Antonio Pizzi^1,*, Marie-Pierre Laborie^2,3, Zeki Candan⁴

Journal of Renewable Materials, Vol.12, No.3, pp. 397-425, 2024, DOI:10.32604/jrm.2023.046074 - 11 April 2024

Abstract Condensed and hydrolysable tannins are non-toxic natural polyphenols that are a commercial commodity industrialized for tanning hides to obtain leather and for a growing number of other industrial applications mainly to substitute petroleum-based products. They are a definite class of sustainable materials of the forestry industry. They have been in operation for hundreds of years to manufacture leather and now for a growing number of applications in a variety of other industries, such as wood adhesives, metal coating, pharmaceutical/medical applications and several others. This review presents the main sources, either already or potentially commercial of More > Graphic Abstract

Bengang Zhang^1,*, Antonio Pizzi^2,*, Mathieu Petrissans¹, Anelie Petrissans¹, Colin Baptiste¹

Journal of Renewable Materials, Vol.11, No.12, pp. 4097-4121, 2023, DOI:10.32604/jrm.2023.029761 - 10 November 2023

Abstract Aminated tannins were prepared by reacting mimosa condensed tannin extract with ammonia yielding the substitution of many, if not all of the tannin hydroxyl groups with –NH₂ groups. A tannin-aminated tannin (ATT) particleboard coating was then prepared by reacting raw tannin extract with aminated tannin extract and thus cross-liking the two by substituting tannin’s hydroxyl groups with the –NH₂ groups on the aminated tannin to form –NH-bridges between the two. The resulting particleboard coating gave encouraging results when pressed at 180°C for 3 min. Conversely, the system in which tannin was reacted/cross-liked with urea (ATU) by… More >

Elham Azadeh¹, Ummi Hani Abdullah^2,3, Christine Gerardin^1,*, Antonio Pizzi^1,*, Philippe Gerardin¹, Cesar Segovia⁴

Journal of Renewable Materials, Vol.11, No.10, pp. 3625-3645, 2023, DOI:10.32604/jrm.2023.030373 - 10 August 2023

Abstract Water repellant, flexible biofoams using tannin esterified with various fatty acid chains, namely lauric, palmitic and oleic acids, by reaction with lauryl chloride, palmitoyl chloride, and oleyl chloride were developed and their characteristics compared with the equivalently esterified rigid biofoams. Glycerol, while initially added to control the reaction temperature, was used as a plasticizer yielding flexible biofoams presenting the same water repellant character that the equivalent rigid foams. Acetaldehyde was used as the cross-linking agent instead of formaldehyde, as it showed a better performance with the esterified tannin. The compression results showed a significant decrease… More >

Antonio Pizzi^*

Journal of Renewable Materials, Vol.11, No.9, pp. 3403-3415, 2023, DOI:10.32604/jrm.2023.030930 - 20 July 2023

Abstract This brief article reviews a very particular and quite narrow field, namely what has been done and what is needed to know for tannin adhesives for wood panels to succeed industrially. The present fashionable focus on bioadhesives has led to producing chemical adhesive formulations and approaches for tannin adhesives as a subject of academic publications. These, as good and original they might be, are and will still remain a rather empty academic exercise if not put to the test of real industrial trials and industrial use. They will remain so without the “little” secrets and… More >

Wen Gu^#, Xinyue Ding^#, Min Tang^*, Feiyan Gong^*, Shuangshuang Yuan, Jintao Duan

Journal of Renewable Materials, Vol.11, No.8, pp. 3245-3259, 2023, DOI:10.32604/jrm.2023.027461 - 26 June 2023

Abstract Biomass adhesive is conducive to decreasing the dependence of the wood adhesive industry on synthetic resin based on fossil resources and improving the market competitiveness of adhesives. It is also a critical breakthrough to realize the goal of carbon peaking and carbon neutrality in the wood industry. In this study, a full biomass wood adhesive composed of tannin and sucrose was developed and applied successfully to the preparation of plywood. The preparation technique of plywood was optimized, and the chemical structure, curing performance, crystallization property and thermal performance of the adhesive were investigated. Results showed… More >

Jianping Deng¹, Qianqian Zhang¹, Yuling Lan¹, Lingcong Luo¹, Zimin Dai¹, Zhonghang Lin¹, Zhixin Lu¹, Jiancheng Yuan¹, Yiqi Fu¹, Lu Luo^2,*, Weigang Zhao^1,*

