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    Structural and Optical Properties of Cu2ZnSn(S1−xSex)4 Nanostructures Thin Film for Photovoltaic Applications

    Bushra A. Hasan1, Ameer J. Fadhl2, Ahmad A. Hasan1, Yasser A. Jebbar3,*
    Chalcogenide Letters, DOI:10.32604/cl.2026.079634
    Abstract Copper zinc tin sulfide selenide, Cu2ZnSn(S1−xSex)4, absorbers are promising earth-abundant and environmentally benign materials for low-cost photovoltaic applications. This study investigates the structural and optical properties of Cu2ZnSn(S1−xSex)4 nanostructured thin films prepared by pulsed laser deposition using melt-quenched targets with selenium compositions x = 0.0–1.0. X-ray diffraction revealed that films with low selenium content remained amorphous, whereas higher selenium incorporation promoted the formation of polycrystalline kesterite–stannite phases with preferred orientations along (112), (200), (220), and (312). The crystallite size increased from 12.3 to 17.9 nm as selenium reached x = 1.0, indicating enhanced crystal growth. Atomic force… More >

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