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  • Open Access

    ARTICLE

    Structural and device fabrication of 2D-MoS2 thin film

    R. Singha,*, S. Kimothib, M. V. Singhc, U. Ranid, A. S. Vermad,e,*

    Chalcogenide Letters, Vol.20, No.8, pp. 573-578, 2023, DOI:10.15251/CL.2023.208.573

    Abstract In this research paper, we have prepared thin film of MoS2 by thermal evaporation technique and characterized it. This thin film depositions lead to amorphous thin film. To make it crystalline, thermal annealing of the film have deposited on the substrates at 800 ℃ for two hour under vacuum environment. X-ray diffraction data of thin film shows the poly-crystalline nature. The Atomic Force Microscopy (AFM) image of the thin film shows the crystallinity with regularly arranged grains. Furthermore, an unconventional MoS2 based FET device has been fabricated by depositing thin film of MoS2 on p-type silicon. Thereafter, More >

  • Open Access

    ARTICLE

    Photoluminescence properties of Ba0.7Sr0.3TiO3:Sm3+ modified K0.5Na0.5NbO3 perovskite oxide ceramics

    K. W. Suna, Z. Liub,*, R. X. Wangb, X. C. Linga, J. W. Suna

    Chalcogenide Letters, Vol.20, No.8, pp. 563-571, 2023, DOI:10.15251/CL.2023.208.563

    Abstract Ba0.7Sr0.3TiO3:Sm3+ modified KxNa(1-x)NbO3 ceramics with perovskite-type structure were synthesized via solid state sintering method. Sm3+ ions doping was designed for substituting both A and B sites in the ABO3 structure, Sm3+ doped Ba0.7Sr0.3TiO3 (Ba0.7Sr0.3TiO3:Sm3+ ) oxide precursor powders with the chemical formula of Ba0.7Sr0.3xSmx(Ti1-xSmx)O3 (x=0.005, 0.015, 0.025) were synthesized. Combined Ba0.7Sr0.3TiO3:Sm3+ with K0.5Na0.5NbO3, the perovskite-type solid solution composite ceramics were fabricated via solid phase sintering method. X-Ray diffraction was used for investigating the phase structure of the precursor powders and luminescent composite ceramics. The photoluminescence properties of the Sm3+ ions in the Ba0.7Sr0.3TiO3-K0.5Na0.5NbO3 composite ceramic materials were systematically investigated by exploring More >

  • Open Access

    ARTICLE

    Systematic investigation of magneto-electronic, structural, thermoelectric and optical properties of Nd2MgX4 (X = S, Se) compounds

    M. Fidaa, Nasarullaha, S. A. Aldaghfagb, M. Yaseena,*, M. Ishfaqa

    Chalcogenide Letters, Vol.20, No.8, pp. 559-562, 2023, DOI:10.15251/CL.2023.208.559

    Abstract The structural, magnetic, optoelectronic, and thermoelectric (TE) characteristics of Nd2MgX4 (X = S, Se) are determined by utilizing the density functional theory (DFT) based full potential linearized augmented plane wave (FP-LAPW) method as employed in WEIN2k code. The exchange and correlation energies along with Coulomb interactions are brought into consideration by employing local density of approximation with Hubbard model (LDA+U). Tolerance (τ) factor and formation enthalpy were utilized to confirm the stability of both spinels. τ values are 0.70 and 0.68, and formation enthalpy values are (ΔHf) are -3.34 eV and -2.19 eV for Nd2MgX4 (X =… More >

  • Open Access

    ARTICLE

    Annealing effect on the photocurrent response of SnS thin films prepared by the chemical spray pyrolysis method

    D. Dekhila,*, H. Guessasa, A. Nouria, S. Ullahb

    Chalcogenide Letters, Vol.20, No.8, pp. 549-558, 2023, DOI:10.15251/CL.2023.208.549

    Abstract SnS thin films were synthesized using the spray pyrolysis method and then annealed at 350, 400, and 450°C. According to the crystallographic analysis, the obtained SnS thin films crystallized in the polycrystalline orthorhombic system. The grains measured 47, 66, and 37 nm for the samples annealed at 350, 400, and 450°C, respectively. SEM and AFM images indicate that the samples’ surfaces were completely covered. Thus, the grains of SnS nanostructures have a granular-like shape and vary in size depending on the annealing temperatures. The transmittance measurement shows that annealing the sample at 400 °C extends… More >

  • Open Access

    ARTICLE

    Calculation of the localized and extended energy states density for Ge60Se40-xTex alloy prepared by melting point method

    J. H. Azzawia, B. A. Ahmedb, K. A. Jasimb, E. M. T. Salmanb,*

    Chalcogenide Letters, Vol.20, No.9, pp. 649-656, 2023, DOI:10.15251/CL.2023.209.649

    Abstract The DC electrical conductivity properties of Ge60Se40-xTex alloy with x = 0, 5, 10, 15 and 20). The samples were formed in the form of discs with the thickness of 0.25–0.30 cm and the diameter of 1.5 cm. Samples were pressed under a pressure of 6 tons per cm2 , using a ton hydraulic press. They were prepared after being pressed using a ton hydraulic press using a hydraulic press. Melting point technology use to preper the samples. Continuous electrical conductivity properties were recorded from room temperature to 475 K. Experimental data indicates that glass containing… More >

