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  • Open Access

    ARTICLE

    Curing Kinetics of Tannin and Lignin Biobased Adhesives Determined by DSC and ABES

    Jaša Saražin1, Ida Poljanšek1, Antonio Pizzi2, Milan Šernek1,*

    Journal of Renewable Materials, Vol.10, No.8, pp. 2117-2131, 2022, DOI:10.32604/jrm.2022.019602

    Abstract The curing process of two biobased adhesives: pine tanninhexamine (TH) and organosolv lignin non-isocyanate polyurethane (NIPU), suitable for interior nonstructural use, were compared with commercial urea-formaldehyde (UF) adhesive. Changes in chemical structure before and after the curing process were observed with Fouriertransform infrared spectroscopy (FTIR). The process of adhesive curing was monitored with differential scanning calorimetry (DSC) and the automated bonding evaluation system (ABES). Both DSC and ABES measurements confirmed UF as the fastest and NIPU as the slowest curing adhesive observed. Taking into account the ABES results, the optimal pressing parameters for the TH adhesive would be 4 min… More >

  • Open Access

    VIEWPOINT

    Therapeutic mechanisms and routes of delivery of mesenchymal stem cells in veterinary medicine: A point of view

    AMANDA BARACHO TRINDADE HILL1,2,*, JONATHAN EDWIN BARACHO TRINDADE HILL2

    BIOCELL, Vol.46, No.5, pp. 1173-1176, 2022, DOI:10.32604/biocell.2022.018637

    Abstract Mesenchymal stem cells (MSCs) represent an important tool in veterinary regenerative medicine due to their ability to home to injury sites and secrete molecules that regulate niches into regenerative microenvironments. Successful cell therapy depends on many factors, including choice of administration route and application of understanding of cell potency and their therapeutic mechanisms. In this point of view, the authors leverage the tumultuous history of the field to demonstrate the need for clinicians to continually update themselves as new discoveries are made in order to avoid misalignments in the future, especially regarding administration routes and dose frequency, as well as… More >

  • Open Access

    ARTICLE

    Clinical Data-Driven Finite Element Analysis of the Kinetics of Chewing Cycles in Order to Optimize Occlusal Reconstructions

    Simon Martinez1, Jürgen Lenz1, Hans Schindler1,2, Willi Wendler1, Stefan Rues3, Karl Schweizerhof1,*, Sophia Terebesi2, Nikolaos Nikitas Giannakopoulos2, Marc Schmitter2

    CMES-Computer Modeling in Engineering & Sciences, Vol.129, No.3, pp. 1259-1281, 2021, DOI:10.32604/cmes.2021.017422

    Abstract The occlusal design plays a decisive role in the fabrication of dental restorations. Dentists and dental technicians depend on mechanical simulations of mandibular movement that are as accurate as possible, in particular, to produce interference-free yet chewing-efficient dental restorations. For this, kinetic data must be available, i.e., movements and deformations under the influence of forces and stresses. In the present study, so-called functional data were collected from healthy volunteers to provide consistent information for proper kinetics. For the latter purpose, biting and chewing forces, electrical muscle activity and jaw movements were registered synchronously, and individual magnetic resonance tomograms (MRI) were… More >

  • Open Access

    ARTICLE

    Predicting Drying Performance of Osmotically Treated Heat Sensitive Products Using Artificial Intelligence

    S. M. Atiqure Rahman1,*, Hegazy Rezk2,3, Mohammad Ali Abdelkareem1,4, M. Enamul Hoque5, Tariq Mahbub6, Sheikh Khaleduzzaman Shah7, Ahmed M. Nassef2,8

    CMC-Computers, Materials & Continua, Vol.67, No.3, pp. 3143-3160, 2021, DOI:10.32604/cmc.2021.015048

    Abstract The main goal of this research is to develop and apply a robust Artificial Neural Networks (ANNs) model for predicting the characteristics of the osmotically drying treated potato and apple samples as a model heat-sensitive product in vacuum contact dryer. Concentrated salt and sugar solutions were used as the osmotic solutions at 27C. Series of experiments were performed at various temperatures of 35C, 40C, and 55C for conduction heat input under vacuum ( −760 mm Hg) condition. Some experiments were also performed in a pure vacuum without heat addition. Dimensionless moisture content (DMC), effective moisture diffusivity, and mass flux were… More >

  • Open Access

    ARTICLE

    Optimization of the in-situ growth conditions based on a novel photo-microcalorimeter for the sustainable cultivation of photosynthetic microorganisms

    YANJUAN LIAO1,#, DONGLING YU2,#, XIAOFANG QIN1, JINMEI WU1, HUI WEI1, HUI LI1, XIANGYING MA1,*, ZAIYIN HUANG1,*

    BIOCELL, Vol.44, No.4, pp. 703-711, 2020, DOI:10.32604/biocell.2020.012047

    Abstract Despite the great potential of photosynthetic microbes in the production of renewable fuels, value-adding chemicals, and water treatment, etc., commercial utilization of them is significantly hindered by the lack of techniques to accurately monitor the thermodynamic and kinetic characteristics of the In-situ growth of microbes under controlled light illumination for optimal cultivation. Herein, we demonstrated that a newly developed highly sensitive photo-microcalorimetric system successfully captured the impacts of the light wavelength and strength on the thermodynamic and kinetic parameters of the In-situ growth of Rhodopseudomonas palustris, a representative photosynthetic microorganism. To our best knowledge, this is the first time that… More >

