High Efficient Synthesis of Hydroxyl-Terminated Polybutadiene (HTPB) based Polyurethane via Microwave Heating
YONG WENa,b, NA TENGa, FEI LIUa, RUOYU ZHANGa, HAIFANG WANGb, JING CHENa,1, JIN ZHUa, HAINING NAa,*
Journal of Polymer Materials, Vol.35, No.3, pp. 355-369, 2018, DOI:10.32381/JPM.2018.35.03.9
Abstract In this work, we establish a facile and efficient method to synthesize the polyurethanes (PUs)
containing hydroxyl-terminated polybutadiene (HTPB) through microwave-assisted reactions.
Comparisons of conventional heat versus microwave reactions have been made. Microwaveassisted synthesis has been found to significantly decrease the reaction time and reduce side
reaction of carbon-carbon bond relative to conventional heat. Moreover, we develop a more
advanced molecular design for HTPB based PU ranging from content of hard segment to types
of non-planer ring structures. The Characterization of the polymers has been conducted with
FT-IR, TGA, thermal and mechanical analysis. Among them, More >