Bio-Derived Tannin-Modified Phenolic Carbon Cryogels with Optimized Microstructure for Supercapacitors Application
Zhiying Lin1, Boju Deng1, Qianqian Zhang1, Jingming Chen2, Xinqiang Ye3, Yuling Lan1, Jiuping Rao1,*, Mizi Fan4, Weigang Zhao1,*
Journal of Renewable Materials, Vol.14, No.5, 2026, DOI:10.32604/jrm.2025.02025-0096
- 28 May 2026
(This article belongs to the Special Issue: Renewable Nanostructured Porous Materials: Synthesis, Processing, and Applications)
Abstract Bio-derived carbon cryogels have garnered significant interest as promising electrode materials for supercapacitors due to their high specific surface area (SSA), hierarchical porosity, and eco-friendly synthesis methods. In this study, a tannin-modified phenolic hydrogel was synthesized using a sustainable tannin–phenol precursor system and subsequently subjected to three distinct drying methods-freeze-drying (FD), supercritical drying (SCD), and ambient pressure drying (APD)-to systematically evaluate their influence on structural integrity, porosity, and electrochemical behavior. Among these, the sample obtained via freeze-drying (TPUF-FD) maintained the most intact porous network, minimizing structural collapse during sublimation of ice under vacuum. This preservation… More >
Graphic Abstract