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  • Open Access

    ARTICLE

    Preparation of Optically Active Polyimides Based on 2,2´-diamino-1,1´-binaphthalene

    PETR SYSEL1, ROMAN HOLAKOVSKÝ2, ŠTĚPÁN HOVORKA3, JAROSLAV Ž ÁDNÝ4, PAVEL IZÁK4

    Journal of Polymer Materials, Vol.39, No.3-4, pp. 325-335, 2022, DOI:10.32381/JPM.2022.39.3-4.10

    Abstract Linear polyimides based on both of the 2,2´-diamino-1,1´-binaphthalene enantiomers and their racemic mixture were synthesized and characterized. A two-step synthetic route, consisting of the preparation of the polyimide precursor followed by its thermal imidization at temperatures not exceeding 200°C, was employed. The products were analyzed by FTIR and 1 H NMR spectroscopy. All of the tested materials were nearly fully imidized after 25 h. The final polyimides possess high glass transition temperatures, are thermo-oxidatively stable and are soluble in common organic solvents as 1-methyl-2-pyrrolidone, tetrahydrofuran and chloroform; additionally, those prepared from the enantiomers show optical activity. The values of specific… More >

  • Open Access

    ARTICLE

    The Identification of Phenylalanine Ammonia-Lyase (PAL) Genes from Pinus yunnanensis and an Analysis of Enzyme Activity in vitro

    Dejin Mu1,2, Lin Chen1,2, Heze Wang1,2, Zhaoliu Hu1,2, Sihui Chen1,2, Shi Chen1,2, Nianhui Cai1,2, Yulan Xu1,2, Junrong Tang1,2,*

    Phyton-International Journal of Experimental Botany, Vol.93, No.3, pp. 503-516, 2024, DOI:10.32604/phyton.2024.048786

    Abstract Phenylalanine ammonia lyase (PAL) is the rate-limiting and pivotal enzyme of the general phenylpropanoid pathway, but few reports have been found on PAL genes in Pinus yunnanensis. In the present study, three PAL genes were cloned and identified from P. yunnanensis seedlings for the first time, namely, PyPAL-1, PyPAL-2, and PyPAL-3. Our results indicated that the open-reading frames of PyPAL genes were 2184, 2157, and 2385 bp. Phylogenetic tree analysis revealed that PyPALs have high homology with other known PAL genes in other plants. In vitro enzymatic analysis showed that all three PyPAL recombinant proteins could catalyze the deamination of… More >

  • Open Access

    ARTICLE

    Toughening of Unsaturated Polyester Resin by Blending with Polyether Telechelics. Dependency of Toughening Efficacy on End Groups

    JEEMOL. P. A1, SURESH MATHEW1, REGHUNADHAN NAIR C.P.2,*

    Journal of Polymer Materials, Vol.39, No.1-2, pp. 111-120, 2022, DOI:10.32381/JPM.2022.39.1-2.7

    Abstract Polyether telechelics based on ethylene glycol,1,2-propylene glycol and 1,4- butylene glycol of with various molar masses and bearing at both terminals functional groups such as maleimide, itaconimide, nadimide and hydroxyl groups were individually examined as toughening agents for an unsaturated polyester resin (UPER). For a given telechelic, the toughening effect was evaluated at different mass ratios. The difference in toughening efficacy arose from the differential reactivity of the telechelics end groups combined with the unsaturation of the UPER with the reactive diluent, styrene. This causes a differential distribution of the polyether groups in the UPER matrices, resulting in a differential… More >

  • Open Access

    ARTICLE

    Gamma Radiation Induced Mutual Grafting of Quaternary Ammonium-Based Monomer on to Rayon Fibers to Improve its Water Absorbency and Antibacterial Efficacy

    SUBRATA PAL1,2, BHUVNESHWAR RAI1, AJAY KUMAR TYAGI1, SUNITA RATTAN2, VIRENDRA KUMAR3

    Journal of Polymer Materials, Vol.39, No.1-2, pp. 55-70, 2022, DOI:10.32381/JPM.2022.39.1-2.4

    Abstract The present work is focused on the study of antimicrobial and water absorption properties of the surface of grafted rayon fiber with quaternary ammonium-based salts containing 3- Acrylamidopropyl trimethyl ammonium chloride (APTAC) monomer induced by gamma radiation. Grafting was qualitatively confirmed by FTIR-ATR,TGA, SEM and by calculating grafting yield and grafting efficiency. The performance was examined for water absorbency and antibacterial efficacy (R) against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). Study showed that water absorption, grafting yield and grafting efficiency increased steadily with the increase in monomer concentration and absorbed gamma irradiation dose up to a certain… More >

  • Open Access

    ARTICLE

    Bioactivity of Nanohybrid: Comprising of Metallosalen Incorporated into Lacunary Polyoxometalate and Encapsulated with Chitosan Biopolymer

    SHIVA ARUNa, VINAY KUMAR SINGHa,#, PRABHA BHARTIYAb, PRADIP KUMAR DUTTAc,*

    Journal of Polymer Materials, Vol.40, No.1-2, pp. 19-31, 2023, DOI:10.32381/JPM.2023.40.1-2.2

