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  • Open AccessOpen Access

    ARTICLE

    Enhancement of Thermoelectric Properties in N-Type and P-Type Ag–Te Nanocomposites via Stirring-Assisted Hydrothermal Synthesis

    Donghyeon Lee#, Jiu Kim#, Yong-Wook Jeong#, Miso Shin, Yong Jin Jeong*
    Chalcogenide Letters, Vol.23, No.2, 2026, DOI:10.32604/cl.2026.077885 - 28 February 2026
    Abstract Silver tellurides (Ag–Te) are promising low-temperature thermoelectric materials because their transport properties can be tuned by subtle compositional variations and nanostructuring. Here, we report a stirring-assisted hydrothermal route that enables controlled synthesis of n-type and p-type Ag–Te nanostructures by adjusting the Ag:Te precursor ratio and hydrodynamic conditions. Samples with Ag:Te ratios of 2:1 (Ag2/Te1) and 1:2 (Ag1/Te2) were synthesized at 120°C for 12 h, varying the stirring speed from 0 to 2000 rpm. X-ray diffraction confirms Ag2Te as the dominant phase for Ag2/Te1 across all conditions, while Te-rich Ag1/Te2 forms a composite mainly consisting of Te More >

  • Open AccessOpen Access

    ARTICLE

    Numerical Simulation of High-Performance Lead-Free BaZrS3/CIGS Tandem Solar Cells

    Jun Zhang, Jiayi Song, Wangjian Fu, Jiren Yuan*
    Chalcogenide Letters, Vol.23, No.2, 2026, DOI:10.32604/cl.2026.077226 - 28 February 2026
    Abstract Tandem solar cells employing lead-free perovskite materials offer a compelling pathway to simultaneously achieve high power conversion efficiency (PCE) and improved environmental sustainability. In this work, we present a comprehensive numerical simulation study of monolithic and mechanically stacked tandem solar cells based on the chalcogenide perovskite BaZrS3 as the top subcell and Cu(In,Ga)Se2 (CIGS) as the bottom subcell. For the four-terminal (4-T) configuration, a systematic optimization workflow was implemented, encompassing the thickness of absorber and carrier-transport layers, doping concentrations, and the introduction of a LiF anti-reflection coating. This approach led to a marked reduction in parasitic… More >

  • Open AccessOpen Access

    ARTICLE

    A Comprehensive Insight to the Physical Properties of NaCuZrS3

    Hongli Guo1,*, Huanyin Yang1, Suihu Dang1, Shunru Zhang2, Haijun Hou3
    Chalcogenide Letters, Vol.23, No.2, 2026, DOI:10.32604/cl.2026.076290 - 28 February 2026
    Abstract To gain deeper insights into the characteristics of orthorhombic NaCuZrS3, this study investigates its mechanical, electronic and thermal properties using a theoretical approach grounded in density functional theory (DFT). The computed structural parameters align closely with experimental data. Additionally, its elastic constants and moduli show an increasing trend as pressure increases. It confirms that this material is brittle at 0 GPa, but as the pressure increases, it transforms into a ductile material after 10 GPa. Through computational analysis, the electronic properties for NaCuZrS3 are determined. The material is an indirect bandgap semiconductor with a bandgap of More >

  • Open AccessOpen Access

    ARTICLE

    Impact of Lead Incorporation on the Crystallization Kinetics and Thermal Stability of Se87.5Te10Pb2.5

    M. A. Al-Maghrabi*
    Chalcogenide Letters, Vol.23, No.2, 2026, DOI:10.32604/cl.2026.078794 - 28 February 2026
    Abstract The present study investigates the influence of lead incorporation on the crystallization kinetics and thermal behavior of Se87.5Te10Pb2.5 glass prepared by the melt-quenching technique and characterized by differential scanning calorimetry over heating rates of 5–99 K·min1. Nonisothermal kinetic parameters were evaluated using model-free isoconversional methods, namely the Friedman and Vyazovkin approaches, while the Matusita model was employed to gain insight into the crystallization dimensionality. Complementary isothermal simulations were used to support the kinetic interpretations. The apparent activation energy exhibits a systematic decrease with increasing temperature and crystallized fraction, suggesting a multi-stage crystallization process. At lower temperatures,… More >

  • Open AccessOpen Access

    ARTICLE

    DFT-Based Study of Structural, Electronic, Optical and Elastic Properties of CdGeAs2 and CdSnAs2 Chalcopyrires

    Khaled Lazar1, Y. Megdoud2,3,*, R. Meneceur1, M. Laouamer1, Y. Yahiaoui4, A. Achour5, Y. Benkrima6,*, A. Boukhari1
    Chalcogenide Letters, Vol.23, No.2, 2026, DOI:10.32604/cl.2026.076585 - 28 February 2026
    Abstract This study reports a comprehensive first-principles investigation of the chalcopyrite semiconductors CdGeAs2 and CdSnAs2, with particular emphasis on their structural, electronic, optical, and elastic properties. The calculations were carried out within the density functional theory (DFT) framework using the full-potential linearized augmented plane wave (FP-LAPW) method. The optimized equilibrium structural parameters, including lattice constants a and c as well as the internal coordinate u, show very good consistency with available experimental measurements and earlier theoretical predictions. Band structure calculations confirm that both compounds exhibit direct band gaps, which makes them attractive candidates for photovoltaic and optoelectronic More >

  • Open AccessOpen Access

    ARTICLE

    Bi2S3 Nanorod–Carbon Fiber Hybrid Electrode for Sensitive Electrochemical Detection of Zearalenone in Cereal Samples

    Feifei Tong1, Junliang Han1, Chuansheng Tang2,*, Jie Yang3, Shibo Luo3, Xinmeng Wu4
    Chalcogenide Letters, Vol.23, No.2, 2026, DOI:10.32604/cl.2026.076718 - 28 February 2026
    Abstract Zearalenone (ZEA) contamination in cereal-based food products represents a significant threat to global food safety and public health. As a potent non-steroidal estrogenic mycotoxin, ZEA mimics 17β-estradiol and acts as an endocrine disruptor, leading to severe reproductive toxicity and pathologies such as hepatotoxicity and immunotoxicity. Its prevalence in staple crops like maize and wheat results in substantial economic losses and necessitates adherence to stringent regulatory limits (e.g., 50 μg/kg set by EFSA) to protect consumers from chronic low-dose exposure. This work reports the development of a novel electrochemical sensor based on a bismuth sulfide nanorod–carbon… More >

  • Open AccessOpen Access

    ARTICLE

    Photocatalytic Performance of Kaolin/Cu2CdSnS4 Composite Synthesized via Solvothermal Route

    Hao Guan*, Zicheng Wang, Ruiyang Dai, Tao Dai
    Chalcogenide Letters, Vol.23, No.2, 2026, DOI:10.32604/cl.2026.075941 - 28 February 2026
    Abstract Cu2CdSnS4 (CCTS) has positioned itself as an efficient option used as a photocatalyst, while kaolin is an ideal catalyst carrier material. In the study, kaolin/Cu2CdSnS4 composite catalyst is effectively synthesized by a one-step solvothermal route and applied to remove methylene blue (MB), a typical pollutant in the textile industry. The structural, morphological, and photocatalytic properties of the composite catalyst are characterized by XRD, SEM, FTIR, PL, etc. The results show that a pure kaolin/Cu2CdSnS4 composite is obtained. The flower-like structure of Cu2CdSnS4 exhibits higher photocatalytic activity due to its relatively large specific surface area, while kaolin creates More >

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