Jiapeng Wang¹, Bo Zhang^1,*, Haoqiang Cheng¹, Zhixiang Xu²

Journal of Renewable Materials, Vol.11, No.10, pp. 3595-3612, 2023, DOI:10.32604/jrm.2023.030005

Abstract A new method of pretreatment of corn straw with Phanerochaete chrysosporium combined with pyrolysis was proposed to improve the quality of bio-oil. The characterization results demonstrated that microbial pretreatment was an effective method to decrease the lignin, which can achieve a maximum removal rate of 44.19%. Due to the destruction of biomass structure, the content of alkali metal and alkaline earth metal is reduced. Meanwhile, the depolymerized biomass structure created better pyrolysis conditions to promote the pyrolysis efficiency, increase the average decomposition rate of pyrolysis and reduce the residue. In fast pyrolysis, because of the enrichment of cellulose and the… More > Graphic Abstract

Wenjing Xia^1,*, JinHui Wang¹, Tao Xu¹, Nan Jiang²

Journal of Renewable Materials, Vol.11, No.8, pp. 3387-3402, 2023, DOI:10.32604/jrm.2023.026971

Abstract To understand the effects of filler-asphalt ratio on different properties of lignin and polyester fiber reinforced shape memory polyurethane (SMPU)/styrene butadiene styrene (SBS) composite modified asphalt mortar (PSAM), as well as to reveal the reinforcing and toughening mechanisms of lignin and polyester fibers on PSAM, SMPU, SBS and mineral powder were first utilized to prepare PSAM. Then the conventional, rheological and anticracking properties of lignin fiber reinforced PSAM (LFAM) and polyester fiber reinforced PSAM (PFAM) at different filler-asphalt ratios were characterized. Test results indicate that the shear strength, deformation resistance and viscosity are increased after adding 0.8wt% lignin fiber or… More > Graphic Abstract

Honghong Wang¹, Zhixin Xiong^1,*, Yunchao Hu¹, Zhijian Liu¹, Long Liang²

Journal of Renewable Materials, Vol.11, No.6, pp. 2713-2727, 2023, DOI:10.32604/jrm.2023.025817

Abstract This study aims to realize the sharing of near-infrared analysis models of lignin and holocellulose content in pulp wood on two different batches of spectrometers and proposes a combined algorithm of SPA-DS, MCUVE-DS and SiPLS-DS. The Successive Projection Algorithm (SPA), the Monte-Carlo of Uninformative Variable Elimination (MCUVE) and the Synergy Interval Partial Least Squares (SiPLS) algorithms are respectively used to reduce the adverse effects of redundant information in the transmission process of the full spectrum DS algorithm model. These three algorithms can improve model transfer accuracy and efficiency and reduce the manpower and material consumption required for modeling. These results… More >

Chengxiang Li, Yue Wu, Chunhui Zhang^*, Yao Liu, Qixuan Lin, Junli Ren^*

Journal of Renewable Materials, Vol.11, No.6, pp. 2555-2574, 2023, DOI:10.32604/jrm.2023.026908

Abstract Hemicellulose and lignin are not reasonably utilized during the dissolved pulp preparation process. This work aimed to propose a process for the co-production of dissolving pulp, furfural, and lignin from eucalyptus. High-grade dissolving pulp was prepared from eucalyptus using a combination of extremely low acid (ELA) pretreatment, Kraft cooking, and elementary chlorine-free (ECF) bleaching. The obtained pre-hydrolysate was catalytic conversion into furfural in a biphasic system, and lignin during Kraft cooking and ECF was recovered. The process condition was discussed as well as the mass flow direction. The results showed that ELA pretreatment could effectively remove 80.1% hemicellulose. Compared with… More >

Sri Hidayati^1,*, Eugenia Fonny Budiyanto¹, Hadi Saputra¹, Sutopo Hadi¹, Apri Heri Iswanto^2,3, Nissa Nurfajrin Solihat⁴, Petar Antov⁵, Lee Seng Hua^6,7, Widya Fatriasari^4,8, Mohd. Sapuan Salit⁹

Journal of Renewable Materials, Vol.11, No.6, pp. 2865-2879, 2023, DOI:10.32604/jrm.2023.027579

Abstract Black liquor is obtained as a by-product of the pulping process, which is used to convert biomass into pulp by removing lignin, hemicelluloses and other extractives from wood to free cellulose fibers. Lignin represents a major constituent in black liquor, with quantities varying from 20% to 30%, of which a very low share is used for manufacturing value-added products, while the rest is mainly burned for energy purposes, thus underestimating its great potential as a raw material. Therefore, it is essential to establish new isolation and extraction methods to increase lignin valorization in the development of bio-based chemicals. The aim… More > Graphic Abstract

