Reynaldo Palacios-Bereche¹, Adriano Ensinas², Marcelo Modesto¹, Silvia Nebra^1,3,*

Journal of Renewable Materials, Vol.6, No.2, pp. 183-194, 2018, DOI:10.7569/JRM.2017.634175

Abstract The aim of this study is to assess the possibility of increasing ethanol production by introducing the bagasse hydrolysis process into conventional distilleries. Simulations were performed for mass and energy balances using Aspen Plus® software. It was assumed that sugarcane trash and lignin cake—hydrolysis process residues—are available as supplementary fuel. Several cases were evaluated, including: (a) conventional ethanol distillery, (b) conventional plant combined with a hydrolysis process without heat integration, with different solid contents in the hydrolysis reactor, and (c) conventional plant combined with the hydrolysis process applying heat integration by pinch analysis. The highest ethanol yield was achieved in… More >

Bruno Henrique dos Santos, Karen de Souza do Prado, Asaph Armando Jacinto, Márcia Aparecida da Silva Spinacé*

Journal of Renewable Materials, Vol.6, No.2, pp. 176-182, 2018, DOI:10.7569/JRM.2018.634101

Abstract Although thermoplastic starch (TPS) is biodegradable, its low mechanical resistance limits its wide application. Sugarcane bagasse (SB) fibers can be used as reinforcement in TPS matrix composites, but the influence of fiber size on the properties of the composite is still unknown. In this study, TPS composites reinforced with SB short fibers of four sizes were processed and characterized in order to analyze the influence of fiber size on the mechanical properties of the TPS/SB composite. It was observed that the interaction between fiber and matrix was good and optimized when the fibers are sifted in sieves between 30 and… More >

Kênia F. R. Lamounier¹, Patrisia O. Rodrigues¹, Daniel Pasquini^2*, Milla A. Baffi¹

Journal of Renewable Materials, Vol.6, No.2, pp. 169-175, 2018, DOI:10.7569/JRM.2017.634151

Abstract This study investigates the efficiency of a crude enzymatic extract produced by Aspergillus fumigatus SCBM6 by solid state fermentation (SSF) in the hydrolysis of alkali pretreated sugarcane bagasse (PTB). After SSF using in natura sugarcane bagasse (SCB), the enzymatic extract presented 21.33 U.g–1 of β-glucosidase and 544.46 U.g–1of xylanase. The alkaline pretreatment with sodium hydroxide (2% NaOH (w/v) removed 43% of the lignin from PTB and the cellulosic fraction increased to 75%. The hydrolysis was optimized as a function of time, temperature, and concentration of PTB. After hydrolysis, the maximum yield (30.05%) of total released reducing sugars (TRS) was obtained… More >

Lísias Pereira Novo^1,2*, Julien Bras^3,4, Mohamed Naceur Belgacem^3,4, Antonio Aprigio da Silva Curvelo²

Journal of Renewable Materials, Vol.6, No.2, pp. 160-168, 2018, DOI:10.7569/JRM.2017.634165

Abstract Two distinct lignocellulosic fractions (rind and core) can be obtained through a physical separation of sugarcane stalks. Although presenting differences in morphology, both fractions can be employed to produce pulps and papers. The pulps and paper sheets produced from the core and rind fractions were characterized by their chemical composition, physical properties and mechanical properties. The pulps obtained from the core presented a higher amount of fines, lower drainage ability and rendered denser and stiffer sheets. The pulps from the rind, which have a higher content of fibers and higher degree of polymerization, produced sheets with higher air permeability and… More >

Marcelo M. Oliveira^1,2, Antônio A. S. Curvelo^2,3, Carlos Driemeier^1*

Journal of Renewable Materials, Vol.6, No.2, pp. 152-159, 2018, DOI:10.7569/JRM.2017.6341576

Abstract Lignocellulose conversion into cellulosic ethanol and coproducts starts with a pretreatment step. Most current industrial plants of cellulosic ethanol use thermochemical pretreatments under hydrothermal conditions, with or without addition of acid catalyst. Such pretreatments modify biomass chemistry and morphology, particularly at the nanoscale. In this work, we use X-ray diffraction, dynamic vapor sorption and calorimetric thermoporometry to investigate the biomass nanostructural changes promoted by hydrothermal conditions. We compare and differentiate the rind and pith fractions of sugarcane stalks in order to contribute to the understanding of rind-pith contrasting recalcitrance. Moreover, for both cane fractions our results point consistently to cellulose… More >

