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  • Open Access

    ARTICLE

    New Rigid Furan Biofoams Based on Hydrolysable Chesnut (Castanea sativa) Tannin by Chemical Expansion

    João Vitor Dorini Falavinha1, Pedro Henrique Gonzales De Cademartori2, Philippe Gérardin1, Antonio Pizzi1, Christine Gérardin-Charbonnier1,*

    Journal of Renewable Materials, Vol.13, No.4, pp. 687-697, 2025, DOI:10.32604/jrm.2025.058902 - 21 April 2025

    Abstract Tannins are polyphenols widely present in the plant kingdom, commonly divided into two groups: condensed and hydrolysable tannins. Sustainable furanic bio-foams based on condensed tannins have been largely studied, but little is described about the use of hydrolysable tannins for this material. This study examined the potential of hydrolysable chestnut tannin in comparison to condensed mimosa tannins to produce furanic foams by chemical expansion. Due to the low reactivity of the hydrolysable tannin, the use of an external source for its polymerization and curing was necessary. Through Fourier transform infrared spectroscopy (FTIR) chromatography, it was More > Graphic Abstract

    New Rigid Furan Biofoams Based on Hydrolysable Chesnut (<i>Castanea sativa</i>) Tannin by Chemical Expansion

  • Open Access

    ARTICLE

    Physical and Mechanical Properties of Gmelina Wood (Gmelina arborea Roxb.) Modified with Furfuryl Alcohol-Tannin

    Mahdi Mubarok1,*, Pirda Maharani Nafisah1, Adi Santoso2, Saefudin2,*, Efrida Basri2, Yusuf Sudo Hadi1,3, Adik Bahanawan2, Rohmah Pari2, Imam Busyra Abdillah1, Jingjing Liao4, Dede Hermawan1, Trisna Priadi1, Philippe Gérardin5, Wayan Darmawan1

    Journal of Renewable Materials, Vol.13, No.4, pp. 731-752, 2025, DOI:10.32604/jrm.2024.057476 - 21 April 2025

    Abstract Furfurylation, a renowned chemical modification technique, uses furfuryl alcohol to enhance the properties of wood. This technology can be further refined by incorporating renewable tannins, which promote cross-linking with furfuryl alcohol. This study investigates the effects of furfurylation and tannin-modified furfurylation on the physical and mechanical properties of tropical Gmelina wood (Gmelina arborea Roxb.). Experiments involved impregnating Gmelina wood with aqueous solutions of furfuryl alcohol (FA) at 40% and 70% concentrations, as well as FA-tannin combinations (FA 40%-TA and FA 70%-TA), followed by polymerization at 103°C. The results demonstrated that both FA and FA-tannin treatments significantly… More > Graphic Abstract

    Physical and Mechanical Properties of Gmelina Wood (<i>Gmelina arborea</i> Roxb.) Modified with Furfuryl Alcohol-Tannin

  • Open Access

    REVIEW

    Recent Developments in Bioadhesives and Binders

    Hong Lei1, Xiaojian Zhou2, Antonio Pizzi3,*, Guanben Du2,*, Xuedong Xi2

    Journal of Renewable Materials, Vol.13, No.2, pp. 199-249, 2025, DOI:10.32604/jrm.2025.02024-0048 - 20 February 2025

    Abstract This review is composed of three main parts each of which is written by well-known top specialists that have been, in a way or other, also the main participants of the majority of the developments reported. Thus, after a general part covering the grand lines and more in-depth views of more recent tannin, lignin, carbohydrate and soy bioadhesives, some mix of the other bio raw materials with soy protein and soy flour and some other differently sourced bioadhesives for wood, this review presents a more in-depth part on starch-based wood adhesives and a more in-depth… More > Graphic Abstract

    Recent Developments in Bioadhesives and Binders

  • Open Access

    ARTICLE

    Why Sustainable Porous Carbon Should be Further Explored as Radar-Absorbing Material? A Comparative Study with Different Nanostructured Carbons

    Alan F.N. Boss1, Manuella G.C. Munhoz1, Gisele Amaral-Labat2, Rodrigo G.A. Lima2, Leonardo I. Medeiros2,3, Nila C.F.L. Medeiros2,3, Beatriz C.S. Fonseca2, Flavia L. Braghiroli4,*, Guilherme F.B. Lenz e Silva1

