Baolin Wang¹

The International Conference on Computational & Experimental Engineering and Sciences, Vol.8, No.2, pp. 81-84, 2008, DOI:10.3970/icces.2008.008.081

Abstract When the size of a physical system is smaller than its characteristic dimensions, the macroscopic viewpoint may not be applicable. In addition, experiments at micro/nanometer scale are difficult and the analysis of nano-experimental data is far from simple. This is mostly due to the lack of effective models that are able to study the structural characteristics and mechanics behavior of the micro/nanometer physical systems. Atomic simulation simulation has been used extensively in the investigation of nanoscale phenomena. However, the size limit of atomic simulation is far short to reach the macroscale because of the limitation in computer capacity. Therefore, the… More >

T. Aizawa¹, H. Akebono², H.Suzuki¹

The International Conference on Computational & Experimental Engineering and Sciences, Vol.5, No.4, pp. 193-198, 2008, DOI:10.3970/icces.2008.005.193

Abstract In order to achieve power transmission parts like a compact gearwheel which indicates high performance properties, hybrid surface modification was performed by combining Super Rapid Induction Heating & Quenching(SRIQ) which creates high fatigue strength and Diamond Like Carbon (DLC) coating which are well known for their high hardness, low friction and excellent wear resistance. And, in order to prevent the base material from decreasing its fatigue strength, DLC was coated by using Unbalanced Magnetron Sputtering (UBMS) method which can coat at low temperature. Rotational bending fatigue tests and friction-wear tests were carried out. It was clear that it is possible… More >

Ingrid Souza Vieira da Silva¹, Natália Soares Prado¹, Patrícia Gontijo de Melo², Danilo Campion Arantes³, Mara Zeni Andrade⁴, Harumi Otaguro¹, Daniel Pasquini^1,*

Journal of Renewable Materials, Vol.7, No.1, pp. 73-87, 2019, DOI:10.32604/jrm.2019.00042

Abstract In this work, nine different types of edible coating based on pectin, cellulose nanocrystals, glycerol, and essential oil of lemongrass were prepared and used to coat strawberries with a film formed directly on the surface of the coated fruit. The effects of the different edible coatings on refrigerated fruits in terms of weight loss, titratable acidity, total soluble solids, pH, and anthocyanin content was evaluated after 2 days, 4 days, 6 days, and 8 days of storage. Application of the edible coatings reduced the weight loss of the coated strawberries and the anthocyanin content. The total soluble solids content of… More >

Azam Sardari^1,2, Ali Asghar Sabbagh Alvani^1,2,3,*, Seyed Reza Ghaffarian^1,2

Journal of Renewable Materials, Vol.7, No.1, pp. 31-40, 2019, DOI:10.32604/jrm.2019.00045

Abstract In this study, three sorts of polyols were successfully synthesized from castor oil using a Dean-Stark quick, eco-friendly and high-efficiency method. For this purpose, castor oil was epoxidized in the presence of two types of catalysts including γ-alumina and formic acid, named as ECOAl and ECOF, respectively. Epoxidized castor oils were then characterized by use of hydrogen nuclear magnetic resonance (H-NMR) and oxirane oxygen content analysis. The relative percentages of conversion double bond to oxirane were obtained 96% and 74% for ECOAl and ECOF, respectively. Ring opening reaction of ECOAl was performed by two types of saponified castor oil as… More >

A. Abolins*, V. Yakushin and D. Vilsone

Journal of Renewable Materials, Vol.6, No.7, pp. 737-745, 2018, DOI:10.32604/JRM.2018.00119

Abstract Linseed oil was epoxidized using hydrogen peroxide (H2O2), acetic acid (AcOH) and ion exchange resin Amberlite IR-120 as a catalyst. Epoxidized oil was separately dissolved in isopropyl alcohol (IPA) or diethylene glycol butyl ether (DGBE) and phosphorylated with different amounts of phosphoric (H3PO4) acid (1%, 2%, 3% and 5%). The formation of phosphate polyesters was confirmed by Fourier-transform infrared (FTIR) and 31P nuclear magnetic resonance (NMR) spectra. Based on the synthesized polyols, polyurethane (PU) coatings were prepared. PU coating based on linseed oil diethylene glycol ester polyol was used as the reference. For the characterization of coatings, mechanical tests and… More >

