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C. M. Fu^a, M. Z. Ge^b, X. Q. Zhang^c, W. Yan^c,*
Chalcogenide Letters, Vol.22, No.8, pp. 665-677, 2025, DOI:10.15251/CL.2025.228.665
Abstract Constructing heterojunctions represents a crucial strategy for enhancing semiconductor photocatalysts. In this study, the C-MoO₂/Cd_0.9Zn_0.1S S-scheme heterojunction composite was successfully fabricated through a self-assembly approach. XPS analysis confirmed the spontaneous transfer of intrinsic electrons from Cd_0.9Zn_0.1S to C-MoO₂ in the dark, establishing an internal electric field at the C-MoO2/Cd_0.9Zn_0.1S interface. Under visible light irradiation, the C-MoO₂/Cd_0.9Zn_0.1S composite exhibited significantly enhanced hydrogen evolution activity, achieving a 6.3-fold improvement compared to pristine Cd_0.9Zn_0.1S. PL, TRPL, and electrochemical measurements collectively demonstrated that the incorporation of C-MoO₂ effectively suppressed the recombination of photogenerated electrons in Cd_0.9Zn_0.1S. The outstanding photocatalytic performance and improved charge More >

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ARTICLE

S. R. Ahmed^a,*, M. V. V. K. Srinivas Prasad^b, K. Keerthivasan^c
Chalcogenide Letters, Vol.22, No.8, pp. 679-691, 2025, DOI:10.15251/CL.2025.228.679
Abstract This work used a sonication-aided approach to make Cadmium sulfide nanoparticles and Nitrogen-doped CdS nanoparticles. Doping Nitrogen into CdS NPs enhances the material's electrical, chemical, and structural properties by altering its surface area and functional sites. XRD, FTIR, SEM/EDX, TGA, UV-Vis, and PSA are used to evaluate the characteristic features of CdS NPs. The photovoltaic responses of the prepared CdS and CdS-N NPs were evaluated by electrochemical impedance and IV analysis. The obtained XRD data confirms that nitrogen doping significantly changes the crystal size of CdS NPs. The XPS spectrum depicts the presence of trace More >

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Q. Fei^1,*, B. Jin², B. C. Jiang³, J. S. Huang⁴, L. Li⁵
Chalcogenide Letters, Vol.22, No.8, pp. 693-705, 2025, DOI:10.15251/CL.2025.228.693
Abstract An innovative hybrid nanostructure composed of diketopyrrolopyrrole (DPP) oligomers and cadmium sulfide (CdS) nanoparticles was developed to enhance the efficiency of organic– inorganic photovoltaic devices. The DPP-CdS hybrids were synthesized via a solution-phase mixing method, resulting in uniform nanoparticle dispersion along polymer fibrils and strong interfacial coupling. Structural characterization confirmed the coexistence of crystalline CdS domains and partially ordered DPP phases, while spectroscopic analyses indicated notable redshifts and band broadening, evidencing electronic interactions at the interface. The hybrid material displayed significantly broadened light absorption across the 400–700 nm range and an optimized optical bandgap of… More >

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Y. Arooj^a, A. Farhan^b, S. Maqsood^a,c, A. Erum^a, M. Ishaq^d, S. Rafique^a, A. Khalid^b, F. Wazahat^a, M. A. Qamar^e,*
Chalcogenide Letters, Vol.22, No.8, pp. 707-717, 2025, DOI:10.15251/CL.2025.228.707
Abstract Chemical co-precipitation synthesis was used to make pure and zirconium-doped cobalt sulfide (Co3S4) nanoparticles (NPs). Important characterizations such as FTIR, UV-VIS, Raman, PL, SEM, XRD, and four probe methods were used to examine the influence of the Zr (0%, 5%, 10%, 15%, and 20%) doping on optical, electrical, structural, and thermoelectric characteristics of Co₃S₄ NPs. X-ray diffraction and SEM examination verified the cubic structure and grain size of pure and Zr-doped Co₃S₄-NPs. The FTIR spectrum revealed the rotational and vibrational modes linked to the material's surface. The material is optimal for photocatalytic activity with a redshift More >

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F. F. Tong^a,*, J. L. Han^b
Chalcogenide Letters, Vol.22, No.8, pp. 719-733, 2025, DOI:10.15251/CL.2025.228.719
Abstract In this study, hierarchical ZnS–CNT hybrids were synthesized via a solvothermal reaction at 180 °C for 48 h, producing ∼200 nm ZnS spheres uniformly anchored onto oxidized multiwalled carbon nanotubes. Structural analyses by XRD confirmed the cubic sphalerite phase, while SEM and TEM revealed a “pearl-necklace” morphology and effective nanoparticle dispersion. XPS spectra verified Zn²⁺ and oxygen-containing surface groups on the composite. Nitrogen adsorption–desorption measurements showed that incorporating CNTs transformed the material’s isotherm from type III to type IV, increasing the BET surface area from 68 to 155 m² /g and introducing mesoporosity. When drop-cast onto More >

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A. W. Jabbar^a, N. K. Abbas^b,*
Chalcogenide Letters, Vol.22, No.8, pp. 735-752, 2025, DOI:10.15251/CL.2025.228.735
Abstract Nanostructured CdS and CdS: Cu thin films were synthesized by pulsed laser deposition with a Nd: YAG laser of different energies, 0.1, 0.5, and 1 W. The number of pulses was 300, and the frequency was 20 kHz. The CdS nanoparticles were deposited on a glass substrate. The optical, structural, and morphological properties were investigated utilized X-ray diffraction, UV-Vis spectrophotometry, and field emission scanning electron microscopy. From 2.25 to 2.1 eV, the results demonstrate that the band gap energy reduces as laser energy increases. Morphological investigations reveal that the laser energy has a significant impact More >

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Sh. B. Utamuradova^a, F. A. Giyasova^b, M. S. Paizullakhanov^c, S. Yu. Gerasimenko^d, M. A. Yuldoshev^e,g,*, S. R. Boydedayev^g, M. R. Bekchanova^h
Chalcogenide Letters, Vol.22, No.8, pp. 753-764, 2025, DOI:10.15251/CL.2025.228.753
Abstract Based on the experimental data, the results of the study of photoelectric and gain characteristics of modified multi-barrier photodiode Au-nCdS-nSi-pCdTe-Au structures are presented, which are obtained by the method of vacuum evaporation in a quasi-closed volume by sputtering cadmium sulfide and cadmium telluride layers on a silicon substrate with a specific resistance of 607.47 Ohm⋅cm. It is shown that the structures in the passing direction of the current at low illumination levels operate as injection photodiodes, and also the optical spectral range (0.3÷0.95 μm) covers from the nSi-pCdTe-Au side and (1.0÷1.4 μm) from the Au-nCdS-nSi More >

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