc Silicate Coating Modified by Organosilicone and Iron Substrate

    Hengjiao Gao1, Yuqing Xiong1,*, Kaifeng Zhang1, Shengzhu Cao1, Mingtai Hu1, Yi Li1, Ping Zhang2, Xiaoli Liu3

    Journal of Renewable Materials, Vol.11, No.4, pp. 1715-1729, 2023, DOI:10.32604/jrm.2022.024023 - 01 December 2022

    Abstract The interface properties of Fe(101)/zinc silicate modified by organo-siloxane (KH-570) was studied by using the method of molecular dynamics simulation. By calculating the temperature and energy fluctuation of equilibrium state, equilibrium concentration distribution, MSD of layer and different groups, and interaction energy of two interface models, the influencing mechanism on the interface properties of adding organosiloxane into coating system was studied at the atomic scale. It shows that the temperature and energy of interface oscillated in a small range and it was exited in a state of dynamic equilibrium within the initial simulation stage (t More > Graphic Abstract

    Molecular Dynamics Simulation of Interface Properties between Water-Based Inorganic Zinc Silicate Coating Modified by Organosilicone and Iron Substrate

  • Open Access

    ARTICLE

    Mechanical Properties, Biocompatibility and Anti-Bacterial Adhesion Property Evaluation of Silicone-Containing Resin Composite with Different Formulae

    Muzi Liao1,2,#, Hui Tong1,2,#, Xiangya Huang1,2, Fang Liu3, Jingwei He3,*, Sui Mai1,2,*

    Journal of Renewable Materials, Vol.10, No.12, pp. 3201-3215, 2022, DOI:10.32604/jrm.2022.022090 - 14 July 2022

    Abstract Novel branched silicone methacrylate was developed. The mechanical and biological properties of the resin system were investigated to select the formula proportion with the best overall performance. The novel silicone-containing monomers were combined with an incremental sequence of glass filler concentrations in commonly used Bis-GMA/TEGDMA (50/50, wt./wt.) dental resin systems. Physicochemical properties, surface properties, antibacterial adhesion effect, anti-biofilm effect, protein adsorption, and cytotoxicity were evaluated. The results showed that BSMs did not affect the double bond conversion of dental resin, but could reduce volumetric shrinkage (p < 0.05). The BSM containing resins can resist protein and… More >

  • Open Access

    ARTICLE

    Aging Characteristics and Influencing Factors of the Sheds of Composite Insulators in Karst Regions of China

    Wei Zhao1, Miao Jiang2, Jun Dong1, Lee Li2,*

    Energy Engineering, Vol.118, No.6, pp. 1755-1766, 2021, DOI:10.32604/EE.2021.015467 - 10 September 2021

    Abstract In recent years, more and more high-voltage overhead transmission lines were built passing through the karst regions in southwestern China. This type of special landform seems to have an adverse effect on the aging of the sheds of the line suspension composite insulators, which may lead to unexpected flashover and line tripping. In order to find out the particularity of the aging characteristics of insulators operating in the karst regions, samples in operation were selected from both the karst regions and the flatlands. Hydrophobicity, amount of surface contamination, and contaminant composition of the sheds were… More >

  • Open Access

    ARTICLE

    Nanotitanium Dioxide Reinforced High Performance PEI/Silicone Rubber Composites: Mechanical, Thermal and Morphological Characteristics

    R.M. MISHRAA, R. VIJAYVARGIYAA, K.N. PANDEYA, J.S.P. RAIB

    Journal of Polymer Materials, Vol.37, No.3-4, pp. 179-188, 2020, DOI:10.32381/JPM.2020.37.3-4.5

    Abstract The present investigation is targeted to prepare nanocomposites based on binary blends of polyetherimide (PEI)-silicone rubber incorporated with varied loadings of nanotitanium dioxide particles. Nanocomposites have been prepared by melt blending process using twin screw extruder. Thermal properties of the developed nanocomposites have been investigated with the help of thermogravimetric analyzer (TGA) and dynamic mechanical analyzer (DMA). Scanning electron microscopy (SEM) is used to analyze the morphological properties of the nanocomposites. Mechanical properties (tensile strength, tensile modulus, elongation at break, impact strength) of the nanocomposites have been evaluated by universal testing machine (UTM). Mechanical testing… More >

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