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  • Open Access

    ARTICLE

    Modularized and Parametric Modeling Technology for Finite Element Simulations of Underground Engineering under Complicated Geological Conditions

    Jiaqi Wu1, Li Zhuo1,*, Jianliang Pei1, Yao Li2, Hongqiang Xie1, Jiaming Wu1, Huaizhong Liu1

    CMES-Computer Modeling in Engineering & Sciences, Vol.140, No.1, pp. 621-645, 2024, DOI:10.32604/cmes.2024.046398

    Abstract The surrounding geological conditions and supporting structures of underground engineering are often updated during construction, and these updates require repeated numerical modeling. To improve the numerical modeling efficiency of underground engineering, a modularized and parametric modeling cloud server is developed by using Python codes. The basic framework of the cloud server is as follows: input the modeling parameters into the web platform, implement Rhino software and FLAC3D software to model and run simulations in the cloud server, and return the simulation results to the web platform. The modeling program can automatically generate instructions that can run the modeling process in… More >

  • Open Access

    ARTICLE

    Fabrication of Microspherical Catalyst with Hierarchical Porous Structure from Functional Monomers via Low-Temperature Phase-Separation Photopolymerization

    KEMIN WANG, LIFEI HE

    Journal of Polymer Materials, Vol.36, No.3, pp. 253-260, 2019, DOI:10.32381/JPM.2019.36.03.5

    Abstract This study proposes a simple approach for the fabrication of microspherical catalysts with a hierarchical porous structure. The cross-linked porous microspheres with catalytic ability were prepared directly from small-molecular monomers via low-temperature phase-separation photopolymerization of water/oil suspension. The morphology, pore size, chemical structure, and thermal stability of the obtained porous microspheres were characterized by SEM, Mercury Intrusion Porosimetry, FTIR, and TGA. The porous microspheres directly served as an acid catalyst for the condensation reaction of benzaldehyde and ethylene glycol, which exhibited superior catalytic activity and recyclability. The results indicated that such porous microspheres have great potential in the application of… More >

  • Open Access

    REVIEW

    Recent Advancement in Comb-like Polymers: A Review

    AMRITA SHARMA, P. P. PANDE

    Journal of Polymer Materials, Vol.36, No.2, pp. 175-194, 2019, DOI:10.32381/JPM.2019.36.02.6

    Abstract ‘Comb-like polymers’ are a special class of polymers. These are consisting of two types of chains, first one is the backbone chain and second is long side chains. The structure of such a polymer is very similar to hair comb. Usually, every monomer unit in the backbone has a long n-alkyl side chain. Comb like polymers have an intrinsic ability towards forming ordered structure. Now-a-days, these polymers find wide range of applications because of their excellent physicochemical properties. Some applications are in preparation of polysoaps (polymeric disinfectants), as dispersing agent for ink and paints, textile industry, in surface modification of… More >

  • Open Access

    ARTICLE

    Effect of Feed Composition in Gas-phase Polymerization on Structure and Properties of In Situ Impact Polypropylene Copolymer

    XIAOYAN LIUa,*, XU CHENa, HONGXING ZHANGb, CHANGJUN ZHANGa, SHIYUAN YANGa, GUANGQUAN LIa

    Journal of Polymer Materials, Vol.36, No.2, pp. 121-132, 2019, DOI:10.32381/JPM.2019.36.02.2

    Abstract In this work, three in situ impact polypropylene copolymer(IPC) samples were prepared through Ziegler-Natta catalyst only changing the feed composition (ethylene to ethylene and propylene molar ratio, C2/C2+C3) in gas-phase polymerization reactor. Polymer (IPC) were characterical by solvent classification, gel permeation chromatography (GPC), differential scanning calorimetry (DSC), successive self-nucleation and annealing (SSA), nuclear magnetic resonance(13C-NMR) and scanning electron microscopy(SEM). The mechanical properties of IPC samples were tested.The results indicate that with similar ethylene content, the feed composition which determines the content and structure of EPR and EbP component in IPC, further impacts the rubber phase size and distribution in IPC,… More >

  • Open Access

    ARTICLE

    Structural, Thermal, Optical, Mechanical and Morphological Properties of ABS/RGO with DBDPE Nanocomposites

    İBRAHIM KARTERIa,b,*, MUSTAFA ÖZYEŞILDAĞb

    Journal of Polymer Materials, Vol.38, No.1-2, pp. 167-177, 2021, DOI:10.32381/JPM.2021.38.1-2.13

    Abstract This study aims to provide a comprehensive account of chemically reduced graphene oxide (RGO) and decabromodiphenyl ethane (DBDPE) filled acrylonitrile-butadiene-styrene (ABS) multifunctional filaments for fused deposition modeling (FDM) applications. ABS/RGO with DBDPE nanocomposites (ABS-GDM) were fabricated by single-screw extrusion at a diameter of 1.75 mm. The proportion of RGO and DBDPE for the ABS-GDM filaments was set to 0.75 wt%. The properties of the ABS-GDM were determined using optical, mechanical, thermal, and morphological characteristics (using scanning electron microscopy). A three-dimensional (3D) model was successfully printed using the developed ABS-GDM filaments for FDM 3D printing. These ABS-GDM have the potential to… More >

