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  • Open Access

    ARTICLE

    Chemically Modified Lignin: Correlation between Structure and Biodegradability

    Meifeng Wang1,2, Wubliker Dessie2, Hui Li1,*

    Journal of Renewable Materials, Vol.9, No.12, pp. 2119-2128, 2021, DOI:10.32604/jrm.2021.016811

    Abstract Lignin is the most abundant heteropolymer based on aromatic subunits in nature. Large quantities of lignin are annually produced from pulping processes and biorefinery industries. Its unclearly defined structure and difficult biodegradation mainly limit its utilization. This work focused on the effect of hydroxylation of lignin on its microbial degradation. Butyloxy carbonyl-modified lignin, and hydroxylated-lignin were synthesized with di-tert-butyl dicarbonate and hydrogen peroxide, respectively, using lignin as raw material. The degradation of the modifiedlignins both by P. chrysosporium and B. subtilis were analyzed using UV-vis spectroscopy. Results revealed that the lignin degradation velocity raises with the increase hydroxylation level of… More > Graphic Abstract

    Chemically Modified Lignin: Correlation between Structure and Biodegradability

  • Open Access

    ARTICLE

    Alcoholysis of Waste Polyurethane Rigid Foam and Its Modification with Lignin for Recovery

    Xiaohua Gu1,*, Shiwei Lyu1, Siwen Liu2

    Journal of Renewable Materials, Vol.9, No.11, pp. 1913-1926, 2021, DOI:10.32604/jrm.2021.015400

    Abstract A bi-component alcoholysis agent containing propylene glycol (PG) and ethanolamine (ETA) was used to catalyst the degradation of the waste polyurethane rigid foam. The oligomer polyols obtained through degradation were used as raw materials to produce recycled polyurethane rigid foam composites with lignin as reinforcing filler. The effect of alcoholysis mass ratio on degradation was investigated by analyzing the viscosity, hydroxyl content and chemical structure of the degradation products. The effect of lignin addition on the properties of regenerated polyurethane rigid foam were investigated by analyzing water absorption rate, compressive strength, porosity, thermal stability, thermal conductivity coefficient, morphology and thermal… More >

  • Open Access

    ARTICLE

    Photodegradation and Removal of Diclofenac by the Green Alga Nannochloropsis oculata

    Danaé Samara Sánchez-Sandoval#, Omar González-Ortega#, Mara Fernanda Navarro-Martínez, Juan Marcos Castro-Tapia, Ramón Fernando García de la Cruz, Ruth Elena Soria-Guerra*

    Phyton-International Journal of Experimental Botany, Vol.90, No.5, pp. 1519-1533, 2021, DOI:10.32604/phyton.2021.015087

    Abstract The emerging contaminants (ECs) are organic compounds including pharmaceuticals. These products are consumed in large quantities, favoring their continuous entrance to the environment and affecting the health of living beings. Diclofenac is a non-steroidal anti-inflammatory drug with analgesic properties of prolonged release. It is the commonest postoperative analgesic, and it is highly consumed without prescription. In recent years, the capability of microalgae to remove pharmaceuticals in water has been tested as a promising tool. In this work, the removal efficiency of diclofenac (16 µg/mL) by the microalga Nannochloropsis oculata CCAP 186/7 was evaluated. The major nutrient concentrations in Bold’s Basal… More >

  • Open Access

    ARTICLE

    Biodegradable Behavior of Waste Wool and Their Recycled Polyester Preforms in Aqueous and Soil Conditions

    Sudhakar Muniyasamy1,2,*, Asis Patnaik3,*

    Journal of Renewable Materials, Vol.9, No.10, pp. 1661-1671, 2021, DOI:10.32604/jrm.2021.014904

    Abstract Present study deals with the biodegradable behavior of individual components and their preforms of nonwoven biocomposites developed from waste wool fibers including coring wool (CW), dorper wool (DW) and recycled polyester fibers (RPET). A respirometric technique was employed to estimate the production of CO2 during the biodegradation experiments under soil and aqueous media conditions. Functional groups of test samples before and after biodegradation were analyzed using Fourier transform infrared spectroscopy (FTIR). Leaching chemicals such as formaldehyde (hydrolyzed) and Chromium VI (Cr VI) was also measured. The CO2 emission in wool fibers CW and DW indicated 90% and 60% biodegradation in… More >

  • Open Access

    REVIEW

    Biodegradable Materials as Nanocarriers for Drugs and Nutrients

    Xingran Kou1,2, Qixuan Zhao2, Wenwen Xu2, Zuobing Xiao2, Yunwei Niu2, Kai Wang3,*

    Journal of Renewable Materials, Vol.9, No.7, pp. 1189-1211, 2021, DOI:10.32604/jrm.2021.015268

    Abstract Several important drugs and nutritional supplements are limited by their lack of bioavailability. Nanomaterials display unique beneficial properties that might help improve the bioavailability of drugs and nutritional supplements. Unfortunately, nanomaterials produced from synthetic polymers and metals may have similar difficulties with bioavailability and toxicity. Naturally occurring biopolymers are biodegradable and non-toxic and are adaptable to the synthesis of nanoparticles. Drugs and other substances can be encapsulated or embedded in such particles with an increase in bioavailability. The search for biodegradable nanomaterials is an active research field. This review summarizes the research on nanocrystalline cellulose, starch, lignin, and other biological… More >

  • Open Access

    ARTICLE

    Chaperone-mediated autophagy targeting chimeras (CMATAC) for the degradation of ERα in breast cancer