Nicolás M. Clauser^1*, Soledad Gutiérrez², María C. Area¹, Fernando E. Felissia¹, María E. Vallejos¹

Journal of Renewable Materials, Vol.6, No.2, pp. 139-151, 2018, DOI:10.7569/JRM.2017.634145

Abstract Small-scale biorefinery from sugarcane bagasse offers new possibilities to the sugar and ethanol industries. The aim of this study was to evaluate the feasibility of a small-scale biorefinery for the production of xylitol from sugarcane bagasse. The liquid fraction from the autohydrolysis treatment was selected as the source of sugars for xylitol and two scenarios were analyzed for the residual solid: ethanol or pellet production. A technical-economic analysis of alternatives was applied. The internal rate of return (IRR) was used to compare the selected proposals. The highest IRR values were obtained when processing 70,000 dry tons per year of bagasse.… More >

Enzo Alvarado-Cordero¹, Gabriela Montes de Oca-Vásquez², Reinaldo Pereira-Reyes², José Vega-Baudrit², Marianelly Esquivel-Alfaro^1*

Journal of Renewable Materials, Vol.5, No.3-4, pp. 323-331, 2017, DOI:10.7569/JRM.2017.634123

Abstract Biodegradable polymers from renewable resources are generating growing interest in the plastic industry because they have properties similar to synthetic polymers. Polyhydroxyalkanoates, mainly polyhydroxybutyrate (PHB), have mechanical and physicochemical properties very similar to their synthetic counterparts. This work explores the use of residual glycerol from the bioenergy industry for the production of PHB by Bacillus megaterium DSM 32. The glycerol works as a source of carbon and energy. Raw glycerol was purified with sulfuric acid in order to neutralize saponified fatty acids. The purification process generated three different phases. One of the phases was the glycerol-rich layer; this layer was… More >

Joaquín E. González-Hernández¹, Jorge M. Cubero-Sesin^1,2*, Elena Ulate-Kolitsky¹, Priscilla Navarro¹, Stephen Petretti¹, Zenji Horita^3,4

Journal of Renewable Materials, Vol.5, No.3-4, pp. 300-306, 2017, DOI:10.7569/JRM.2017.634120

Abstract In this work, a modification of the microstructure of a commercial Ti-6Al-7Nb alloy was accomplished by high-pressure torsion (HPT) at room temperature, to produce a bulk nanostructure on discs of 10 mm diameter and ~0.8 mm thickness. The metallographic analyses of the discs were performed by optical microscopy and scanning electron microscopy with energy dispersive spectroscopy. The results confirmed the presence of aluminum (Al) and niobium (Nb) as the sole alloying elements, promoting a duplex (α + β) titanium (Ti) microstructure prior to HPT processing. After HPT processing, nanostructure refinement was attained, reflected in the X-ray diffraction profiles as broadening… More >

Hilary Ureña-Saborío^1*, Sergio Madrigal-Carballo¹, Jorge Sandoval², José R. Vega-Baudrit³, Alejandro Rodríguez-Morales²

Journal of Renewable Materials, Vol.5, No.3-4, pp. 290-299, 2017, DOI:10.7569/JRM.2017.634119

Abstract Currently there is a trend towards reducing the use of agrochemicals in developing countries. However, they are still being applied intensively in tropical countries. Thus, there is a trend towards developing new products based on natural chemicals for pest control, leading to second-generation pesticides incorporating nano- and biotechnologies. Costa Rica is one of the largest producers of bananas in the world. One of the most important pests of banana and plantain crops is the burrowing nematode, Radopholus similis (Cobb) Thorne. Highly toxic chemical compounds have traditionally been used to control this specific pest in banana plants, which can have dangerous… More >

A. Ramírez-Jiménez^1*, S. Hernández López¹, E. Bucio², E. Vigueras Santiago¹

Journal of Renewable Materials, Vol.5, No.2, pp. 132-144, 2017, DOI:10.7569/JRM.2016.634138

Abstract Epoxidized linseed oil (ELO) was synthesized and functionalized with propargylamine (PA) or 3-ethynylaniline (EA) and the products were crosslinked to obtain the diacetylene-functionalized epoxidized linseed oil polymers which were used as matrices in the preparation of the composites with multiwalled carbon nanotubes (MWCNTs). Electrical resistance at percentages between 4 and 20 wt/wt% of filler was measured and the percolation threshold was calculated, obtaining 1.2 and 1.7% for the composites with EA and PA respectively. Low critical concentration evidenced a good dispersion of the MWCNTs without necessity of any modification. The final products were used in the sensing of acetone, chloroform… More >