  • Open Access

    ARTICLE

    Enhancing the Performance of Polylactic Acid (PLA) Reinforcing with Sawdust, Rice Husk, and Bagasse Particles

    A. MADHAN KUMAR1, K. JAYAKUMAR2,*, M. SHALINI3

    Journal of Polymer Materials, Vol.39, No.3-4, pp. 269-281, 2022, DOI:10.32381/JPM.2022.39.3-4.7

    Abstract Polylactic acid (PLA) is the most popular thermoplastic biopolymer providing a stiffness and strength alternative to fossil-based plastics. It is also the most promising biodegradable polymer on the market right now, thus gaining a substitute for conservative artificial polymers. Therefore, the current research focuses on synthesizing and mechanical characterization of particlereinforced PLA composites. The hot compression molding technique was used to fabricate PLA-based composites with 0, 2.5, 5, and 7.5 weight % of sawdust, rice husk, and bagasse particle reinforcements to enhance the performance of the PLA. The pellets of PLA matrix were taken with an average size of 3… More >

  • Open Access

    ARTICLE

    Study of the Effect of UV-exposure on HDPE/Carbon Black Composite Floating Structure

    ALOK K. SAHUa, RAJSHREE VIJAYVARGIYAa, R. M. SARVIYAb

    Journal of Polymer Materials, Vol.39, No.3-4, pp. 183-193, 2022, DOI:10.32381/JPM.2022.39.3-4.1

    Abstract HDPE material is found to be best suited material for the manufacturing of floating bed structure for the solar photovoltaic (PV) system due to its light weight and excellent mechanical & chemical resistant properties. However, the major restriction in this regard is the limited engineering design and also the effect of UV radiations present in the natural environment that leads to the degradation of the plastic materials. Hence, in order to improve its UV stability carbon black is incorporated into it as UV resistant additive and hollow cubical floats of such HDPE/carbon black composite material has been manufactured by rotational… More >

  • Open Access

    ARTICLE

    Study of the Neutron Radiation Effect on Bi-oriented Polyethylene Naphthalate Structure

    A. BELOUADAH1, S. BERDOUS1,3, D. BERDOUS2, M. IZERROUKEN4, N. SAIDI-AMROUN1

    Journal of Polymer Materials, Vol.39, No.1-2, pp. 1-15, 2022, DOI:10.32381/JPM.2022.39.1-2.1

    Abstract In this work, neutron induced structural modifications, on the biaxially-oriented polyethylene naphthalate (BOPEN) film, were studied by X-ray diffraction technique (XRD), Fourier transform infrared spectroscopy (FTIR/ATR), scanning electron microscopy (SEM) and polarized light optical microscopy (PLOM). The irradiation with neutron was carried out, under air, at room temperature. The changes of the structure, in volume and in surface were evaluated under the impact of neutron’s flux composed by thermally neutrons and fast neutrons. The X-ray technique showed the effect of the neutron flux’s fluence on the crystallinity of the BOPEN, which was also determined through the FTIR/ATR spectroscopy, traduced by… More >

  • Open Access

    ARTICLE

    Chiral Copolymers of (R)-N-(1-Phenyl-Ethyl) Methacrylamide (R-NPEMAM) and 2-Hydroxy Ethyl Methacrylate (HEMA): Investigation of PhysicoChemical Behavior, Thermal Properties and Degradation Kinetics

    DIBYENDU S. BAG*, SHILPI TIWARI, AKANSHA DIXIT, KM. MEENU

    Journal of Polymer Materials, Vol.40, No.1-2, pp. 105-123, 2023, DOI:10.32381/JPM.2023.40.1-2.9

    Abstract In this paper, we report the microstructural investigation and influence of H-bonding on the thermal behavior e.g., glass transition (Tg ) and thermal degradation of chiral copolymers of (R)- N-(1-phenyl-ethyl) methacrylamide (R-NPEMAM) and 2-hydroxy ethyl methacrylate (HEMA). The Tg increases with the increase of chiral unit content in the copolymers and then attains optimum at around 25 mole % of chiral content. Thereafter it decreases with the increase of chiral content. The effect of copolymer composition and secondary interaction associated with the Hbonding on the thermal properties of these copolymers was also studied. Secondary interaction, specifically H-bonding has been interpreted… More >

  • Open Access

    ARTICLE

    Influence of Bottom Inclination on the Flow Structure in a Rotating Convective Layer

    Andrei Vasiliev, Andrei Sukhanovskii*, Elena Popova

    FDMP-Fluid Dynamics & Materials Processing, Vol.20, No.4, pp. 739-748, 2024, DOI:10.32604/fdmp.2024.048092

    Abstract The formation of convective flows in a rotating cylindrical layer with an inclined bottom and free surface is studied. Convection is driven by localized cooling at the center of the upper free surface and by rim heating at the bottom near the sidewall. The horizontal temperature difference in a rotating layer leads to the formation of a convective flow with a complex structure. The mean meridional circulation, consisting of three cells, provides a strongly non-uniform differential rotation. As a result of the instability of the main cyclonic zonal flow, the train of baroclinic waves appears in the upper layer. The… More >

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