Journal of Renewable Materials, Vol.11, No.6, pp. 2631-2646, 2023, DOI:10.32604/jrm.2023.027163 - 27 April 2023

Abstract The development and utilization of biomass and agroforestry processing byproducts for high-value applications have been an important topic in the field of renewable materials research. Based on this, a two-step microwave hydrothermal pre-carbonization and KOH activation method was proposed to synthesize tannin-based activated carbons with a high specific surface area, hierarchical pore structure, and good electrochemical performance. The microstructure, texture properties, and physicochemical characteristics were investigated. The results show that the prepared tannin-based activated carbons presented a hierarchical pore structure (micro- and mesopores) with a specific surface area as high as 997.46 m³ g⁻¹ . The… More > Graphic Abstract

Elham Azadeh¹, Antonio Pizzi^1,2,*, Christine Gerardin-Charbonnier^1,*, Philippe Gerardin¹

Journal of Renewable Materials, Vol.11, No.6, pp. 2823-2848, 2023, DOI:10.32604/jrm.2023.027651 - 27 April 2023

Abstract Non-isocyanate polyurethane (NIPU) foams from a commercial hydrolysable tannin extract, chestnut wood tannin extract, have been prepared to determine what chemical species and products are taking part in the reactions involved. This method is based on two main steps: the reaction with dimethyl carbonate and the formation of urethane bonds by further reaction of the carbonated tannin with a diamine-like hexamethylene diamine. The hydroxyl groups on the tannin polyphenols and on the carbohydrates intimately linked with it and part of a hydrolysable tannin are the groups involved in these reactions. The carbohydrate skeleton of the… More > Graphic Abstract

Mahdi Mubarok^1,2, Christine Gérardin-Charbonnier^1,*, Elham Azadeh¹, Firmin Obounou Akong¹, Stéphane Dumarçay¹, Antonio Pizzi¹, Philippe Gérardin^1,*

Journal of Renewable Materials, Vol.11, No.2, pp. 505-521, 2023, DOI:10.32604/jrm.2022.024872 - 22 September 2022

Abstract Furfurylation is a well-known wood modification technology. This paper studied the effect of tannin addition on the wood furfurylation. Three kinds of dicarboxylic acids, adipic acid, succinic acid, and tartaric acid, as well as glyoxal as a comparing agent, were used to catalyse the polymerisation of furanic or tannin-furanic solutions during wood modification. Impregnation of furanic or tannin-furanic solution at a certain concentration into the wood followed with curing at 103°C for a specific duration was performed for the wood modification. Different properties of the modified woods like dimensional stability, resistance of treatment to leaching, More >

Antonio Pizzi^*

Journal of Renewable Materials, Vol.11, No.1, pp. 1-25, 2023, DOI:10.32604/jrm.2022.023314 - 10 August 2022

Abstract Soy flour (SF), soy protein and soy protein isolates (SPI) have been the focus of increasing research on their application as new materials for a variety of applications, mainly for wood adhesives and other resins. Tannins too have been the focus of increasing research for similar applications. While both materials are classed as non-toxic and have achieved interesting results the majority of the numerous and rather inventive approaches have still relied on some sort of hardeners or cross-linkers to bring either of them or even their combination to achieve acceptable results. The paper after a More >

Elham Azadeh¹, Xinyi Chen², Antonio Pizzi^2,*, Christine Gérardin¹, Philip Gérardin¹, Hisham Essawy³

Journal of Renewable Materials, Vol.10, No.12, pp. 3217-3227, 2022, DOI:10.32604/jrm.2022.022740 - 14 July 2022

Abstract Non-isocyanate polyurethane (NIPU) foams using a hydrolysable tannin, also vulgarly called tannic acid, namely here commercial chestnut wood tannin extract was prepared. Compression strength did not appear to depend on the foam apparent density while the formulation composition of the NIPU foams has been shown to be more determinant. These NIPU foams appeared to be self-extinguishing once the high temperature flame is removed. The ignition time gave encouraging results but for improved fire resistance the foams may need some fire-retardant addition. FTIR spectrometry showed the formation of non-isocyanate urethane linkages. Thermogravimetric analysis indicated a good More >