W. Li¹ and T. Siegmund¹

CMES-Computer Modeling in Engineering & Sciences, Vol.5, No.1, pp. 81-90, 2004, DOI:10.3970/cmes.2004.005.081

Abstract Results of a computational study of the mechanics of indentation induced interface delamination are described for a system consisting of a ductile film on an elastic substrate. Special attention is paid to the properties of the interface between film and substrate, and the influence of the interface properties on the indentation response. Specifically, strong interfaces are considered. The interface is characterized by the use of a cohesive zone model. The finite element method is used to solve the boundary value problem, with the interface behavior incorporated via a cohesive model in a traction-separation formulation. The model does not include any… More >

Kunal Wazarkar, Anagha Sabnis*

Journal of Renewable Materials, Vol.6, No.5, pp. 517-528, 2018, DOI:10.7569/JRM.2017.634181

Abstract This research work discloses the preparation of polyurethane coatings from cardanol modified using thiolene chemistry, wherein unsaturated long alkyl chain of cardanol was successfully utilized via thiol-ene click reaction to synthesize polyol. For this purpose, cardanol and thioglycerol was reacted in the presence of Irgacure 184 (photoinitiator) and 1,8-Diazabicyclo[5.4.0]undec-7-ene (catalyst) and exposed to UV light for 12 h at 80 °C. One mole of thioglycerol was successfully added across the double bond of fatty chain of cardanol and confirmed by chemical and spectroscopic analysis. Further, the polyol thus prepared was cured with various polyisocyanates, viz., N-75 (HDI based), L-67/BA (TDI… More >

Kunal Wazarkar, Anagha Sabnis*

Journal of Renewable Materials, Vol.6, No.4, pp. 438-449, 2018, DOI:10.7569/JRM.2017.634159

Abstract The research work presented in this article deals with the synthesis of cardanol-based polyol and its curing with hexabutoxymethyl melamine (HBMM) for application in coatings. Cardanol-based polyol was prepared via thiol-ene click reaction using thioglycerol. Unsaturation present in the long chain of cardanol was successfully utilized to synthesize polyol via thiol-ene coupling. The reaction was carried out between cardanol and thioglycerol in the presence of Irgacure 184 (photoinitiator) and 1,8-Diazabicyclo[5.4.0]undec-7-ene (catalyst) under UV light for 12 h at 80 °C. After completion of the reaction, one mole of thioglycerol was successfully added across the double bond of a fatty chain… More >

Ragab E. Abou-Zeid^1*, Mohamed A. Diab¹, Salah A. A. Mohamed², Ahmed Salama¹, Hind Abdullah Aljohani³, Kamel Rizq Shoueir⁴

Journal of Renewable Materials, Vol.6, No.4, pp. 394-401, 2018, DOI:10.7569/JRM.2017.634156

Abstract The current article addresses a new strategy for the preparation of polylactic acid/cellulose nanocrystal (PLA/CNCs) nanobiocomposite films with improved structural morphology, mechanical and barrier properties for food packaging applications. The addition of hexadecyltrimethylammonium bromide (CTAB) and sodium lauryl sulfate (SLS) as cationic and anionic surfactants respectively, was found to play a crucial role in preventing re-aggregation of the CNCs during drying and improving the dispersion of CNCs in the PLA. The coated paper was characterized using mechanical tests, water vapor permeability (WVP), X-ray diffraction (XRD), scanning electron microscopy (SEM) and air permeability. The results showed that the paper coated with… More >

Mingzhe Jiang¹, S. Nicole DeMass¹, D. Ross Economy², Thomas Shackleton¹, Christopher L. Kitchens^1*

Journal of Renewable Materials, Vol.4, No.5, pp. 377-387, 2016, DOI:10.7569/JRM.2016.634131

Abstract Spin coating was used to cast a uniform film of cellulose nanocrystals with low surface roughness and variable thickness as a function of operational parameters that include rotational speed and dispense suspension concentration. The film thickness was controllable from 40 nm up to 1 μm with surface roughness an order of magnitude less than blade-coating methods. The degree of radial orientation was qualitatively assessed and shown to be variable with processing parameters. Under specific processing conditions, the formation of striation patterns was observed and associated with film drying instability. The striation patterns are periodic in nature where the wavelength and… More >