    JUN ZHANG, YEHONG HUANG, WENZHUO LIU, LULU LI, LIMING CHEN*

    BIOCELL, Vol.44, No.4, pp. 591-595, 2020, DOI:10.32604/biocell.2020.011642

    Abstract Estrogen receptor alpha (ERα/ESR1) is overexpressed in over half of all breast cancers and is considered a valuable therapeutic target in ERα positive breast cancer. Here, we designed a membrane-permeant Chaperonemediated Autophagy Targeting Chimeras (CMATAC) peptide to knockdown endogenous ERα protein through chaperone-mediated autophagy. The peptide contains a cell membrane-penetrating peptide (TAT) that allows the peptide to by-pass the plasma membrane, an αI peptide as a protein-binding peptide (PBD) that binds specifically to ERα, and CMA-targeting peptide (CTM) that targeting chaperone-mediated autophagy. We validated that ERα targeting peptide was able to target and degrade ERα to reduce the viability of… More >

  • Open Access

    ARTICLE

    The Effects of Stacking Sequence on Dynamic Mechanical Properties and Thermal Degradation of Kenaf/Jute Hybrid Composites

    Tabrej Khan1, Mohamed Thariq Hameed Sultan1,2,3,*, Mohammad Jawaid2, Syafiqah Nur Azrie Safri2, Ain Umaira Md Shah2, Mohd Shukry Abdul Majid4,5,*, Nik Noriman Zulkepli6, Haliza Jaya6

    Journal of Renewable Materials, Vol.9, No.1, pp. 73-84, 2021, DOI:10.32604/jrm.2021.011385

    Abstract This research focused on the dynamic mechanical and thermal properties of woven mat jute/kenaf/jute (J/K/J) and kenaf/jute/kenaf (K/J/K) hybrid composites. Dynamic mechanical analysis (DMA) and Thermo-gravimetric Analysis (TGA) were used to study the effect of layering sequence on the thermal properties of kenaf/jute hybrid composites. The DMA results; it was found that the differences in the stacking sequence between the kenaf/jute composites do not affect their storage modulus, loss modulus and damping factor. From the TGA and DMA results, it has been shown that stacking sequence has given positive effect to the kenaf/jute hybrid composite compared to pure epoxy composite.… More >

  • Open Access

    ARTICLE

    Degradation of Spent Radioactive Ion Exchange Resins and Its Mechanisms by Fenton Process

    Wendong Feng1,2, Jian Li2, Hongxiang An2, Yunhai Wang1,*

    Journal of Renewable Materials, Vol.8, No.10, pp. 1283-1293, 2020, DOI:10.32604/jrm.2020.011000

    Abstract Spent IERs are released during the operation and decommissioning of nuclear facilities. The safe and efficient treatment of spent IERs is an emergent problem in nuclear industry. IRN77 is a typical ion exchange resin widely used in many nuclear power plants. Fenton process can degrade organic resins and reduce the radioactive residues volume and the disposal cost significantly. In this work, the IRN77 resin was selected as a model ion exchange resin and its treatment via Fenton process was investigated. The influencing factors for resin degradation, including catalyst dosage, reaction time, initial pH, temperature and oxidant dosage were investigated and… More >

  • Open Access

    ARTICLE

    Novel Mycelium-Based Biocomposites (MBB) as Building Materials

    Zinta Zimele1,*, Ilze Irbe2, Juris Grinins2, Oskars Bikovens2, Anrijs Verovkins2, Diana Bajare1

    Journal of Renewable Materials, Vol.8, No.9, pp. 1067-1076, 2020, DOI:10.32604/jrm.2020.09646

    Abstract Novel mycelium-based biocomposites (MBB) were obtained from local agricultural (hemp shives) and forestry (wood chips) by-products which were bounded together with natural growth of fungal mycelium. As a result, hemp mycocomposites (HMC) and wood mycocomposites (WMC) were manufactured. Mechanical, water absorption and biodegradation properties of MBB were investigated. MBB were characterized also by ash content and elemental composition. The results of MBB were compared with the reference materials such as the commercial MBB material manufactured by Ecovative® Design (EV), hemp magnesium oxychloride concrete (HC) and cemented wood wool panel (CW), manufactured by CEWOOD®. The mechanical properties of HMC and WMC… More >

  • Open Access

    ARTICLE

    Dissolution and Degradation of Spent Radioactive Cation Exchange Resin by Fenton Oxidation Combining Microwave

    Jiangbo Li1,2, Lielin Wang1,2,*, Hua Xie1,2, Xiaoyu Li1,2, Zhiqiang Feng1,2, Wenxiu Zhang1,2

    Energy Engineering, Vol.117, No.3, pp. 129-142, 2020, DOI:10.32604/EE.2020.010336

    Abstract This study introduced a significantly effective approach called the microwave-enhanced Fenton method to degrade spent radioactive cation exchange resin. Compared with the Fenton (99% after 180 min) and photo-Fenton (90% after 198 min) reactions, this unique microwave-enhanced Fenton reaction has the highest degradation rate for spent radioactive cation exchange resin degradation (98.55% after 60 min). Carbon dioxide, sulfate and small molecular compounds were produced in the degradation of cation exchange resin, as determined by XRD and FT-IR. A model for the microwave-enhanced Fenton degradation mechanism of cation exchange resin was constructed. Microwaves were implemented to boost the concentration of hydroxyl… More >

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