  • Open Access

    ARTICLE

    Rational design of MoS2 nanosheet/ MoS2 nanowire homostructures and their enhanced hydrogen evolution reaction

    L. Yang*, X. Q. Yuan, R. Y. Liu, R. X. Song, Q. W. Wang, W. Liang

    Chalcogenide Letters, Vol.20, No.9, pp. 639-648, 2023, DOI:10.15251/CL.2023.209.639

    Abstract In this paper, we report a facile method for the synthesis of MoS2 nanosheet/ MoS2 nanowire homostructures by growing MoS2 nanosheets on the surface of MoS2 nanowires. Benefiting from the uniform coating of MoS2 nanosheets on the surface of MoS2 nanowires, the MoS2 nanosheet/ MoS2 nanowire homostructures highly expose their electrocatalytic active edge sites and exhibit an enhanced electrocatalytic performance. It demonstrates a low overpotential of 107 mV at 10 mA/cm2 and a small Tafel slope of 64 mV/dec in 0.5 M H2SO4. This work provides an inspiration for the design of efficient electrocatalysts with no stacking and aggregation More >

  • Open Access

    ARTICLE

    The effects of thickness and doping concentration on the solar efficiency of GaN/p-Si based solar cells

    N. S. Khairuddina, M. Z. Mohd Yusoffa,*, H. Hussinb

    Chalcogenide Letters, Vol.20, No.9, pp. 629-637, 2023, DOI:10.15251/CL.2023.209.629

    Abstract In this study, we used the PC1D simulator to demonstrate the performance analysis of a solar cell model based on gallium nitride (GaN). It has been discovered that when the layer thickness of the GaN substrate grows, the efficiency of solar cells decreases. This was found by comparing the doping concentration and layer thickness on the GaN and silicon substrates. As the thickness of the p-doping Si layer rises, cell efficiency increases just modestly. The optimal doping concentrations for GaN and p-silicon are 1x1018 cm-3 and 1x1017 cm-3 , respectively. In compared to other designs, GaN/p-silicon solar More >

  • Open Access

    ARTICLE

    Nucleation and growth study of SnS nanostructures prepared by electrodeposition method

    A. Nouri*, D. Dekhil, H. Guessas

    Chalcogenide Letters, Vol.20, No.10, pp. 753-758, 2023, DOI:10.15251/CL.2023.2010.753

    Abstract SnS nanostructures were prepared using the electrodeposition technique in aqueous solutions containing 0.1M of SnSO4 and Na2SO4. Three concentrations (0.05M, 0.10M, and 0.15M) of Na2SO4 were tested. The electrodeposition of SnS nanostructures on ITO substrates was investigated by cyclic voltammetry, chronoamperometry, SEM microscopy, and X-ray diffraction techniques. The concentration-dependent nucleation and growth mechanisms of electrodeposited SnS were analyzed using current transients. For the concentrations (0.05M and 0.10 M), the SnS films follow 3D growth in instantaneous nucleation mode. For a concentration of 0.15M, the SnS films start with progressive nucleation before switching to the instantaneous More >

  • Open Access

    ARTICLE

    Influence of deposition voltage on tribological properties of W-WS2 coatings deposited by electrospark deposition

    T. X. Liua, C. A. Guoa,*, F. S. Lub, X. Y. Zhanga,c, L. Zhangb, Z. J. Wanga, Z. Y. Xua, G. L. Zhua

    Chalcogenide Letters, Vol.20, No.10, pp. 741-749, 2023, DOI:10.15251/CL.2023.2010.741

    Abstract Electrospark deposition coatings were prepared with different deposition voltage on CrNi3MoVA steel substrates by using a W-WS2 sintered electrode and their tribological properties were investigated. The microhardness, roughness and tribological properties of the coatings were tested by using Vickers hardness tester, confocal laser scanning microscope and tribometer, and the morphologies, composition and phase structure were obtained by utilizing scanning electron microscopy (SEM), energy dispersive X-ray spectrum (EDS) and X-ray diffraction(XRD). The results showed that with the increase of deposition voltage, the hardness and roughness of the coatings increase. The coatings remarkably increase the tribological properties of More >

  • Open Access

    ARTICLE

    Enhancement efficiency of cadmium selenium solar cell by doping within silver

    M. H. Mustafa, H. M. Ali*, G. S. Ahmed, B. H. Hussein

    Chalcogenide Letters, Vol.20, No.10, pp. 733-740, 2023, DOI:10.15251/CL.2023.2010.733

    Abstract We studied at the morphology, structural setup, and optical characteristics of thin cadmium (CdSe) films a thickness of 250 nm that were created by thermal evaporation over glass, The films exhibited a hexagonal shape were crystalline, and tended to form grains in the (111) crystallographic direction, according to the X-ray diffraction examinations. These characteristics were established using the investigation's findings. Through the use of thin films of CdSe doped with Ag at a concentration of 1.5%, the crystal structure orientations for pure CdSe (25.32, 41.84) and CdSe:Ag (25.39, 41.01) that were both pure as well More >

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