    Journal of Renewable Materials, Vol.12, No.10, pp. 1639-1659, 2024, DOI:10.32604/jrm.2024.056004 - 23 October 2024

    Abstract Radar Absorbing Materials (RAM) are a class of composites that can attenuate incident electromagnetic waves to avoid radar detection. Most carbon allotropes that have the potential to be used as RAM are either carbon nanotubes (CNTs), graphene, carbon black (CB) and ultimately, sustainable porous carbon (SPC). Here, black wattle bark waste (following tannin extraction) was used as a sustainable source to produce SPC made from biomass waste. It was characterized and used as a filler for a silicone rubber matrix to produce a flexible RAM. The electromagnetic performance of this composite was compared with composites… More > Graphic Abstract

    Why Sustainable Porous Carbon Should be Further Explored as Radar-Absorbing Material? A Comparative Study with Different Nanostructured Carbons

  • Open Access

    ARTICLE

    Chemically Modified Sugarcane Bagasse for Innovative Bio-Composites. Part One: Production and Physico-Mechanical Properties

    Peyman Ahmadi1,*, Davood Efhamisisi1,*, Marie-France Thévenon2,3, Hamid Zarea Hosseinabadi1, Reza Oladi1, Jean Gerard2,3

    Journal of Renewable Materials, Vol.12, No.10, pp. 1715-1728, 2024, DOI:10.32604/jrm.2024.054076 - 23 October 2024

    Abstract Sugarcane bagasse is an agro-waste that could replace timber resources for the production of bio-composites. Composite boards such as particleboard offer an issue for the use and recycling of poor quality timber, and these engineered products can overcome some solid wood limitations such as heterogeneity and dimension. Bagasse offers an alternative to wood chips for particleboard production but present some disadvantages as well, such as poor physico-mechanical properties. To address these issues, bagasse fibers were treated with an innovative natural resin formulated with tannin and furfural. Impregnated particles with different concentrations of resin (5%, 10%,… More > Graphic Abstract

    Chemically Modified Sugarcane Bagasse for Innovative Bio-Composites. Part One: Production and Physico-Mechanical Properties

  • Open Access

    ARTICLE

    Tannins from Acacia mangium Bark as Natural Dyes for Textiles: Characteristics and Applications

    Maya Ismayati1,*, Nissa Nurfajrin Solihat1, Fifi Melinda Setiawati2, Wasrin Syafii2, Yuki Tobimatsu3, Deni Zulfiana4

    Journal of Renewable Materials, Vol.12, No.9, pp. 1625-1637, 2024, DOI:10.32604/jrm.2024.054739 - 25 September 2024

    Abstract Tannins are capable of producing natural dyes with antioxidant and antibacterial propertis, while synthetic dyes are commonly used in the textile industry, causing environmental issues like water pollution. This research aims to utilize waste tannins as natural dyes as an alternative to synthetic dyes. This study examined the effect of the extraction method on tannin properties such as phenolic content, antioxidants, and antibacterial activity. In addition, Pyrolysis Gas Chromatography‒Mass Spectrometry (Py-GCMS) analysis was used to identify the effect of extraction temperature on the chemical elucidation of tannin. The effect of tannin concentration was evaluated against… More > Graphic Abstract

    Tannins from <i>Acacia mangium</i> Bark as Natural Dyes for Textiles: Characteristics and Applications

  • Open Access

    ARTICLE

    Numerical Simulation of the Mechanical Stirring Process in a Tannin-Based Foaming Precursor Resin

    Lan Huang1, Wenbin Yuan1, Hisham Essawy2, Xiaojian Zhou3,*, Xinyi Chen3,*

    FDMP-Fluid Dynamics & Materials Processing, Vol.20, No.10, pp. 2219-2234, 2024, DOI:10.32604/fdmp.2024.052445 - 23 September 2024

    Abstract Tannin foam is a new functional material. It can be widely applied to the automobile industry, construction industry, and packaging industry due to its wide range of raw materials, renewable, easily degraded, low cost and almost no pollution. Preparing tannin foam is a very complex process that includes high temperature, two phases, mechanical agitation, and phase change. To investigate the influence of the stirring velocity and paddle shape, simulation was calculated by making use of the volume of fluid (VOF) method and multiple reference frame (MRF) method in a three-dimensional flow field of tannin-based foaming… More > Graphic Abstract