  • Open Access

    ARTICLE

    Preliminary Optimization and Kinetics of SnCl2-HCl Catalyzed Hydrothermal Conversion of Microcrystalline Cellulose to Levulinic Acid

    Dexby de Guzman, Rizalinda de Leon*

    Journal of Renewable Materials, Vol.9, No.1, pp. 145-162, 2021, DOI:10.32604/jrm.2021.011646

    Abstract Levulinic acid (LA) is a platform biorefinery chemical from biomass which can be converted to green solvents, plasticizers, polymer precursors, bio-based cleaning agents, fuels and fuel additives. This study assessed the potential of SnCl2-based mixed acid systems as catalyst in the hydrothermal conversion of microcrystalline cellulose to levulinic acid. Maximum LA yield of 36.2 mol% was achieved using 0.2 M SnCl2 concentration at test conditions of 3 h, 180°C and 1% w/v cellulose loading. To reduce precipitate formation and further improve LA yield, the strategy employed was to combine SnCl2 (a Lewis acid) with conventional mineral acids (Bronsted acids). Evaluation… More >

  • Open Access

    ARTICLE

    Green Composite Material Made from Typha latifolia Fibres Bonded with an Epoxidized Linseed Oil/Tall Oil-Based Polyamide Binder System

    Günter Wuzella1, Arunjunai Raj Mahendran1, Andreas Kandelbauer2,*

    Journal of Renewable Materials, Vol.8, No.5, pp. 499-512, 2020, DOI:10.32604/jrm.2020.09615

    Abstract Here, we report the mechanical and water sorption properties of a green composite based on Typha latifolia fibres. The composite was prepared either completely binder-less or bonded with 10% (w/w) of a bio-based resin which was a mixture of an epoxidized linseed oil and a tall-oil based polyamide. The flexural modulus of elasticity, the flexural strength and the water absorption of hot pressed Typha panels were measured and the influence of pressing time and panel density on these properties was investigated. The cure kinetics of the biobased resin was analyzed by differential scanning calorimetry (DSC) in combination with the iso-conversional… More >

  • Open Access

    ARTICLE

    Synthesis and Kinetics of Hydrogenated Rosin Dodecyl Ester as an Environmentally Friendly Plasticizer

    Qiaoguang Li1, Sheng Gong1, Jie Yan1, Hongchao Hu1, Xugang Shu1,2,*, Hanqing Tong3,*, Zhiye Cai1

    Journal of Renewable Materials, Vol.8, No.3, pp. 289-300, 2020, DOI:10.32604/jrm.2020.08897

    Abstract The plasticizer is an important polymer material additive. Non-toxic and environmentally friendly plasticizers are developed recently in order to decrease fossil fuel reserves, serious environmental pollution and the toxicity of phthalate esters. In this study, a new, efficient and environmentally friendly plasticizer of hydrogenated rosin dodecyl ester was prepared by an esterification reaction of hydrogenated rosin and dodecanol. The influences of different reaction conditions (including different catalysts, the catalyst concentration, the ratio of the reactants, reaction temperature, and reaction time) on the esterification yield are examined and discussed. Hydrogenated rosin dodecyl ester with 71.8% yield was synthesized under the optimized… More >

  • Open Access

    ARTICLE

    Orientation on the Mechanistics of Electron-Transfer on Oxidation of Chondroitin-4-Sulfate as Sustainable Sulfated Polysaccharide by Permanganate Ion in Aqueous Perchlorate Solutions

    Refat Hassan1,*, Hideo Takagi2, Samia Ibrahim3

    Journal of Renewable Materials, Vol.8, No.2, pp. 205-218, 2020, DOI:10.32604/jrm.2020.08530

    Abstract A spectrophotometric investigation of oxidation of chondroitin-4-sulfate (CS) as a sustainable and biodegradable sulfated macromolecule by oxyanion permanganate ion as multi-equivalent oxidant in acid perchlorate solutions at a constant ionic strength of 2.0 mol dm-3 has been studied. The experimental results on the influence of the concentration of the reactants the reaction rates revealed first-order dependence in MnO4 , fractional second-order in [CS] and fractional first-order with respect to the hydrogen ion concentration. The hydrogen acid concentration dependence of the rate constants indicated that the oxidation rates were increased with increasing the acid concentration which means that the oxidation reaction… More >

  • Open Access

    ABSTRACT

    Contour-Based Data Analysis: Loading Rate Dependence in Dynamic Catch of Integrin-Ligand Bonds

    Xueyi Yang1, Yue Xu1, Chun Yang1,*

    Molecular & Cellular Biomechanics, Vol.16, Suppl.2, pp. 101-101, 2019, DOI:10.32604/mcb.2019.07117

    Abstract Cell-matrix interactions guide various cell behaviors, including proliferation, differentiation, migration, etc. Integrins, as a known transmembrane mechanosensor, undergo conformational changes in response to mechanical stimuli, and manipulate cell-matrix chemical-mechanical coupled signaling transduction [1]. The integrin-ligand bond kinetics has gain increasing attention among researchers. Independent studies showed that the integrin-ligand bond has been reported to be reinforced by the applied force f, while the loading rate df/dt had little effect on the bond lifetime [2].
    We previously observed a dramatic increase in bond lifetime beyond a loading rate threshold for the integrin α2β1-DGEA bond, by introducing AFM (Atomic Force Microscopy)… More >

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