    Abstract Biocompatible polymer chitosan has note-worthy applications in biomedical science. Nanohybrids synthesized by using chitosan as an encapsulating unit for polyoxometalates (POMs) and study of its biomedical applications is a fast-emerging field. In this research work, a lacunary polyoxometalate (α-K8SiW11O39) has been synthesized and then alkylsilane has been inserted into its lacunary position. It has been then reacted with 2-hydroxy-1-naphtaldehyde followed by copper metalation and finally encapsulated into chitosan by using the ionotropic gelation technique, in which the chitosan and the POM served as cation and anion, respectively. The bands in UV-Vis spectra at characteristic wavelength indicate that the organosilane is… More >

  • Open Access

    ARTICLE

    Shifting the Paradigm: A Fresh Look at Physical Activity Frequency and Its Impact on Mental Health, Life Satisfaction, and Self-Rated Health in Adolescents

    Wenjie Li1, Yucheng Gao2, Guoqing Liu2, Rongkai Hao2, Meijie Zhang2, Xiaotian Li1,*

    International Journal of Mental Health Promotion, Vol.26, No.2, pp. 83-92, 2024, DOI:10.32604/ijmhp.2023.042014

    Abstract As adolescent mental health problems are becoming a more serious issue globally, this paper explores the relationship of physical activity in adolescents and its frequency on mental health as well as examines the mediating effects of life satisfaction and self-rated health in order to provide a reference for the promotion of mental health in adolescents. A sample of 3578 Chinese high school students completed questionnaires assessing their mental health, physical activity frequency, life satisfaction, and self-rated health. The mean SCL-90 value for adolescents was found to be 1.629%, and 24.73% of adolescents had varying degrees of mental health issue. Increased… More >

  • Open Access

    ARTICLE

    Driving Activity Classification Using Deep Residual Networks Based on Smart Glasses Sensors

    Narit Hnoohom1, Sakorn Mekruksavanich2, Anuchit Jitpattanakul3,4,*

    Intelligent Automation & Soft Computing, Vol.38, No.2, pp. 139-151, 2023, DOI:10.32604/iasc.2023.033940

    Abstract Accidents are still an issue in an intelligent transportation system, despite developments in self-driving technology (ITS). Drivers who engage in risky behavior account for more than half of all road accidents. As a result, reckless driving behaviour can cause congestion and delays. Computer vision and multimodal sensors have been used to study driving behaviour categorization to lessen this problem. Previous research has also collected and analyzed a wide range of data, including electroencephalography (EEG), electrooculography (EOG), and photographs of the driver’s face. On the other hand, driving a car is a complicated action that requires a wide range of body… More >

  • Open Access

    ARTICLE

    Design of a Lightweight Compressed Video Stream-Based Patient Activity Monitoring System

    Sangeeta Yadav1, Preeti Gulia1,*, Nasib Singh Gill1,*, Piyush Kumar Shukla2, Arfat Ahmad Khan3, Sultan Alharby4, Ahmed Alhussen4, Mohd Anul Haq5

    CMC-Computers, Materials & Continua, Vol.78, No.1, pp. 1253-1274, 2024, DOI:10.32604/cmc.2023.042869

    Abstract Inpatient falls from beds in hospitals are a common problem. Such falls may result in severe injuries. This problem can be addressed by continuous monitoring of patients using cameras. Recent advancements in deep learning-based video analytics have made this task of fall detection more effective and efficient. Along with fall detection, monitoring of different activities of the patients is also of significant concern to assess the improvement in their health. High computation-intensive models are required to monitor every action of the patient precisely. This requirement limits the applicability of such networks. Hence, to keep the model lightweight, the already designed… More >

  • Open Access

    ARTICLE

    Smart Healthcare Activity Recognition Using Statistical Regression and Intelligent Learning

    K. Akilandeswari1, Nithya Rekha Sivakumar2,*, Hend Khalid Alkahtani3, Shakila Basheer3, Sara Abdelwahab Ghorashi2

    CMC-Computers, Materials & Continua, Vol.78, No.1, pp. 1189-1205, 2024, DOI:10.32604/cmc.2023.034815

    Abstract In this present time, Human Activity Recognition (HAR) has been of considerable aid in the case of health monitoring and recovery. The exploitation of machine learning with an intelligent agent in the area of health informatics gathered using HAR augments the decision-making quality and significance. Although many research works conducted on Smart Healthcare Monitoring, there remain a certain number of pitfalls such as time, overhead, and falsification involved during analysis. Therefore, this paper proposes a Statistical Partial Regression and Support Vector Intelligent Agent Learning (SPR-SVIAL) for Smart Healthcare Monitoring. At first, the Statistical Partial Regression Feature Extraction model is used… More >

  • Open Access

    ARTICLE

    Ellagic Acid Enhances Antioxidant System Activity and Maintains the Quality of Strawberry Fruit during Storage

    Jian Chen1, Jing Zhang2, Gang Pan3, Dandan Huang1,*, Shuhua Zhu1

    Phyton-International Journal of Experimental Botany, Vol.93, No.1, pp. 15-28, 2024, DOI:10.32604/phyton.2023.045621

    Abstract Ellagic acid (EA) is a natural antioxidant, widely present in a lot of forms’ soft fruits, nuts, and other plant tissues, and helpful for promoting human health; however, its protective effect on postharvest fruit and improving the quality index of postharvest fruit have rarely been studied. In this experiment, the strawberries were soaked in 0, 100, 200, 300, 400, and 500 mg L−1 EA, respectively, and the influential EA on fruit quality and the antioxidant system of strawberries were studied. Compared with the control, EA treatment can reduce the browning degree and rotting rate of strawberry fruit during storage and… More >

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