    Numerical Simulation of the Mechanical Stirring Process in a Tannin-Based Foaming Precursor Resin

  • Open Access

    REVIEW

    Overview of the Synthesis, Characterization, and Application of Tannin-Glyoxal Adhesive for Wood-Based Composites

    Awanda Wira Anggini1,2, Rita Kartika Sari2, Efri Mardawati3,4, Tati Karliati5, Apri Heri Iswanto6, Muhammad Adly Rahandi Lubis1,4,*

    Journal of Renewable Materials, Vol.12, No.7, pp. 1165-1186, 2024, DOI:10.32604/jrm.2024.051854 - 21 August 2024

    Abstract More than a century after its initial synthesis, urea-formaldehyde (UF) resins still have dominant applications as adhesives, paints, and coatings. However, formaldehyde in this industry produces formaldehyde emissions that are dangerous to health. Scientists have spent the last decade replacing formaldehyde and phenol with environmentally friendly substances such as glyoxal and tannin to create bio-based adhesives. This review covers recent advances in synthesizing glyoxal tannin-based resins, especially those made from sustainable raw material substitutes and changes made to synthetic processes to improve mechanical properties. The efficacy of using tannin-glyoxal adhesives in producing wood-based composites has… More > Graphic Abstract

    Overview of the Synthesis, Characterization, and Application of Tannin-Glyoxal Adhesive for Wood-Based Composites

  • Open Access

    ARTICLE

    Structural Elucidation of the Polymeric Condensed Tannins of Acacia nilotica Subspecies by 13C NMR, MALDI-TOF and TMA as Sources of Bioadhesives

    Zeinab Osman1,2,3,*, Antonio Pizzi2,*, Bertrand Charrier3

    Journal of Renewable Materials, Vol.12, No.7, pp. 1291-1310, 2024, DOI:10.32604/jrm.2024.051619 - 21 August 2024

    Abstract Tannin was extracted from different subspecies of Acacia nilotica, Acacia nilotica nilotica (Ann), Acacia nilotica tomentosa (Ant) and Acacia nilotica adansonii (Ana). The aim was to elucidate their structure and evaluate their reactivity as bioadhesives in the wood industry. The extracts were prepared by hot water extraction (90°C temperature). Their gel time with paraformaldehyde was used at first to compare their reactivity. The tannin contents and the percentage of total polyphenolic materials in different solutions of the extracts spray dried powder were determined by the hide powder method. Concentrated solutions (47%) were tested by both MALDI ToF, CNMR.… More > Graphic Abstract

    Structural Elucidation of the Polymeric Condensed Tannins of <i>Acacia nilotica</i> Subspecies by <sup>13</sup>C NMR, MALDI-TOF and TMA as Sources of Bioadhesives

  • Open Access

    ARTICLE

    Matrix Assisted Laser Desorption Ionization Time of Flight (MALDI-TOF)-Mass Spectrometry and 13C-NMR-Identified New Compounds in Paraberlinia bifoliolata (Ekop-Beli) Bark Tannins

    Liliane Nga1, Benoit Ndiwe1,2, Achille Bernard Biwolé1, Antonio Pizzi3,*, Jean Jalin Eyinga Biwole1, Joseph Zobo Mfomo1

    Journal of Renewable Materials, Vol.12, No.3, pp. 553-568, 2024, DOI:10.32604/jrm.2023.046568 - 11 April 2024

    Abstract Extracts of plant origin, particularly tannins, are attracting growing interest for the sustainable development of materials in the industrial sector. The discovery of new tannins is therefore necessary. The aim of this work was to contribute to the understanding of the properties of Paraberlinia bifoliolata tannin by Matrix Assisted Laser Desorption Ionization Time of Flight Mass Spectroscopy MALDI-TOF/MS and Carbon 13 Nuclear Magnetic Resonance (13C NMR). The chemical composition of tannin extracted from Paraberlinia bifoliolata bark was determined, as was the mechanical strength of the resin hardened with Acacia nilotica extracts. Yield by successive water extraction was 35%. MALDI-TOF/MS… More >

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