Saeed Kazemi Najafi¹, Farhood Najafi², Antonio Pizzi^3,*, Fatemeh Hassani Khorshidi^1,*, Rabi Behrooz¹

Journal of Renewable Materials, Vol.11, No.5, pp. 2171-2189, 2023, DOI:10.32604/jrm.2023.027835

Abstract Polyols are groups of organic compounds which contain carbon and are randomly linked to other atoms, especially carbon-carbon and carbon-hydrogen. These compounds are mainly used as reactants to make other polymers. Among biopolymers, lignin is regarded as the base of a new polymer in polyol construction. The present study aimed to investigate the effects of amine type (diethylenetriamine and ethylenediamine) on the modification of lignin-based polyols, so as to provide an alternative to petroleum polyols and, in turn, increase functional groups and reduce their harm to humans’ health and the environment. To this aim, first, lignin was extracted from raw… More > Graphic Abstract

Hamed Younesi-Kordkheili^1,*, Antonio Pizzi^2,*

Journal of Renewable Materials, Vol.11, No.5, pp. 2075-2083, 2023, DOI:10.32604/jrm.2023.026706

Abstract The influence of nanolignin coupling bio-agent on some characteristics of polypropylene-wood flour composites was studied. Thus, nanolignin was prepared by the acidic method, and then different ratios of it (0, 1, 3 and 5 wt%) were added to a polypropylene-wood flour mixture. After mechanically mixing wood flour, nanolignin, and polypropylene, the mixture was injection molded. ASTM methods were used to measure the structural properties of nanolignin, and prepared composites’ water absorption, thickness swelling, bending modulus, and bending, tensile and impact strengths. Transforming the original lignin to nanolignin did not change the chemical bonds of the material. The addition of nanolignin… More >

Penghui Li^1,2, Zhengwei Jiang², Chi Yang², Jianpeng Ren^1,2, Bo Jiang^1,2, Wenjuan Wu^1,2,*

Journal of Renewable Materials, Vol.11, No.5, pp. 2233-2248, 2023, DOI:10.32604/jrm.2023.025279

Abstract Lignin is a natural polymer, second only to cellulose in natural reserves. Degradation is one of the ways to achieve the high-value transformation of lignin. Deep eutectic solvent (DES) thermal degradation of lignin can be used as an excellent green degradation method. This paper introduces the degradation mechanism and effect of the lactic acid-choline chloride DES system in dissolving and degrading alkaline lignin, and the final solvent recovery. It can also be found from the scanning electron microscope (SEM) images that the surface of the degraded solid product is transformed from smooth to disordered. Fourier transform infrared (FTIR) spectroscopy and… More > Graphic Abstract

Chao Wang, Xuezhen Feng, Wanbing Li, Shibin Shang^*, Haibo Zhang^*

Journal of Renewable Materials, Vol.11, No.4, pp. 1793-1805, 2023, DOI:10.32604/jrm.2023.024521

Abstract Due to the low content of adsorption-active groups in lignin, its application in the field of adsorption is limited. Herein, we first prepared cationic kraft lignin acrylate, from which a cationic lignin (CKLA) hydrogel was further prepared by cationic kraft lignin acrylate, acrylamide, and N, N’-methylenebisacrylamide. The morphology, compression properties and swelling properties of CKLA hydrogels were investigated. The prepared CKLA hydrogel was applied as an adsorbent for Congo red. The effect of CKLA hydrogel dosages, initial concentration of Congo red, and pH on adsorption efficiency was investigated. The maximum Congo red removal efficiency was obtained at the initial concentration… More >

Lijing Huang, Penghui Li, Kangjie Jiang, Wenjuan Wu^*

Journal of Renewable Materials, Vol.11, No.4, pp. 1613-1626, 2023, DOI:10.32604/jrm.2022.023605

Abstract The effect of lignin structural units on enzymatic hydrolysis of lignocellulosic biomass was investigated, especially the inhibitory role of lignin in non-productive adsorption with enzymes. Milled wood lignin (MWL) was isolated from different hardwoods of poplar, eucalyptus and acacia. The isolated lignin samples were characterized by elemental analysis, gel permeation chromatography, nitrobenzene oxidation and fourier infrared spectroscopy. The mechanism of lignin structural units on enzymatic hydrolysis of cellulose was studied by quartz crystal microbalance (QCM). The results showed that different structural units of lignin had different adsorption capacity for enzymes. The results of nitrobenzene oxidation indicated that the S/G ratio… More > Graphic Abstract